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Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents

Shu-Hua Zhang, Emma Carter, Hong-Wei Xi, Yongxin Li, Kok Hwa Lim, and Cheuk-Wai So*

Structure and Bonding Investigation of Plutonium Peroxocarbonate Complexes Using Cerium Surrogates and Electronic Structure Modeling

Lucas E. Sweet*, Jordan F. Corbey, Frédéric Gendron, Jochen Autschbach, Bruce K. McNamara, Kate L. Ziegelgruber, Leah M. Arrigo, Shane M. Peper, and Jon M. Schwantes

Design and Synthesis of Tris-Heteroleptic Cyclometalated Iridium(III) Complexes Consisting of Three Different Nonsymmetric Ligands Based on Ligand-Selective Electrophilic Reactions via Interligand HOMO Hopping Phenomena

Yosuke Hisamatsu, Sarvendra Kumar, and Shin Aoki*

Crystal Structure, Defects, Magnetic and Dielectric Properties of the Layered Bi3n+1Ti7Fe3n–3O9n+11 Perovskite-Anatase Intergrowths

Dmitry Batuk*, Maria Batuk, Dmitry S. Filimonov, Konstantin V. Zakharov, Olga S. Volkova, Alexander N. Vasiliev, Oleg A. Tyablikov, Joke Hadermann, and Artem M. Abakumov

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    Copper(II)–Silver(I) Macrocyclic Metal–Organic Framework: A Highly Efficient Reusable Triplet Oxygen Collector and Singlet Oxygen Generator

    Jian-Cheng Wang, Jing Yang, Shen-Qing Wang, Jian-Ping Ma, and Yu-Bin Dong
    Publication Date (Web): January 23, 2017 (Communication)
    DOI: 10.1021/acs.inorgchem.6b02918

    Synopsis

    A copper(II)−silver(I) bimetallic macrocycle that is a highly efficient reusable triplet oxygen receptor and singlet oxygen generator was reported.

    Figure

    Evolution of the Structural and Electronic Properties of Medium-Sized Sodium Clusters: A Honeycomb-Like Na20 Cluster

    Wei Guo Sun, Jing Jing Wang, Cheng LuXin Xin Xia, Xiao Yu Kuang, Andreas Hermann
    Publication Date (Web): January 20, 2017 (Article)
    DOI: 10.1021/acs.inorgchem.6b02340

    Synopsis

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    Figure

    Lactide as the Playmaker of the ROP Game: Theoretical and Experimental Investigation of Ring-Opening Polymerization of Lactide Initiated by Aminonaphtholate Zinc Complexes

    Dawid Jędrzkiewicz, Grażyna Adamus, Michał Kwiecień, Łukasz John, and Jolanta Ejfler
    Publication Date (Web): January 20, 2017 (Article)
    DOI: 10.1021/acs.inorgchem.6b02439

    Synopsis

    A family of homo/heteroleptic zinc complexes bearing aminonaphtholate ligands was synthesized and fully characterized. Surprisingly, a detailed experimental and theoretical ... Read Morestudy of catalytic activity [LZn(μ-OR)]2 in the ROP of lactides showed that although well-defined alkoxy dimers possess a single-site structural motif, the most active initiator is obtained during an in situ alcoholysis reaction of the alkylzinc precursor. These results indicate the potential of rational ancillary and alkoxy ligand design taking into account its mutual interaction on monomer coordination. Minimize
    Figure

    Green-to-Red Electrochromic Fe(II) Metallo-Supramolecular Polyelectrolytes Self-Assembled from Fluorescent 2,6-Bis(2-pyridyl)pyrimidine Bithiophene

    Sandesh Pai, Michael Moos, Maximilian H. Schreck, Christoph Lambert, and Dirk G. Kurth
    Publication Date (Web): January 20, 2017 (Article)
    DOI: 10.1021/acs.inorgchem.6b02496

    Synopsis

    Metallo-supramolecular polyelectrolytes based on Fe(II) and Co(II) metal ions were self-assembled from a novel 2,6-bis(2-pyridyl)pyrimidine bithiophene ligand. The introduction ... Read Moreof bithiophene spacer leads to tunable absorption and emission properties. Thin films of high optical quality are prepared by dip coating on ITO glass. The MEPE displays NIR electrochromism due to the charge delocalization in the bithiophene spacer. Minimize
    Figure

    Synthesis, Chemistry, and Electronic Structures of Group 9 Metallaboranes

    Rosmita Borthakur, Sourav Kar, Subrat Kumar Barik, Somnath Bhattacharya, Gargi Kundu, Babu Varghese, and Sundargopal Ghosh
    Publication Date (Web): January 20, 2017 (Article)
    DOI: 10.1021/acs.inorgchem.6b02626

    Synopsis

    Structural diversity in dimetallaoctaborane(12) derivatives of group 8 and 9 transition metals, [M2B6H10+x] (M = Ru, x = 2; M = Co, Rh, and Ir, x = 0).

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    Photocatalytic Oxidation of Bromide to Bromine

    Kelvin Yun-Da Tsai and I-Jy Chang
    Publication Date (Web): September 7, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b01652

    Synopsis

    The ruthenium(II) complex [Ru(deeb)2(dmbpy)]2+ efficiently photocatalyzes bromide oxidation to bromine and tribromide. The electronically excited ruthenium complex (*Ru) ... Read Morereacts first with ArN2BF4 to produce a ruthenium(III) (RuIII) intermediate, triggering a subsequent reaction with Br−. Without interference of back-electron transfer, Br2•− follows a bimolecular reaction to form Br2 and Br3−. Minimize
    Figure

    Slow Magnetic Relaxation in Weak Easy-Plane Anisotropy: the Case of a Combined Magnetic and HFEPR Study

    Yuan-Yuan ZhuFang Liu, Jia-Jia Liu, Yin-Shan Meng, Shang-Da Jiang, Anne-Laure BarraWolfgang Wernsdorfer, Song Gao
    Publication Date (Web): December 22, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b01972

    Synopsis

    Two mononuclear tetrahedral [Co(NCS)4]2− complexes display slow magnetic relaxation under an applied direct-current field. The weak easy-plane anisotropy is accurately ... Read Moredetermined by high-field/high-frequency electron paramagnetic resonance spectroscopy, and the hysteresis loops are observed at very low temperatures. Minimize
    Figure

    Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents

    Shu-Hua Zhang, Emma Carter, Hong-Wei Xi, Yongxin Li, Kok Hwa Lim, and Cheuk-Wai So
    Publication Date (Web): December 23, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b02427

    Synopsis

    The reaction of the amidinato silylsilylene 1 with ArN═C═NAr (Ar = 2,6-iPr2C6H3) in toluene afforded the delocalized hypervalent silyl radical 2.

    Figure

    Two Li–Zn Cluster-Based Metal–Organic Frameworks: Strong H2/CO2 Binding and High Selectivity to CO2

    Yong-Liang Huang, Di-Chang ZhongLong Jiang, Yun-Nan Gong, Tong-Bu Lu
    Publication Date (Web): December 29, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b02407

    Synopsis

    Two metal−organic frameworks have been constructed from Li−Zn clusters and pyrene-1,3,6,8-tetracarboxylic acid (H4PTCA) under solvothermal conditions. Gas sorption measurements ... Read Morehave revealed that the pore of desolvated 2 shows extremely strong binding to H2 and CO2 and highly selective adsorption of CO2 over N2 and CH4. Minimize
    Figure

    Estimating the Donor–Acceptor Distance To Tune the Emission Efficiency of Luminescent Lanthanide Compounds

    Jorge H. S. K. Monteiro, Ana de Bettencourt-DiasFernando A. Sigoli
    Publication Date (Web): December 22, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b02637

    Synopsis

    The donor−acceptor distance is the key parameter in the efficiency of sensitized europium(III) emission.

    Figure
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    Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties

    Constantinos C. Stoumpos, Christos D. Malliakas, and Mercouri G. Kanatzidis
    Publication Date (Web): July 8, 2013 (Article)
    DOI: 10.1021/ic401215x

    Synopsis

    The hybrid iodide perovskites of Sn and Pb have been long considered as puzzling compounds displaying a metal-like conductivity. The results demonstrated here provide ... Read Moresolid evidence for the semiconducting nature of this family of compounds that display high carrier mobilities and ambient temperature photoluminescence. Moreover, the compounds show tunable charge-transport and optical properties depending strongly on the preparation method. Minimize
    Figure

    Redox-Active Metallacarborane-Decorated Octasilsesquioxanes. Electrochemical and Thermal Properties

    Justo Cabrera-González, Víctor Sánchez-Arderiu, Clara Viñas, Teodor Parella, Francesc TeixidorRosario Núñez
    Publication Date (Web): November 10, 2016 (Communication)
    DOI: 10.1021/acs.inorgchem.6b02394

    Synopsis

    Polyanionic and electroactive hybrids based on octasilsesquioxanes bearing eight metallacarborane units are developed. The grafting of these metallacarboranes to octavinylsilsesquioxane ... Read More(OVS) produces an outstanding thermal stability on the final hybrids. Remarkably, these materials exhibit high solubility in organic solvents. Electrochemical studies show that the peripheral metallacarboranes act as independent redox units and simultaneously undergo the redox process, despite the rigid nature of OVS, providing insight into electron transfer in dendrimers. Minimize
    Figure

    Multifunctional Luminescent Eu(III)-Based Metal–Organic Framework for Sensing Methanol and Detection and Adsorption of Fe(III) Ions in Aqueous Solution

    Jian Wang, Min Jiang, Ling Yan, Ren Peng, Mengjie Huangfu, Xinxin Guo, Yang Li, and Pengyan Wu
    Publication Date (Web): November 30, 2016 (Article)
    DOI: 10.1021/acs.inorgchem.6b01815

    Synopsis

    A chiral MOF has been constructed that exhibits a size-selective response to methanol and is also a good on−off chemosensor for acetone molecule with especially high ... Read Moresensitivity. Moreover, it is able to effectively detect and adsorb Fe3+ ions, and a simple and portable test paper based on the MOF fluorescent sensor system provides convenient and reliable detection of Fe3+ in practical applications. Minimize
    Figure

    Confinement Effects of Metal–Organic Framework on the Formation of Charge-Transfer Tetrathiafulvalene Dimers

    Ting Chen, Peng Huo, Jin-Le Hou, Jing Xu, Qin-Yu ZhuJie Dai
    Publication Date (Web): December 2, 2016 (Article)
    DOI: 10.1021/acs.inorgchem.6b02062

    Synopsis

    A 3-D MOF with TTF and bpp ligands constructed from tetranuclear Cd(II)-O cluster nodes exerts a confinement effect on the formation of TTF dimers, which shows enhanced photocurrent response property.

    Figure

    Adsorption of Iodine Based on a Tetrazolate Framework with Microporous Cages and Mesoporous Cages

    Zhi-Qiang Jiang, Fei WangJian Zhang
    Publication Date (Web): December 1, 2016 (Article)
    DOI: 10.1021/acs.inorgchem.6b02696

    Synopsis

    A three-dimensional tetrazolate framework was synthesized with solvothermal reaction. Single-crystal X-ray diffraction analysis shows that the framework is fabricated ... Read Moreby a microporous cage (1.35 nm) and mesoporous cage (2.85 nm) via vertex-sharing packing mode. Minimize
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