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Carbon Ion Pump for Carbon Dioxide Removal

Lawrence Livermore National Laboratory

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Technology Marketing Summary

The limitation to reducing greenhouse gases in the atmosphere is the expense of stripping carbon dioxide from other combustion gases. Without a cost-effective means of accomplishing this, hydrocarbon resources cannot be used freely. A few power plants currently remove carbon dioxide from flue gas for sale as an industrial product. Oil companies commonly remove carbon dioxide from natural gas to improve its energy content. In both cases, the most common technology is a temperature-swing absorption (TSA) using a methylated ethyl amine solvent (MEA).

Description

LLNL has developed a new method of separating carbon dioxide from flue gas. LLNL's ion pump method increases the concentration of dissolved carbonate ion solution. This increases the vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, or the Cussler ion pump.

Benefits

LLNL's novel approach to increasing the concentration of the extracted gas permits new approaches to treating flue gas and other gas mixtures of inert gas like nitrogen, with acid gases like carbon dioxide of sulfur dioxide. The process may be operated to produce clean water (similar to reverse osmosis water) as an additional product. The simple, robust nature of the process lends itself to small separation plants.

Applications and Industries
  • Eliminating carbon dioxide as a greenhouse gas pollutant:
    • coal fired power plants
    • oil or gas fired power plants
    • cement production
    • bio-fuel combustion
  • Separation of carbon dioxide from other combustion gases
  • Separation of carbon dioxide from gas mixtures:
    • natural gas fields
    • methane from landfill decomposition
  • Separation of carbon dioxide from the atmosphere
  • Separation of sulfur dioxide
  • Production of carbon dioxide for use in enhanced oil recovery
  • Production of carbon dioxide as a food additive
Patents and Patent Applications
ID Number
Title and Abstract
Primary Lab
Date
Patent 7,828,883
Patent
7,828,883
Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures
A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.
Lawrence Livermore National Laboratory 11/09/2010
Issued
Technology Status
Technology IDDevelopment StageAvailabilityPublishedLast Updated
19608PrototypeAvailable05/05/201105/05/2011

Contact LLNL About This Technology

To: Annemarie Meike<meike1@llnl.gov>