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Onsite Research
Fugitive Gas Emissions Detection Facilities

NETL uses an array of innovative laboratory techniques and field methods to detect and monitor fugitive emissions of CO2 stored in geologic formations. By providing an accurate accounting of stored CO2 and a high level of confidence that the CO2 will permanently remain in storage, these efforts can help ensure the technical soundness and economic viability of carbon sequestration, a technology that is critical to meeting the national goal of reduced greenhouse gas emissions. Successful research to establish the stability and integrity of host formations will help developers of sequestration projects secure permits and emissions reduction credits, while preventing damage to ecosystems and ensuring public health and safety.

To identify possible CO2 migration pathways, NETL scientists are investigating surface and near-surface characteristics by combining satellite and aerial photography with remote sensing, ground-penetrating radar, and ground-based measurements. In cooperation with Regional Sequestration Partnerships, long- and short-term CO2 monitoring is being conducted at depleted oil wells, saline aquifers, and coal-bed methane test sites. For example, using ground-penetrating radar, NETL found extremely low levels of CO2 leakage associated with subsurface thinning and faulting under the sandy soil at the West Pearl Queen, New Mexico depleted oil well sequestration test site. NETL registered similar low levels of leakage using several techniques to monitor the Frio saline aquifer sequestration test site near Houston, Texas .

A novel technique NETL used at both the West Pearl Queen and Frio sites to monitor sequestered CO2 is to add chemically inert perfluorocarbon tracer compounds to the CO2 stream being sequestered, and then detect any resulting tracer emissions in soil-gas at extremely low concentrations. NETL developed the protocol for tracer detection and quantification, the soil sampling pump, and several sampling systems. Other NETL-developed techniques are capable of monitoring fugitive emissions of non-CO2 greenhouse gases such as methane.

Syringe Pump
Perfluorocarbon tracers in a syringe pump located in the back of the NETL van are being added to carbon dioxide as it is injected underground at the Frio saline aquifer sequestration test site near Houston, Texas.

Partners in these detection efforts include: Brookhaven National Laboratory, Carnegie Mellon University , Los Alamos National Laboratory, Midwest Geological Sequestration Consortium, Sandia National Laboratory, Southeast Regional Carbon Sequestration Partnership, Southwest Regional Partnership for Carbon Sequestration, and West Virginia University .

NETL's complementary suite of resources for sequestration measurement, monitoring, and verification (MM&V), referred to as SEQURE, includes:

  • Specialized reactor equipment, including an yttrium stabilized zirconia pH probe
  • Airborne and ground-based magnetometry, radiometry, and methanometry surveys
  • Remote sensing: Optical, near infrared, thermal infrared and radar regions
  • Vertical Seismic Profile (VSP) studies and well-logging data interpretation
  • Modeling and testing of tracer/CO2 interactions with reservoir, overlying strata, and well-sealing cements
  • Perfluorocarbon tracers detected in soil-gas at parts-per-quadrillion levels
  • Surface well water monitoring
  • Radon, methane, and hydrocarbon monitoring in soil-gas

For more information contact: Arthur Wells