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Kinetics and Thermodynamics of Reversible Thiol Additions to Mono- and Diactivated Michael Acceptors: Implications for the Design of Drugs That Bind Covalently to Cysteines

Elizabeth H. Krenske*, Russell C. Petter, and K. N. Houk*

Total Synthesis of the Bis-silyl Ether of (+)-15-epi-Aetheramide A

Omkar Revu and Kavirayani R. Prasad*

Conversion of Arylboronic Acids to Tetrazoles Catalyzed by ONO Pincer-Type Palladium Complex

Arumugam Vignesh, Nattamai S. P. Bhuvanesh, and Nallasamy Dharmaraj*

Rhodium-Catalyzed [3 + 2] Annulation of Cyclic N-Acyl Ketimines with Activated Olefins: Anticancer Activity of Spiroisoindolinones

Satyasheel Sharma, Yongguk Oh, Neeraj Kumar Mishra, Umasankar De, Hyeim Jo, Richa Sachan, Hyung Sik Kim, Young Hoon Jung, and In Su Kim*

Ionic Liquid-Based Microemulsions in Catalysis

Mahtab Hejazifar, Martyn Earle, Kenneth R. Seddon, Stefan Weber, Ronald Zirbs, and Katharina Bica*

    Articles ASAP (As Soon As Publishable)

    ASAP articles are edited and published online ahead of issue. See all ASAP articles.

    Probing the Role of Glycol Chain Lengths in π-Donor–Acceptor [2]Pseudorotaxanes Based on Monopyrrolo-Tetrathiafulvalene and Cyclobis(paraquat-p-phenylene)

    Rikke Kristensen, Sissel S. Andersen, Gunnar OlsenJan O. Jeppesen
    Publication Date (Web): December 27, 2016 (Article)
    DOI: 10.1021/acs.joc.6b02466
    Figure

    Synthesis and Electron Spin Relaxation of Tetracarboxylate Pyrroline Nitroxides

    Shengdian Huang, Joseph T. Paletta, Hanan Elajaili, Kirby Huber, Maren Pink, Suchada Rajca, Gareth R. Eaton, Sandra S. Eaton, and Andrzej Rajca
    Publication Date (Web): December 29, 2016 (Article)
    DOI: 10.1021/acs.joc.6b02737
    Figure

    Lewis Acid Catalyzed Dehydrogenative Coupling of Tertiary Propargylic Alcohols with Quinoline N-Oxides

    Ya-Ya-Ping Han, Xue-Song Li, Xin-Yu Zhu, Ming Li, Li Zhou, Xian-Rong Song, and Yong-Min Liang
    Publication Date (Web): January 6, 2017 (Article)
    DOI: 10.1021/acs.joc.6b02882
    Figure

    A Theoretical Mechanistic Study of the Asymmetric Desymmetrization of a Cyclic meso-Anhydride by a Bifunctional Quinine Sulfonamide Organocatalyst

    Katie Blise, Milan W. Cvitkovic, Nolly J. Gibbs, Sean F. Roberts, Reid M. Whitaker, Gretchen E. HofmeisterDaniela Kohen
    Publication Date (Web): December 13, 2016 (Article)
    DOI: 10.1021/acs.joc.6b02320
    Figure

    Total Synthesis of the Labdane Diterpenes Galanal A and B from Geraniol

    Shih-Che Lin and Rong-Jie Chein
    Publication Date (Web): December 30, 2016 (Article)
    DOI: 10.1021/acs.joc.6b02766
    Figure
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    Just Accepted Manuscripts

    Just Accepted manuscripts are peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. See all Just Accepted Manuscripts.

    An Atom-Economic Synthesis of Pentaleno[2,1-b]indoles via Tandem Cyclization of Alkynones Initiated by Aminopalladation

    Junjie Chen, Xiuling Han, and Xiyan Lu
    Publication Date (Web): January 14, 2017 (Article)
    DOI: 10.1021/acs.joc.6b02817
    Figure

    π-Conjugated Triazenes: Intermediates that Undergo Oxidation and Substitution Reactions

    Enrique Barragan and Alejandro Bugarin
    Publication Date (Web): January 13, 2017 (Article)
    DOI: 10.1021/acs.joc.6b02705
    Figure

    Gold-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Iodoalkynes: Access to (Z)-β-Iodoenol Esters and 1,4-Disubstituted (Z)-Enynyl Esters

    Pedro J. González-Liste, Javier Francos, Sergio Emilio García-Garrido, and Victorio Cadierno
    Publication Date (Web): January 13, 2017 (Article)
    DOI: 10.1021/acs.joc.6b02712
    Figure

    Azepinoindole Synthesis via a N-Bromosuccinimide-Induced Cycloisomerization of Enaminoester/Enaminone

    Lina Chang, Tao Guo, Ziyi Wang, Shaozhong Wang, and Zhu-Jun Yao
    Publication Date (Web): January 13, 2017 (Article)
    DOI: 10.1021/acs.joc.6b02760
    Figure

    A Useful Allene for the Stereoselective Synthesis of Protected Quaternary 2-Amino-2-Vinyl-1,3-diols

    Aleix Rodriguez, Xavier Ariza, Miguel A. Contreras, Jordi Garcia, Paul Lloyd-Williams, Nerea Mercadal, and Carolina Sánchez
    Publication Date (Web): January 13, 2017 (Note)
    DOI: 10.1021/acs.joc.6b02765
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    Current Issue

    The latest published issue of The Journal of Organic Chemistry. See all articles.

    Editorial for The Journal of Organic Chemistry

    Scott J. Miller (Editor-in-Chief)
    Publication Date (Web): January 6, 2017 (Editorial)
    DOI: 10.1021/acs.joc.6b03061
    Figure

    Domino Ring-Opening Cyclization of Activated Aziridines with Indoles: Synthesis of Chiral Hexahydropyrroloindoles

    Abhijit Mal, Masthanvali Sayyad, Imtiyaz Ahmad Wani, and Manas K. Ghorai
    Publication Date (Web): October 19, 2016 (Featured Article)
    DOI: 10.1021/acs.joc.6b01731
    Figure

    Triazole- and Tetrazole-Bridged Nucleic Acids: Synthesis, Duplex Stability, Nuclease Resistance, and in Vitro and in Vivo Antisense Potency

    Yasunori Mitsuoka, Tsuyoshi Yamamoto, Akira Kugimiya, Reiko Waki, Fumito Wada, Saori Tahara, Motoki Sawamura, Mio Noda, Yuko Fujimura, Yuki Kato, Yoshiyuki Hari, and Satoshi Obika
    Publication Date (Web): December 2, 2016 (Featured Article)
    DOI: 10.1021/acs.joc.6b02417
    Figure

    Synthesis and Properties of 7-Deazapurine- and 8-Aza-7-deazapurine-Locked Nucleic Acid Analogues: Effect of the Glycosidic Torsion Angle

    Takashi Hara, Tetsuya KodamaYumi Takegaki, Kunihiko Morihiro, Kosuke Ramon Ito, Satoshi Obika
    Publication Date (Web): December 13, 2016 (Featured Article)
    DOI: 10.1021/acs.joc.6b02525
    Figure

    A Stereoselective Route to Tetrahydrobenzoxazepines and Tetrahydrobenzodiazepines via Ring-Opening and Aza-Michael Addition of Activated Aziridines with 2-Hydroxyphenyl and 2-Aminophenyl Acrylates

    Chandan Kumar Shahi, Aditya Bhattacharyya, Yerramsetti Nanaji, and Manas K. Ghorai
    Publication Date (Web): October 5, 2016 (Article)
    DOI: 10.1021/acs.joc.6b01919
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    Most Read Articles

    Most Read articles are refreshed daily and are based on full text downloads (PDF and HTML) from the previous 30 days and previous 12 months. Below is a Top 5 excerpt from the previous 30 days.

    NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities

    Hugo E. Gottlieb, Vadim Kotlyar and Abraham Nudelman
    Publication Date (Web): October 17, 1997 (Note)
    DOI: 10.1021/jo971176v
    Figure

    Recent Advances in C–H Functionalization

    Huw M. L. Davies and Daniel Morton
    Publication Date (Web): January 15, 2016 (Editorial)
    DOI: 10.1021/acs.joc.5b02818
    Figure

    Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine

    Qi Zhou, Zhikun Zhang, Yujing Zhou, Shichao Li, Yan Zhang, and Jianbo Wang
    Publication Date (Web): December 6, 2016 (Article)
    DOI: 10.1021/acs.joc.6b01864
    Figure

    Recent Developments in Amide Synthesis Using Nonactivated Starting Materials

    Andrea Ojeda-Porras and Diego Gamba-Sánchez
    Publication Date (Web): November 8, 2016 (JOCSynopsis)
    DOI: 10.1021/acs.joc.6b02358
    Figure

    Photoredox Catalysis in Organic Chemistry

    Megan H. Shaw, Jack Twilton, and David W. C. MacMillan
    Publication Date (Web): August 1, 2016 (Perspective)
    DOI: 10.1021/acs.joc.6b01449
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    JOC Virtual Issues feature current research articles that are hand picked by ACS Editors. Virtual Issues are in areas of particular interest to the scientific community.

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    JOCSynopses are brief focused reviews of current topics of interest to organic chemists written by active researchers that include work from their own laboratories. JOCSynopses are invited or are submitted and screened before a formal review.

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