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Reactive Air Aluminizing

Pacific Northwest National Laboratory

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Reactive Air Aluminizing process diagram
Reactive Air Aluminizing process diagram

This image reveals the continuous protective layer remains intact following extreme heat exposure.
This image reveals the continuous protective layer remains intact following extreme heat exposure.

Technology Marketing Summary

Reactive Air Aluminizing is a process for applying a protective coating on steel components in solid oxide fuel cells and other high temperature electrochemical devices. This innovative process results in a continuous aluminum oxide coating that reduces chromium volatility and mitigates chemical interaction between glass seals and steel components during exposures at extremely high temperatures (up to 800° Celsius in lab tests).

Description

During SOFC operation, the high operating temperature causes chromium evaporation from steel interconnects and balance-of-plant components, which can result in cathode poisoning, which will degrade the SOFC stack performance over time. In addition, chemical reactions between glass seals and steel interconnects can form high thermal expansion interfacial phases, which substantially reduce the mechanical integrity of the sealing region of the SOFC stack. The new process represents a significant advance over the current state-of-the-art aluminization processes, by allowing for reduction of both materials and processing costs. Developed by researchers at Pacific Northwest National Laboratory, the key benefit to the Reactive Air Aluminizing process is the fact that the process is performed in air. This eliminates the need for more costly and involved processes for heating requiring controlled atmosphere environments.

Benefits

• Provides a continuous protective layer
• Remains stable over time at high temperatures (up to 800 degrees Celsius) and prevents chromium evaporation
• Aluminum reservoir in steel allows for self-healing of damaged regions
• Delivers simplicity - the process does not require a special environment for heating
• Reduces material and processing costs

Applications and Industries

Potential industry applications include: Aerospace & Defense, Automotive & Transportation, Energy & Utilities, and Manufacturing & Warehousing.

Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
15848PrototypeAvailable10/03/201110/03/2011

Contact PNNL About This Technology

To: Jennifer Hodas<Jennifer.Hodas@pnnl.gov>