Research Highlights
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Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods
This study provides extensive validation for 3D-to-2D model reduction for redox flow batteries (RFBs). This computationally light, 2D model is used to generate a data set of >6,000 unique RFB simulations for statistical quantification. Read More
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Ion-conducting Thermo-responsive Films Based on Polymer Grafted Cellulose Nanocrystals
Mechanically robust, thermoresponsive, ion-conducting nanocomposite films have been prepared from ionic liquid imbibed poly(2-phenylethyl methacrylate)-grafted cellulose nanocrystals. On account of the lower critical solution temperature (LCST) of the grafted polymer in the ionic liquid, these materials exhibit a conductivity decrease around 60 °C Read More
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Competition of Stacking and Piling Improves Molecular Solubility in Electrolyte
Organic redox-active molecules (redoxmers) are charge carriers in redox flow cells. Since the energy density of a battery fluid is proportional to concentration of active molecules, high molecular solubility is desirable. However, as the redoxmer solutions become crowded, solute-solute interactions become stronger, opposing high solubility. Here we demonstrate how a small redoxmer molecule, 2,1,3-benzothiadiazole (BzNSN), can achieve exceptionally high solubility through a competition of two packing motifs – N-H bond piling and π-stacking – that introduces disorder that frustrates crystallization in concentrated solutions. Read More
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Greater redoxmer stability through nanoconfinement
Structural diversity of organic redox-active molecules (redoxmers) permits tuning not only solute-electrolyte interactions but also solute-solute interactions in concentrated electrolyte solutions. The 1,4-dimethoxybenzene (DMB) family is an example of such flexibility. We show that DMB molecule 1 forms extended aggregates in concentrated solutions whereas simpler DMB molecules 2 and 3 do not. The resulting networks expel solvent and aggregated ions to small and increasingly isolated nanodomains. Charged redoxmer molecules are also expelled to such domains and their stability increases dramatically due to nanoconfinement (“microreactor”) effects. Read More
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Highly Reversible Plating/Stripping of Porous Zinc Anodes for Multivalent Zinc Batteries
Highly reversible Zn plating/stripping achieved with electrodes prepared by electrodepositing Zn onto porous 3D Cu foam. Read More
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Ion Solvation Engineering: How to Manipulate the Multiplicity of the Coordination Environment of Multivalent Ions
Advanced free-energy sampling analysis shows that the multiplicity of thermodynamically stable solvation configurations is a general feature of free divalent cations, their ion-pairs and neutral aggregates in low dielectric solvents. We reveal the macro- and microscopic factors of the solvation multiplicity and show how their interplay can be used to manipulate ion solvation environments and thus the ion solvation-desolvation dynamics. Read More
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Direct observation of cyclic polymer dynamics in shear flow reveals non-equilibrium behavior for flow-based applications
Single ring polymers were directly visualized in the flow-gradient plane of shear flow to understand their dynamic behavior such as tumbling and stretching in flow, as well as the distribution of polymer conformations far-from-equilibrium. Read More
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Oxygen Facilitates Mg2+ Diffusion Through Fe3O4
Controlled processing of carefully designed Fe3O4/MgO heterostructures allowed identification of the Mg2+ diffusion pathways, reaction intermediates, and the key role of the anion in these energy-relevant systems. Read More
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Bis(diisopropylamino)cyclopropenium-arene Cations as High Oxidation Potential and High Stability Catholytes for Nonaqueous Redox Flow Batteries
Development of a new catholyte with both extremely high potential and much improved cycling stability Read More
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A Highly Concentrated Electrolyte for High Capacity and Coulombic Efficiency in Li-NCM811 Cells
Replacing a dilute 1 M LiPF6-based electrolyte with a hydrofluoroether (HFE)-modified highly concentrated electrolyte (HCE) stabilizes the Li metal interface and results in higher discharge capacity, Coulombic efficiency, and thermal stability. Read More
Latest Updates
See All-
Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods
This study provides extensive validation for 3D-to-2D model reduction for redox flow batteries (RFBs). This computationally light, 2D model is used to generate a data set of >6,000 unique RFB simulations for statistical quantification. Read More
-
Ion-conducting Thermo-responsive Films Based on Polymer Grafted Cellulose Nanocrystals
Mechanically robust, thermoresponsive, ion-conducting nanocomposite films have been prepared from ionic liquid imbibed poly(2-phenylethyl methacrylate)-grafted cellulose nanocrystals. On account of the lower critical solution temperature (LCST) of the grafted polymer in the ionic liquid, these materials exhibit a conductivity decrease around 60 °C … Read More
-
Competition of Stacking and Piling Improves Molecular Solubility in Electrolyte
Organic redox-active molecules (redoxmers) are charge carriers in redox flow cells. Since the energy density of a battery fluid is proportional to concentration of active molecules, high molecular solubility is desirable. However, as the redoxmer solutions become crowded, solute-solute interactions become stronger, opposing high solubility. Read More
-
Greater redoxmer stability through nanoconfinement
Structural diversity of organic redox-active molecules (redoxmers) permits tuning not only solute-electrolyte interactions but also solute-solute interactions in concentrated electrolyte solutions. The 1,4-dimethoxybenzene (DMB) family is an example of such flexibility. We show that DMB molecule 1 forms extended aggregates in concentrated solutions whereas simpler … Read More
-
Highly Reversible Plating/Stripping of Porous Zinc Anodes for Multivalent Zinc Batteries
Highly reversible Zn plating/stripping achieved with electrodes prepared by electrodepositing Zn onto porous 3D Cu foam. Read More
