SAFETY--Water Resources Division National Pollutant Discharge Elimination System Safety Policy and Guidance In Reply Refer To: Mail Stop 405 Aug. 10, 1992 WATER RESOURCES DIVISION MEMORANDUM NO. 92.54 Subject: SAFETY--Water Resources Division National Pollutant Discharge Elimination System Safety Policy and Guidance The Water Resources Division (WRD) has been contacted by more than 20 cities requesting our assistance in monitoring urban stormwater runoff. The monitoring is required in order for the cities to obtain a National Pollutant Discharge Elimination System (NPDES) Permit from the U.S. Environmental Protection Agency. Additional cities and some military installations are in the process of formalizing agreements with WRD for NPDES-type monitoring work. The attached WRD NPDES Safety Policy and Guidance has been developed to assist in protecting the safety of all WRD personnel. The Protocol will be effective as of the date of this memorandum. It is the responsibility of managers and supervisors to ensure that the safety procedure and guidance prescribed in this document are followed for all NPDES and NPDES-type projects. The document was prepared by the WRD Safety Subcommittee on NPDES. The Subcommittee consists of G.J. Hwang, Joanne Kurklin, Carlos Arozarena, and John Neil. If you have any questions regarding this document and its implementation, please contact G.J. Hwang, the Subcommittee Chairman and WRD Safety Officer, at (703) 648-5255. William B. Mann IV Attachment Distribution: A,B,S,FO,PO This memorandum does not supersede any previous WRD memorandum. KEY WORDS: Hazardous Waste Sites, Safety U.S. GEOLOGICAL SURVEY, WATER RESOURCES DIVISION, NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM-- SAFETY POLICY AND GUIDANCE Prepared by The Water Resources Division Safety Subcommittee on Safety in NPDES Operations Subcommittee Members G.J. Hwang Joanne K. Kurklin Carlos E. Arozarena John M. Neil This Safety Policy and Guidance is for the administrative use of Members of the Water Resources Division, U.S. Geological Survey. It should not be quoted or cited as a publication. U.S. GEOLOGICAL SURVEY, WATER RESOURCES DIVISION, NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM-- SAFETY POLICY AND GUIDANCE CONTENTS Page CONTENTS 1 1. INTRODUCTION 5 A. General Statement 5 B. Legal and Regulatory Perspective 5 C. Responsibility 6 2. SAFETY PROGRAM PLANNING 6 A. Planning Requirements 6 B. Safety Organization 6 C. Safety Plan 6 3. MEDICAL SURVEILLANCE PROGRAM 7 A. Legal Requirements 7 B. Medical Program Elements 8 (1) Initial Consideration 8 (2) Initial Screening Test 8 (3) Initial Baseline Medical Examination 8 (4) Immunization Requirements 9 (5) First-Aid Provisions 9 (6) Periodic or Followup Medical Examinations 10 (7) Exit Medical Examination 10 (8) Recordkeeping 10 4. SITE CHARACTERIZATION 11 A. Offsite Reconnaissance 11 B. Onsite Survey 11 (1) NPDES Sites 11 (2) NIOSH Confined Space Classification 12 (3) ANSI and ASSE Confined Space Classification 13 (4) Hazard Recognition 13 C. Site Inventory 16 (1) WRD NPDES Site Classification 16 (2) WRD NPDES Site Inventory 16 D. Site Entry Procedures 16 (1) Job Hazard Analysis 16 (2) Entry Permit 17 (3) Atmospheric Testing 19 (4) Monitoring 22 (5) Labeling and Posting 23 E. Hazard Controls 23 (1) Controlling Atmospheric Hazards 23 (2) Controlling Ignition Sources 24 (3) Safe Use of Equipment and Tools 24 5. STANDARD OPERATING PROCEDURES 25 A. Requirements 25 B. WRD NPDES Standard Operating Procedures 26 (1) WRD NPDES Class "A" Site 26 (2) WRD NPDES Class "B" and Class "C" Sites 26 (3) WRD NPDES Class "D" Site 26 (4) Personnel 26 (5) Monitoring Site Conditions 27 6. TRAINING PROGRAM 28 A. Objectives 28 B. Requirements 28 C. Training Courses 29 D. Training Certification 30 E. Training Plan and Recordkeeping 30 7. LABORATORY SAFETY 30 A. Introduction 30 B. Collecting and Processing Samples 31 C. Packaging and Labeling Samples 32 D. Analytical Service Request 32 E. Laboratory Handling of Sample Bottles 32 F. Sample Disposal Procedures 33 8. SPILL CLEAN-UP PROCEDURES 33 9. HAZARDOUS MATERIALS AND WASTE DISPOSAL 33 10. CONCLUSION AND RECOMMENDATIONS 34 REFERENCES 35 APPENDIXES A. WRD NPDES SCREENING TEST FORM 36 B. WRD NPDES SITE INVENTORY FORM 39 C. WRD JOB HAZARD ANALYSIS FORM 41 D. WRD CONFINED SPACE ENTRY PERMIT FORM 43 U.S. GEOLOGICAL SUREY, WATER RESOURCES DIVISION, NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM-- SAFETY POLICY AND GUIDANCE 1. INTRODUCTION A. General Statement To control stormwater runoff quality in compliance with Section 402(p) of the Water Quality Act of 1987, 24 large- (those with a population exceeding 250,000) and medium-sized (those with a population exceeding 100,000) cities have requested that the Water Resources Division (WRD) provide the urban stormwater monitoring assistance needed to obtain a National Pollutant Discharge Elimination System (NPDES) permit from the U.S. Environmental Protection Agency (USEPA). Additional cities and military installations will probably seek similar assistance from the WRD for the NPDES-type monitoring work in the near future. (For convenience, "NPDES" will be used hereafter to refer to "NPDES and NPDES type".) Specifically, NPDES investigations require WRD personnel to work in unsafe urban environments at potentially hazardous sites. NPDES project sites may include sewer inlets and outfalls, stormwater ponds, sewer pipes, natural or manmade open channels, culverts, and manholes. Some of these sites are designated as "confined space" by the Occupational Safety and Health Administration (OSHA), requiring special safety procedures set forth in the OSHA regulations (OSHA 29 CFR #1910.146). To comply with the OSHA regulations and to be in accordance with the U.S. Geological Survey (USGS) Director's memorandum dated February 7, 1992, on the USGS Safety and Occupational Health Program (Ref. A), this Safety Policy and Guidance has been developed. The purpose is to establish minimum safety and health requirements and procedures for the WRD personnel working at NPDES project sites. B. Legal and Regulatory Perspective This Safety Policy and Guidance is intended to comply with the most recent Federal environmental and safety regulations relevant to NPDES project sites and the USGS safety policy on confined space (Ref. B). The Federal regulations shall be considered to be the minimum requirements because State and local jurisdictions may have elected to administer stricter environmental and safety regulations. Federal agencies are required to abide by the State and local regulations in these instances. However, this Safety Policy and Guidance does not attempt to address or cover all the different permutations that site-specific conditions and State and local regulations will create. C. Responsibility It is the responsibility of managers and supervisors to ensure that the safety procedures and guidance prescribed in this Safety Policy and Guidance along with the applicable Federal, State, and local regulations be followed for all NPDES projects. In addition, they need to document that all personnel working at NPDES project sites have the required training, medical surveillance, and safety equipment as stipulated in this Safety Policy and Guidance. 2. SAFETY PROGRAM PLANNING A. Planning Requirements Development of an adequate safety organization and strict adherence to a rigorous safety plan are the most critical and essential elements for safe site operations. B. Safety Organization An adequate safety organization shall include a Project Chief, who has the responsibility for the overall project's safety program, and a Project Safety Officer designated by the Project Chief to implement the safety program. In addition, each site must designate a Site Safety Officer to implement the safety program at the site. For smaller projects, the Project Chief can be the Project Safety Officer and the Site Safety Officer. C. Safety Plan Based on this Safety Policy and Guidance, a safety plan shall be developed by the Project Chief or the Project Safety Officer or both to establish the overall safety operational procedures. A safety plan shall consist of the following elements and documents: (1) Copy of this Safety Policy and Guidance (emphasis on the Standard Operating Procedures Section) (2) Medical Program and documentation (3) Written project site inventory (4) Written project site entry procedure (5) Training program and documentation (6) Written sample shipping and storage procedure (7) Written guide for laboratory safety (8) Written spill cleanup plan (9) Written material and waste-disposal procedure 3. MEDICAL SURVEILLANCE PROGRAM A. Legal Requirements A medical surveillance program is essential to assess and monitor the health and fitness of the project personnel, to provide emergency treatment, and to keep records for future reference. In a memorandum dated May 29, 1979, the USGS instituted a medical surveillance program for personnel exposed to on-the-job health hazards (Ref. C). As the first step in implementing the medical surveillance program, it is essential that those personnel who are or might be exposed to a host of hazardous substances or conditions or both in the work environment be identified. After consulting with the U.S. Department of the Interior (DOI) Medical Director, a determination was made that the risk of exposure of NPDES project personnel to certain on-the-job health hazards is great and that a proper medical surveillance program should be required. Consequently, in a memorandum dated January 22, 1992, the DOI Medical Director recommended specific medical requirements regarding WRD personnel working at NPDES project sites (Ref. D.) The WRD has adopted the DOI Medical Director's recommendations and developed the following medical surveillance program: B. Medical Program Elements (1) Initial Consideration The immediate step after the identification of those personnel who will be part of an NPDES project team is to brief them on the nature of the hazards of working at the project sites and to find out if anyone is medically fit to work on the project sites by the following medical measures: (2) Initial Screening Test (a) To ensure NPDES project personnel are not suffering from any form of phobias, particularly when working at NPDES sites, the WRD NPDES Screening Test Form (Appendix A), which was prepared by the DOI consulting psychologist, shall be used as a screening instrument. This form shall be completed by all NPDES field personnel prior to an assignment to an NPDES site. (b) The completed Screening Test Form shall be forwarded to the WRD Safety Officer who will forward it through the Office of Personnel to the DOI Medical Director for evalution and recommendation by the consulting psychologist. Employees will be evaluated before requiring them to work at project sites. (c) It should be noted that the Psychological Evaluation results cannot and should not be utilized as a condition of participation in a NPDES project other than a field assignment. (3) Initial Baseline Medical Examination (a) To evaluate the ability to carry out the assigned duties and to detect any diseases or abnormalities which may make it difficult to work at NPDES sites, all NPDES field personnel shall have an initial Baseline Medical Examination by a licensed physician experienced in occupational medicine. The Examination shall include, but not be limited to, resting electrocardiogram and pulmonary function studies. It shall also include the following tests: (i) Laboratory tests shall include complete blood count and differentials, liver and kidney function profiles, and urinalysis. In addition, plasma and red cell cholinesterase shall also be included because of the high probability that NPDES personnel could be exposed to phosphate contaminants. (ii) Respirator fit testing shall be conducted to demonstrate the ability to use positive pressure respirators as cited in the OSHA regulations (OSHA 29 CFR #1910.134). (iii) Vision and audiometric tests shall be conducted to demonstrate the ability to see and hear warnings, such as flashing lights, buzzers, or sirens. (b) The completed Baseline Medical Examination results shall be forwarded to the WRD Safety Officer who will forward them through the Office of Personnel to the DOI Medical Director for his evaluation and recommendation. Employees will then be evaluated as to their medical fitness to working at project sites. (4) Immunization Requirements Because of the nature of the worksite environment, all NPDES field personnel shall have an update of their tetanus immunizations and hepatitis B shots, including administration of gamma globulin; if they could be exposed to human waste then an update of their typhoid immunization is recommended. (5) First-Aid Provisions (a) NPDES field personnel shall be currently trained and certified in CPR and basic first-aid procedures. (b) NPDES field personnel shall be aware of the location of the nearest first-aid equipment and how to obtain emergency assistance and medical attention. (6) Periodic or Followup Medical Examinations (a) A periodic or followup medical examination shall be conducted at least every 12 months or when recommended by the DOI Medical Director or examining physician who administered the initial Baseline Medical Exam- ination. The examinations shall be an update of medical and occupational history, a physical examination, and testing based on examination results, exposures, and job class and task. More or less frequent testing may be required on the basis of specific exposures. (b) All periodic or followup medical examination results shall be forwarded to the DOI Medical Director through channels following the same procedures as the Baseline Medical Examination results. (7) Exit Medical Examination A full medical examination shall be conducted when field personnel are reassigned or separated. However, a less-than- full medical examination may be conducted if the last full examination was within the last 6 months, no exposure occurred since the last examination, and no symptoms associated with exposure occurred since the last examination. (8) Recordkeeping All medical records and data pertaining to NPDES Medical Surveillance Program, including records of exposure to known health hazards, shall be filed in employee medical folders maintained by the servicing personnel office. The OSHA regulations (OSHA 29 CFR #1904 and #1910.20) mandate that unless a specific occupational safety and health standard provides a different time period, Federal agencies must: (a) Maintain and preserve medical records on exposed workers for 30 years after separation. (b) Make available to workers their full medical records. (c) Maintain records of occupational injuries and illnesses and post a yearly summary report. 4. SITE CHARACTERIZATION A site characterization shall be conducted by the Project Chief or designated project personnel to identify specific hazards at or near the site and to determine the appropriate safety and health control procedures needed to protect personnel from the identified hazards when working at the site. It consists of the following measures: A. Offsite Reconnaissance Prior to entering a project site, a reconnaissance outside the site perimeter shall be conducted to gather information about the site and its accessibility, potential hazards, pathways for hazardous substances (including offsite sources of hazardous materials and paths by which they could be transported to the site), and locations of medical facilities, fire stations, and police stations. The purpose is to develop safe procedures for conducting an onsite survey. B. Onsite Survey To supplement information from the offsite reconnaissance, an onsite survey without site entry shall be conducted on the premises, or operations or both and shall include a general site hazard assessment and site classification. The purpose is to develop project site inventory and project site entry procedures before commencing any site entry. (1) NPDES Sites All NPDES project sites are either a confined or a nonconfined space. A confined space is any area that by design, has restricted openings for entry and exit, has hazardous atmosphere that could contain or produce dangerous air contaminants, and that is not intended for continuous human occupancy. Examples of confined spaces on NPDES sites include sewers, sewer manholes, most sewer inlets and outfalls, and some culverts. Most other NPDES sites, such as natural or manmade open channels and stormwater ponds, are considered to be nonconfined spaces. (2) NIOSH Confined Space Classification The National Institute for Occupational Safety and Health (NIOSH) has recommended the following classification of confined spaces (Ref. E): (a) Class "A" This space presents situations that are immediately dangerous to life or health (IDLH). The NIOSH Pocket Guide to Chemical Hazards (Ref. F) defines IDLH concentration as the "...maximum level from which one could escape within 30 minutes without any escape- impairing symptoms or any irreversible health effects..." These include, but are not limited to, oxygen deficiency or enrichment with an oxygen concentration of less than 16 or greater than 25 percent, explosive or flammable atmospheres exceeding 20 percent of lower flammable limit (LFL), and toxic substances reaching IDLH exposure concentrations. Rescue procedures require the entry of at least two trained individuals fully equipped with life support equipment. Maintenance of communication requires an additional standby person stationed within the confined space. (b) Class "B" This space presents situations that have the potential for causing injury and illness if preventive measures are not used but not immediately dangerous to life and health. These include, but are not limited to, oxygen content between 16.1 and 19.4 percent or between 21.5 and 25 percent, flammable atmosphere of between 10 and 19 percent of LFL, and toxicity greater than contamination level referenced in the OSHA standard (OSHA 29 CFR #1910.Z) and less than IDLH. Rescue procedures require the entry of only one trained individual fully equipped with life support equipment. Indirect visual or auditory communication with employee(s) is required. (c) Class "C" This space presents situations in which the potential hazards would not require any special modifications of the work procedure. These include, but are not limited to, oxygen content of between 19.5 and 21.4 percent, flammable atmosphere of less than 10 percent of LFL, and toxicity of less than contamination level referenced in OSHA standard (OSHA 29 CFR #1910.Z). Direct communication with employee(s) from outside the confined space is required. (3) ANSI and ASSE Confined Space Classification American National Standard Institute, Inc. (ANSI) and American Society of Safety Engineers (ASSE) have recommended the following classification of confined spaces (Ref. G): (a) Nonpermit Confined Space A space that, by configuration, meets the definition of a confined space but, after evaluation, is found to have little potential for generating hazards or has the hazards potential eliminated by engineering controls. (b) Low-Hazard Permit Space A space where the likelihood that an IDLH or engulfment hazard could be present is extremely low and where all other serious hazards have been controlled. However, a written entry permit is required. (c) Permit-Required Confined Space A space that after evaluation, has actual or potential hazards that require written authorization for entry. (4) Hazard Recognition Special Hazards in most NPDES sites include, but are not limited to, the following: (a) Some toxic vapors, gases, liquids, and dusts including carbon monoxide, hydrogen sulfide, sulfur dioxide, and methane, in excess of their permissible exposure limit. (b) Flammable gases or liquids in excess of 20 percent of the LFL or lower explosive limit (LEL). (c) A lack of (less than 19.5 percent) or excess of (greater than 21.4 percent) oxygen may cause asphyxiation or increased fire hazard. (d) Wastes from hospitals and research facilities may contain disease-causing microorganisms, including human immunodeficiency virus. Etiologic agents may be dispersed by means of water and wind. Other biologic hazards include pathogens and leakage of sanitary sewage into storm-drain systems. (e) Heat stress is a major hazard, especially when wearing protective clothing. The same protective materials that shield the body from chemical exposure also limit the dissipation of body heat and moisture. Depending on the ambient conditions and the work being performed, heat stress can occur in as little as 15 minutes and can pose as great a danger to health as chemical exposure. Heat stress can cause heat rash, heat cramp, heat exhaustion, and heat stroke. (f) Inability to readily get into or out of the confined space as a result of the location or size of openings or both. (g) Most NPDES sites are located in urban areas where workers can fall victim to urban crimes and associated violence and where heavy traffic creates dangerous working environments with potentially fatal motor vehicle accidents. (h) Most NPDES personnel are required to work during wet-weather, severe-storm events. Workers are exposed to extreme hazardous conditions that can lead to accidents, such as slipping, falling, and tripping. (i) NPDES personnel are required to work in areas in which ionizing radiation is present. The three most likely sources of this radiation are illegal disposal of radioactive waste into storm drains, dumping of stolen sources (for example, a neutron moisture probe), and the accumulation of radon in cement storm-drain systems. The first two sources are unlikely to produce significant employee exposures during a storm-sampling event because the high flows will significantly dilute any radioactive waste in the system. However, the first two sources could produce some exposure during low-flow conditions if personnel work at the site for extended periods of time. If the site survey identifies possible sources (for example, hospitals, analytical laboratories, manufacturing facilities, and so forth) of radioactive material upstream from the site or if the cooperator has detected radioactive material at the site in the past, then a radiation meter shall be used to check for above-background levels of radiation. If radiation is present, then personnel working at the site shall be provided with radiation monitoring (for example, film badges), and the radiation meter will be used each time the site is occupied. The results of personnel monitoring shall be maintained with the medical records, and in the unlikely case that an employee receives more than the permitted annual dose or single exposure, that employee will not be allowed to continue working at that site. USEPA regulations require action if more than 4 picocuries of radon are present in a confined space. This level of radon has been documented in poorly ventilated, cement-enclosed spaces and can only be measured with special monitoring equipment that collects data for extended periods of time. C. Site Inventory (1) WRD NPDES Site Classification An inventory of project sites to be entered by its project personnel shall be developed and maintained after an onsite survey is completed. Each site on the inventory shall be classified according to the NIOSH classification of Class "A", Class "B", and Class "C"; an additional WRD classification of Class "D" shall be used to identify nonconfined space sites. (2) WRD NPDES Site Inventory The inventory shall include, but not be limited to, the following information: (a) Site ID and Location (b) Site Classification (c) Site Description (d) Access or Entry Pathway (e) Known or Potential Hazards (f) Entry Permit Status A WRD NPDES Site Inventory Form is provided in Appendix B. D. Site Entry Procedures (1) Job Hazard Analysis A formal written job hazard analysis (JHA) shall be performed for each NPDES job and site, and all personnel working at that site shall be briefed on the JHA prior to entry. A JHA is a procedure for documenting hazards associated with a specific job or assignment and for identifying actions needed to avoid accident or injury. A WRD JHA Form is provided in Appendix C. Each JHA must address the following elements: (a) The job activity or task. (b) A breakdown of the basic job steps or tasks describing what is done, not how it is done. (c) Hazards associated with each job step. (d) Safe job procedures and precautions required to alleviate the hazard. (2) Entry Permit (a) Entry to nonconfined space sites (Class "D") requires no entry permits. Entry permits shall be prepared and issued by the Project Chief for all confined space sites (Classes "A", "B", and "C") prior to each entry. A WRD Confined Space Entry Permit Form (Appendix D) has been developed for use in NPDES projects. The entry permit shall contain the following: (i) Project Job and Site --Project office --Entry and permit time and duration --Job location and description --Site description and classification (ii) Project Personnel --Project Chief and Safety Officer --Entry and other assigned personnel --Other entry supporting personnel --Rescue personnel (iii) Hazard Recognition --Oxygen deficiency --Flammable and explosive materials --Toxic and corrosive materials --Other safety problems and hazards (iv) Safety Equipment --Personal protective equipment --Respirators --Shields --Lighting --Fire Extinguishers --Safety lifelines and harness --Other (v) Testing and Monitoring Equipment (vi) Rescue and Escape Equipment --Tripod emergency escape unit --Escape lifelines and harness --Resuscitator and inhalator (vii) Communications Equipment (viii) Atmospheric Testing and Monitoring --Initial atmospheric test readings for oxygen level, flammability or explosive levels or both, and toxicity levels --Atmospheric monitoring while work is being performed (ix) Emergency and Rescue Plan --Emergency rescue procedures --Location of first-aid equipment --Emergency telephone numbers (b) The original of an entry permit shall be posted at the site, with copies being distributed to the project office and to project files. (c) The entry permit for a job site shall be dated and carry an expiration time that will be valid for one entry only. The permit shall be updated for each subsequent entry with the same requirements. However, the entry permit may be valid for multiple entries for the duration of the job at that site if the following conditions are met: (i) The conditions in the confined space have no known potential for presenting either an atmosphere that is IDLH or an engulfing condition. (ii) Acceptable conditions for entry are validated by inspection and atmospheric testing each time the site is occupied. (iii) No new process or procedure will be conducted if it is not covered under the original entry permit. (d) An entry permit that is valid for up to 1-year may be issued in operation where workers are required to make routine, repetitive entry into confined spaces that have no known potential for presenting an atmosphere that is IDLH or an engulfment condition or both. Specific practices and procedures must be established and followed. Atmospheric conditions must be tested prior to entry. (e) All personnel must be immediately withdrawn from the confined space and entry permits shall be voided if inspection and atmospheric testing indicate that a condition exists that poses a threat to the personnel or that conditions outside the space could pose a hazard to personnel on the inside. After abatement of these hazards, a new permit must be obtained before reentering the confined space. (3) Atmospheric Testing (a) Purpose Except for Class "D" sites, atmospheric testing shall be conducted to identify any IDLH and other dangerous conditions, such as flammable or explosive atmospheres, oxygen-deficient environments, and highly toxic levels of airborne contaminants. Most atmospheric hazards are invisible and can develop anytime; therefore, different test equipment, including oxygen meters, combustible gas indicators, flame ionization detectors, photoionization detectors, colorimetric indicator tubes, and organic vapor monitors, must be used during the entire entry process. Testing sequence shall be oxygen, flammability, and toxicity. (b) General Guidelines (i) If possible, begin testing without disturbing the space. (ii) Test from top to bottom and around ductwork and uneven surfaces. (iii) Avoid leaning over the space being tested. (iv) Allow time for the sample to reach the sensors in the equipment. (v) If test equipment is lowered into a hazardous atmosphere, then make sure it is rated for that environment (it must be intrinsically safe). (c) Measuring Oxygen (i) Oxygen is measured in percent by volume. (ii) Air is made up of approximately 21 percent oxygen at sea level. (iii) Oxygen can be used up by people, combustion, and other natural and manmade processes. (iv) Oxygen can be displaced by other gases and vapors. (v) Because low or high oxygen concentrations can affect flammability readings, test oxygen first. (vi) Lack of oxygen can lead to brain damage or death. (vii) Because oxygen starvation can bring on a feeling of happiness or well being called "euphoria," employees tend to be unaware of being in danger. (d) Detecting Flammable Gases and Vapors (i) At the LEL, a vapor/air mixture will explode if a spark or flame is added. (ii) When a vapor/air mixture is below the lower explosive limit, it is too lean to burn; when it is above the upper explosive limit, it is too rich to burn. (iii) Vapor/air mixtures between the lower and upper explosive limits are in the flammable range. (iv) Standard flammable-gas detectors read flammable gases and vapors as a percentage of the LFL or LEL. (v) Percentage LEL detectors are not designed to detect conditions in or above the flammable range accurately. However, they will indicate that the lower explosive limit has been exceeded. (vi) There is equipment designed to detect gases and vapors in and above the flammable range. (vii) Flammable gases, such as methane, can be created by the decay of organic matter. (e) Detecting Toxic Gases and Vapors (i) Because universal toxic gas detectors are not available at this time, testing personnel must know the specific toxic gas to be detected. (ii) Most electronic toxic gas detectors detect carbon monoxide or hydrogen sulfide or both. (iii) Most toxics must be measured in parts per million or parts per billion. (iv) A concentration of a gas or vapor will be toxic long before it is flammable. (v) Carbon monoxide will combine with human blood more readily than will oxygen. (vi) Hydrogen sulfide will cause olfactory fatigue. The nose will lose its ability to smell the gas, even though it is present in the space. (f) Testing equipment shall be selected for its functional ability to measure hazardous concentrations. Calibration of the instruments shall be conducted in accordance with the manufacturer's guidelines or manuals. Each calibration shall be recorded, filed by the employer, and available for inspection for 1 year after the last calibration date. (g) When the contaminants in the atmosphere cannot be kept within permissible exposure levels as set forth in OSHA 29 CFR #1910.Z, then the employee shall wear a NIOSH- and Mine Safety and Health Administration- approved respirator that shall be fitted and maintained in accordance with OSHA 29 CFR #1910.134. In addition, only fully trained personnel may use a respirator, and only positive-pressure, atmosphere-supplying respirators are permitted. (4) Monitoring A Class "A" site shall be monitored on a continuous basis. All Class "B" and Class "C" sites shall be monitored periodically to include at least a followup and an exit testing after the initial testing. Equipment for continuous monitoring shall be explosion proof and equipped with an audible alarm or danger signaling device that will alert employees when a hazardous condition develops. All monitoring results shall be recorded on the permit. (5) Labeling and Posting (a) All entrances to any confined space shall be posted as follows: DANGER CONFINED SPACE ENTRY BY PERMIT ONLY (b) When specific work is performed or safety equipment is necessary, the following warning signs shall be added: RESPIRATORS REQUIRED FOR ENTRY LIFELINE REQUIRED FOR ENTRY (c) Emergency procedures, including telephone numbers of fire departments and emergency medical services, shall be posted conspicuously within the immediate area of the confined space or at the telephone from which help would be summoned. E. Hazard Controls (1) Controlling Atmospheric Hazards Atmospheric hazards are created in confined spaces by natural and manmade processes, such as welding, decaying plants and animals, painting, cleaning with solvents, and fumigating. Controls vary from good housekeeping to purging and ventilation. (a) Purging Prior to entry, purging with air to displace the air in a confined space site. (b) Ventilation After entry, fresh air shall be circulated through the space to supply fresh air to breathe, to remove potentially hazardous conditions before they become hazardous, and to supply cool air for comfort. A ventilation system may be a forced air system or an exhaust system or a combination of the two. (2) Controlling Ignition Sources The sources include open flames, heat-producing equipment, spark-producing tools, broken lightbulbs, damaged electrical cords, and any ungrounded metal equipment. Bonding and grounding can eliminate the chance of a static spark in a potentially flammable atmosphere. (3) Safe Use of Equipment and Tools (a) Portable electric tools shall be approved in accordance with OSHA 29 CFR #1910.S and be equipped with a ground fault circuit interrupter that meets the OSHA requirements (OSHA 29 CFR #1910.309). All electrical cords, tools, and equipment shall be of a heavy- duty type with heavy-duty insulation and be inspected for visually detectable defects before use. Electrical lines, junctions, and accessories shall be in accordance with National Electrical Code and National Fire Code (Ref. H) as cited in OSHA 29 CFR #1910.309. (b) Air-driven power tools shall be used when flammable liquids are present. The use of such tools will only reduce the risk of explosion, not eliminate it. (c) Lighting used shall be of explosion-proof design and be equipped with guards. Lighting shall not be hung by electric cords unless specifically designed for that purpose. Illumination of the work area shall be sufficient to provide for safe work conditions, and under no circumstances shall matches or open flames be used for illumination. (d) Cylinders of compressed gases shall never be taken into a confined space except when they are part of self- contained breathing apparatus or resuscitation equipment. Only hose lines and components designed especially for the compressed gas and working pressure shall be used, and such systems shall have a pressure relief valve outside the confined space. (e) Ladders shall be adequately secured or be of a permanent tyupe that provides the same degree of safety as cited in OSHA 29 CFR #1910.D. Use ladders equipped with safety feet; set ladders at the correct angle and tie ladders off at the top. Do not use a metal ladder when working around electricity, and use fall-arresting devices whenever the potential for a fall exists. (f) Scaffolding and staging shall be properly designed to carry a maximum expected load (safety factor of 4), be equipped with traction type planking, and meet the OSHA requirements (OSHA 29 CFR #1910.28). (g) Protective clothing can make movement difficult. It also might cause personnel to become overheated quickly. Drink plenty of liquids, even in cold weather. (h) Noise might keep personnel from hearing an alarm. It also could interfere with communication between employees. Maintain good visual contact, or use some other method of communication. 5. STANDARD OPERATING PROCEDURES A. Requirements The following WRD NPDES standard operating procedures (SOP) have been adopted to provide instructions on how to accomplish specific tasks in a safe manner and to supplement or complement or both existing WRD safety procedures when working at all NPDES sites. Any deviations from the SOP must be approved in advance by the WRD Safety Officer. All NPDES personnel involved in site activities must have copies of the SOP and be briefed on their use by the Project Chief or Safety Officer. B. WRD NPDES Standard Operating Procedures (1) WRD NPDES Class "A" Site (a) No WRD personnel shall enter this site without authorization from the project office chief. (b) As an alternative, contractors shall be called in to perform any necessary work within this site and shall be informed of potential hazards with this site. (2) WRD NPDES Class "B" and Class "C" Sites (a) Entry can only be made by authorized and trained employees listed on the permit if authorized by the Project Chief. (b) Permit must be completed in full. (c) For a Class B site, a minimum of two employees, and, for a Class C site, two employees shall be assigned-- one as an authorized entrant and one or more as attendant(s)--to maintain constant visual and audio contact. (d) Attendant(s) shall have a radio or other communication with the project office. (e) The project office shall be notified when entry is made and when completed. (3) WRD NPDES Class "D" Site (a) Entry can be made by one employee without standby attendants and requires no entry permit. (b) The project office shall be notified when entry is made and when completed. (4) Personnel (a) All entry and standby personnel shall be properly trained, have current fit tests and medical surveillance, and be in the same level of personal protective equipment. (b) The "buddy" system shall be in effect for all permit-required entries. It requires standby personnel to be present and to be in constant communication with the entry personnel. It also requires the addition of new standby personnel each time an existing standby employee makes entry. (c) Under no circumstances shall standby personnel make entry to resuce entry personnel if there are no other standby personnel present at the site. Any rescue shall be executed by properly trained rescue personnel. (d) Standby personnel shall be in communication with entry personnel and the project office at all times during entry and egress of entry personnel. Lines of communication shall be established prior to all entries. (e) Standby personnel shall have the rescue equipment needed to remove the entry personnel through the use of mechanically assisted devices and shall ensure that ventilation and rescue equipment remain functional during entry and egress of the entry personnel. (5) Monitoring Site Conditions (a) All NPDES permit-required sites shall be evaluated for oxygen deficiency, LEL, and specific air contaminants utilizing properly functioning, properly calibrated equipment fitted with remote probes designed to provide data before physical entry by personnel. (b) Oxygen level testing shall precede all other testing. Acceptable levels are established as those greater than 19.5 percent. It is recognized that low oxygen levels will result in inaccurate LEL determinations. Entry into oxygen-deficient sites is prohibited until levels are increased and stabilized above 19.5 percent by ventilation. (c) Lower explosive levels shall be collected by utilizing a remotely probed instrument prior to entry where there is suspicion that flammable gases are present. Acceptable levels are established as those levels that are less than 10 percent of the LEL. (d) Special air monitoring shall be conducted for such contaminants as methane, carbon monoxide, and hydrogen sulfide. Continuous ventilation shall be required to provide fresh air and for the removal of contaminants. Entry into sites having unknown contaminants shall require supplied air respirators with a self-contained breathing apparatus as the minimum. (e) Those sites with egress problems shall require escape respirators in addition to the supplied air systems. All escape respirators shall be of the self-contained type. All rescue harnesses shall be of a type that will facilitate removal in a position similar to that of the entry. 6. TRAINING PROGRAM A. Objectives The training program has been developed to make workers aware of the potential hazards, to provide the knowledge and skills necessary to perform the work with minimal risk, to make workers aware of the purpose and limitations of safety equipment that they will be using, and to ensure that workers can safely avoid emergency situations and escape if one occurs. B. Requirements To comply with the legislation and OSHA Regulations and to be in accordance with the USGS policy on confined space entry procedures, the WRD policy requires that all NPDES field personnel must have as a minimum an initial 32-hour training course that includes a 24-hour basic NPDES site safety training and 8-hour basic first-aid and CPR training. The 8-hour basic first-aid and CPR training shall be conducted locally at each project office by the Red Cross or an equivalent. The WRD will provide the 24-hour initial basic site safety training course through the National Training Center (NTC) in Denver for all NPDES field personnel. The NTC course will be conducted annually by a contractor selected through competitive processes. If the basic site safety training course is to be given by someone other than the one contracted by the NTC, then the course syllabus will need approval by the WRD Safety Officer. In addition, at each project office, the Project Chief or the Project Safety Officer or both shall provide a 4-hour annual onsite refresher site-specific training. C. Training Courses Training courses shall include, but not be limited to the following: (1) WRD NPDES Project Safety Policy and Guidance (2) WRD NPDES Standard Operation Procedure (3) WRD NPDES Site Classification (4) WRD NPDES Site Entry Permit System (5) WRD NPDES Medical Surveillance Program (6) First-Aid and CPR (7) Handling Emergencies and Self-Rescue (8) Safe Work Practices (9) Hazard Recognition, Evaluation, Analysis, and Control (10) Use of Instruments to Measure Explosivity, Oxygen Deficiency, Flammability, and Toxicity (11) Personal Protective Equipment Use (12) Buddy System and Use of a Standby Person (13) Communication Systems and Emergency Signals (14) Safety and Rescue Equipment Use and Procedures (15) Use of Respirators (16) Safe Sampling Techniques (17) Safety in Handling, Shipping and Storage of NPDES Samples D. Training Certification All personnel working at a NPDES project site must have a certificate issued by the WRD Safety Officer. A certificate will be issued upon receiving a Standard Form 182 (Request, Authorization, Agreement and Certification of Training) after completion of the 24-hour basic NPDES site safety training and the 8-hour basic first-aid and CPR training. E. Training Plan and Recordkeeping The Project Chief shall prepare a training plan for development of training schedules, coordinate with the WRD Safety Officer, and maintain a written record of training as part of personnel files. The records shall be made available when requested during safety inspections by the Region or Division or both. 7. LABORATORY SAFETY A. Introduction (1) In most circumstances, laboratory safety is established in the USGS Safety and Environmental Health Handbook dated August 1989 (Ref. I); the USGS Laboratory Safety Handbook dated 1983 OFR 83-131 1983) (Ref. J); and various safety procedures, protocols, and memoranda by District Chiefs. (2) Careful planning is the key to minimizing the potential hazards associated with laboratory work activities. The laboratory work activities include sampling and collection of samples, storage of bottles in a vehicle, transportation to the project office, processing bottles for shipment to the National Water Quality Laboratory (NWQL) in Denver, Colorado, log-in procedures in NWQL, preparation and analysis of the NPDES samples, NWQL sample storage procedure, and, finally, disposal of the NPDES stream waste and samples. (3) Many of the potential hazards can be identified by inspecting the areas surrounding the site. Any unusual incidents or occurrences must be recorded on the analysis request form. Records of unusual occurrences will warn NWQL employees to wear appropriate personal protective equipment. Also, it may help identify problems that could interfere with laboratory procedures and analyses. The information provided also expedites the disposal of the stream samples and waste. (4) Minimizing unnecessary handling of the samples will greatly avoid potential exposures and reduce breakages and spillages of the sample bottles. (5) Clearly established procedures and techniques will maintain chain-of-custody requirements, and enforcement of sample-storage procedures will prevent tampering with samples. B. Collecting and Processing Samples (1) A flowchart is a good way to organize and optimize steps involved in sampling, collecting, and processing samples at the project office laboratories and NWQL. (2) All samples must be treated as hazardous and potentially biohazardous. (a) Strict personal hygiene must be enforced when processing samples. (b) Use of personal protective equipment or engineering controls must be available to prevent direct contact with the samples. (3) Plans, equipment, and materials for decontamination of known or potential hazards must be available. (4) Procedures that maintain chain-of-custody requirements must be established, followed, and documented. (5) Secure sample storage must be available at the sampling sites, project office laboratories, and NWQL. C. Packaging and Labeling Samples (1) NPDES samples shall be carefully packaged the same way as regular samples; however, they are to be clearly labeled and segregated from regular samples by double bagging them separately. (2) Individual NPDES sample bottles and shipping packages (Gott cooler) shall be clearly labeled. (3) The shipping packages shall be carefully sealed with tape to prevent the top of the package from opening during transit. (4) In a memorandum dated March 20, 1992, the WRD Office of Water Quality issued a report on sample shipping integrity and cost (Ref. K). This is a good reference for sample shipping procedure. D. Analytical Service Request In addition to the usual information (site identification, coordinates, schedules, laboratory codes, field data, and other information), it is important to record in the "remarks" section any unusual occurrences observed while inspecting or working at the site. Unusual occurrences could be odor, color, quality of the run-off streams, and so forth. The information provided will warn laboratory workers of known hazards so that they can wear appropriate personal protective equipment. Also, it will help in the process of preparing and analyzing the samples. E. Laboratory Handling of Sample Bottles (1) A written procedure of receiving and processing NPDES samples must be established. The procedure must include safety practices dealing with breakage and spillage of samples inside the shipping containers. (2) All samples known or suspected to be hazardous shall be flagged appropriately to warn laboratory workers of known hazards and unusual occurrences at the site. (3) The Gott coolers used to ship NPDES samples to NWQL shall be cleaned (decontaminated) if there is any breakage or spillage from the samples. F. Sample Disposal Procedures The storage and disposal procedure of NPDES samples and laboratory waste streams must be followed in accordance with the appropriate USEPA regulations. Documentation from the project offices and NWQL is the determining factor to establish baselines for appropriate disposal. Therefore, it is critical that as much information as possible be provided by the project offices to complement information collected by NWQL. The WRD has established a goal to minimize quantities and volumes of hazardous materials and wastes used and generated. Therefore, it is important that project offices and NWQL minimize the use of chemicals and potentially hazardous samples. So that problems related to NPDES laboratory safety can be handled quickly and properly, questions should be referred to the NWQL Safety Officer at (303) 467-8035. 8. SPILL CLEAN-UP PROCEDURES A. The project offices and NWQL shall have a written spill cleanup plan in effect for handling NPDES samples. B. The plan must identify the required equipment and material. These items must be available, and everyone working with NPDES samples must have a clear understanding on how to use them. The location of these items must be easily accessible wherever a spill could occur. 9. HAZARDOUS MATERIALS AND WASTE DISPOSAL Liquid and solid hazardous materials and waste must be handled and disposed of in accordance with the transportation and handling procedures as outlined in the Department of Transportation (DOT) regulations (DOT 49 CFR #171-173), and the disposal and containment of hazardous materials and waste, as outlined in USEPA regulations (USEPA 40 CFR #261 and #262). 10. CONCLUSIONS AND RECOMMENDATIONS A. NPDES sites have a much higher degree of risk than other routine sampling sites because of confined space worksites. There exists an extensive body of regulatory requirements for working in confined spaces; this includes OSHA and USGS regulations. B. Safety must be a priority in all NPDES projects, and considerable attention must be paid to safety program planning. C. Sufficient time and money must be budgeted for safety program planning, training, medical program, and safety equipment. REFERENCES: A. USGS Memorandum, "Safety and Occupational Health Program," from Director, February 7, 1992. B. "USGS Occupational Hazards and Safety Procedures Handbook," 445-2-H, April 1992. C. USGS Memorandum, "Medical Surveillance Program for Employees Exposed to On-the-Job Health Hazards," from Assistant Director for Administration, May 29, 1979. D. DOI Memorandum, "Medical Surveillance," from Medical Director, January 22, 1992. E. NIOSH 80-106, "Criteria for A Recommended Standard for Working in Confined Spaces." Dec. 1979. F. NIOSH 90-117, "The NIOSH Pocket Guide to Chemical Hazards," June 1990. G. ANSI Z117.1-1989, "American National Standard," American Society of Safety Engineers and American National Standards Institute, Inc., Oct. 1989. H. National Fire Codes, 1988. I. USGS Safety and Environmental Health Handbook, USGS 445-1-H, 1989. J. USGS Laboratory Safety Handbook, OFR 83-131, 1983. K. USGS WRD Office of Water Quality Technical Memorandum 92.06, "Report--Report of Committee on Sample Shipping Integrity and Cost," March 20, 1992. APPENDIXES (Contact the Branch of Operational Support, Reston, for a copy of these Appendixes.)