LiFePO4 is a high power rate cathode material for lithium ion battery and shows remarkable capacity retention, featuring a 91% capacity retention after 3300 cycles. In this work, we use high-resolution transmission electron microscopy (HRTEM), energy dispersive x-ray spectroscopy (EDS), and electron energy loss spectroscopy (EELS) to study the gradual capacity fading mechanism of LiFePO4 materials. We found that upon prolonged electrochemical cycling of the battery, the LiFePO4 cathode shows surface amorphization and loss of oxygen species, which directly contribute to the gradual capacity fading of the battery. The finding is of great importance for the design and improvement of new LiFePO4 cathode for high-energy and high-power rechargeable battery for electric transportation.
Probing The Failure Mechanism Of Nanoscale LiFePO4 For Li-ion Batteries.
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Gu M, W Shi, J Zheng, P Yan, J Zhang, and CM Wang.2015."Probing The Failure Mechanism Of Nanoscale LiFePO4 For Li-ion Batteries."Applied Physics Letters 106(20):Article No. 203902. doi:10.1063/1.4921628
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2015