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Toluene-2,4-diisocyanate |
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Synonyms & Trade NamesTDI; 2,4-TDI; 2,4-Toluene diisocyanate |
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CAS No.584-84-9 |
RTECS No.CZ6300000 |
DOT ID & Guide2078 156 |
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FormulaCH3C6H3(NCO)2 |
Conversion1 ppm = 7.13 mg/m3 |
IDLHCa [2.5 ppm]See: 584849 |
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Exposure LimitsNIOSH REL: Ca See Appendix AOSHA PEL†: C 0.02 ppm (0.14 mg/m3) |
Measurement MethodsNIOSH 2535 , 5521 , 5522 , 5525; OSHA 18 , 33 , 42 See: NMAM or OSHA Methods |
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Physical DescriptionColorless to pale-yellow solid or liquid (above 71°F) with a sharp, pungent odor. |
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MW:174.2 |
BP:484°F |
MLT: 71°F | Sol:Insoluble |
VP(77°F): 0.01 mmHg | IP:? |
Sp.Gr:1.22 |
Fl.P:260°F |
UEL:9.5% |
LEL:0.9% |
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Class IIIB Combustible Liquid: Fl.P. at or above 200°F. | |||||
Incompatibilities & ReactivitiesStrong oxidizers, water, acids, bases & amines (may cause foam & spatter); alcohols [Note: Reacts slowly with water to form carbon dioxide and polyureas.] |
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Exposure Routesinhalation, ingestion, skin and/or eye contact |
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Symptomsirritation eyes, skin, nose, throat; choke, paroxysmal cough; chest pain, retrosternal (occurring behind the sternum) soreness; nausea, vomiting, abdominal pain; bronchitis, bronchospasm, pulmonary edema; dyspnea (breathing difficulty), asthma; conjunctivitis, lacrimation (discharge of tears); dermatitis, skin sensitization; [potential occupational carcinogen] |
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Target OrgansEyes, skin, respiratory system |
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Cancer Site[in animals: pancreas, liver, mammary gland, circulatory sys & skin tumors] | |||||
Personal Protection/Sanitation(See protection codes)Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated/Daily Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench |
First Aid(See procedures)Eye: Irrigate immediately Skin: Soap wash immediately Breathing: Respiratory support Swallow: Medical attention immediately |
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Respirator Recommendations
NIOSH At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: Escape: |
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See also: INTRODUCTION See ICSC CARD: 0339 See MEDICAL TESTS: 0233 |
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