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Transportation-Related Air Toxics:
Case Study Materials Related to US 95 in Nevada

Revised Final White Paper
STI-902370-2308-RFWP

By:
Todd M. Tamura
Douglas S. Eisinger
Sonoma Technology, Inc.
1360 Redwood Way, Suite C
Petaluma, CA 94954-1169

Prepared for:
Michael Koontz and Michael J. Savonis, HEPN 10
U.S. Federal Highway Administration
Office of Natural Environment
400 7th Street SW
Washington D.C., 20590

March 7, 2003

ACKNOWLEDGMENTS

The authors thank Fred Lurmann, Hilary Hafner, Dr. Patrick Ryan, and Lyle Chinkin of STI for technical comments and advice, and Michael Koontz for providing technical direction as the FHWA project manager.

TABLE OF CONTENTS

LIST OF FIGURES
LIST OF TABLES
ACRONYMS
EXECUTIVE SUMMARY

  1. INTRODUCTION
    1.1 Purpose
    1.2 Report Organization

  2. RELEVANT AIR TOXICS AND QUANTIFICATION OF CANCER RISKS
    2.1 Identification of Relevant On-Road Mobile Source Air Toxics
    2.2 Quantification of Cancer Risks from Air Toxics
    2.3 Conclusions Regarding Important Air Toxics

  3. AIR TOXICS AND REGIONAL AIR QUALITY
    3.1 On-Road Mobile Sources as a Fraction of Regional-Scale Problems: Brief Citations from Example Literature
    3.1.1 EPA National-Scale Air Toxics Assessments
    3.1.2 California Air Resources Board Emissions and Air Quality Almanac
    3.1.3 SCAQMD MATES-II Report
    3.2 Review of the MATES-II Study
    3.2.1 Fraction of MSAT Emissions from On-Road Mobile Sources
    3.2.2 Monitoring Data and Risk Assessment
    3.2.3 Comparison to Other Recent Southern California Research
    3.2.4 Observations Concerning MATES-II vs. EPA DPM Risk Characterizations
    3.3 Regional Emissions Trends
    3.4 Summary Observations Concerning Mobile Sources and Regional Contributions to Air toxics

  4. AIR TOXICS AND LOCALIZED AIR QUALITY
    4.1 Background
    4.2 Measurements of Concentrations as a Function of Distance from Roadways
    4.3 MATES-II Data
    4.3.1 Modeling Data
    4.3.2 Discussion of MATES-II Monitoring Results Near Freeways
    4.4 Epidemiological Studies
    4.4.1 Observations Concerning the Denver, CO, Study
    4.4.2 Observations Concerning Additional Epidemiological Literature
    4.4.3 Summary Comments Concerning Epidemiological Literature
    4.5 Overall Conclusions Regarding Localized Air Quality.

  5. COMMENTS ON SIERRA CLUB CORRESPONDENCE
    5.1 Applicability of MATES-II Findings to Las Vegas
    5.1.1 Summary of MATES-II Findings
    5.1.2 Criteria to Ascertain the Applicability of MATES-II Findings to Las Vegas
    5.1.3 Consideration of Applicability Criteria
    5.2 FINE PARTICULATE MATTER (PM2.5)
    5.2.1 Sierra Club Comments
    5.2.2 Discussion of Comments

  6. SUMMARY AND CONCLUSIONS
    6.1 Regional Impacts from MSAT
    6.2 Local Impacts from MSAT
    6.3 Transferability of MATES-II Findings to Las Vegas.
    6.4 Fine Particulate Matter (PM2.5)
    6.5 Summary Discussion of Issues Raised by the Sierra Club
    6.5.1 Introduction
    6.5.2 Discussion of Sierra Club Comments

  7. REFERENCES

APPENDIX A: ADDITIONAL INFORMATION CONCERNING ESTIMATION OF DIESEL PM CONCENTRATIONS AND VARIABILITY OF DIESEL PM COMPOSITION
APPENDIX B: SUMMARY OF ISSUES SURROUNDING HEALTH RISK
APPENDIX C: DOCUMENTATION OF VEHICLE EMISSION FACTOR MODEL USAGE

LIST OF FIGURES

ES-1. Relative contributions of on-road mobile, non-road mobile, and stationary source emissions of DPM, benzene, 1,3-butadiene, formaldehyde, and acetaldehyde in California's South Coast Air Basin, as documented in the SCAQMD's MATES-II study

3-1. Relative contributions of on-road mobile, non-road mobile, and stationary source emissions of DPM, benzene, 1,3-butadiene, formaldehyde, and acetaldehyde in California's South Coast Air Basin, as documented in the SCAQMD's MATES-II study

3-2. Projections for nationwide mobile source emissions of priority MSAT, as identified in the EPA MSAT rulemaking

4-1. Pollutant concentrations as a function of wind speed and distance from the roadway, as predicted by EPA's CAL3QHC2 model, assuming no background concentrations exist

5-1. Relative contributions to Las Vegas air toxics concentrations, estimated by EPA

5-2. Comparison of monitored ambient elemental carbon concentrations for southern California and Las Vegas

5-3. Calendar year 2000 ambient PM2.5 monitoring data for southern California and the Las Vegas area

LIST OF TABLES

ES-1. Summary listing of major technical issues raised by the Sierra Club

2-1. EPA's 21 Mobile Source Air Toxics

2-2. Comparison of Unit Risk Factors for priority MSAT

5-1. Comparison of on-road fleet average vehicle emission factors for the South Coast and Las Vegas

6-1. Summary listing of major technical issues raised by the Sierra Club

A-1. Comparison of methods to estimate 1982 DPM concentrations in Los Angeles

A-2. Major sources of DPM in MATES-II, and proportions of EC

ACRONYMS

CARB
California Air Resources Board
CO
Carbon Monoxide
DEOG
Diesel Exhaust Organic Gases
DPM
Diesel Particulate Matter
EC
Elemental Carbon
EIS
Environmental Impact Statement
EPA
U.S. Environmental Protection Agency
FHWA
Federal Highway Administration
HC
Hydrocarbons
HDDV
Heavy-Duty Diesel Vehicles
LDGV
Light-Duty Gasoline Vehicles
MATES-II
Multiple Air Toxics Exposure Study
MSAT
Mobile Source Air Toxics
NAAQS
National Ambient Air Quality Standard
NATA
EPA National Air Toxics Assessment
NDOT
Nevada Department of Transportation
OC
Organic Carbon
OEHHA
California Office of Environmental Health Hazard Assessment
PAH
Polycyclic Aromatic Hydrocarbons
PM
Particulate Matter
PMx
Particulate Matter smaller than x mm in diameter
POM
Polycyclic Organic Matter
SCAQMD
South Coast Air Quality Management District
SEIS
Supplemental Environmental Impact Statement
STI
Sonoma Technology, Inc.
UAM
Urban Airshed Model
URF
Unit Risk Factor
VMT
Vehicle Miles Traveled
VPD
Vehicles Per Day
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