Principal Officers and Chiefs of Mission, by year: 1812
Note: Career Foreign Service appointees are asterisked.
- Adams, John Quincy (1767-1848)
- Minister Resident, Netherlands (1794-1797)
- Minister Plenipotentiary, Portugal (1796)
- Minister Plenipotentiary, Germany (1797-1801)
- Minister Plenipotentiary, Russia (1809-1814)
- Envoy Extraordinary and Minister Plenipotentiary, United Kingdom (1815-1817)
- Secretary of State (1817-1825)
- Graham, John (1774-1820)
- Chief Clerk (1807-1817)
- Secretary of State ad interim (1817)
- Minister Plenipotentiary, Portugal (1819-1820)
- Monroe, James (1758-1831)
- Minister Plenipotentiary, France (1794-1796)
- Minister Plenipotentiary, United Kingdom (1803-1807)
- Secretary of State (1811-1814)
- Secretary of State ad interim (1814-1815)
- Secretary of State (1815-1817)
- Sumter, Thomas (1768-1840)
- Minister Plenipotentiary, Portugal (1809-1819)