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Chromic acid and chromates |
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Synonyms & Trade NamesChromic acid (CrO3): Chromic anhydride, Chromic oxide, Chromium(VI) oxide (1:3), Chromium trioxideSynonyms of chromates (i.e., chromium(VI) compounds) such as zinc chromate vary depending upon the specific compound. |
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CAS No.1333-82-0 (CrO3) |
RTECS No.GB6650000 (CrO3) |
DOT ID & Guide1755 154 (acid solution)1463 141 (acid, solid) |
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FormulaCrO3 (acid) |
Conversion |
IDLHCa [15 mg/m3 {as Cr(VI)}]See: 1333820 |
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Exposure LimitsNIOSH REL(as Cr): Ca TWA 0.001 mg/m3 See Appendix A See Appendix COSHA PEL(as CrO3): TWA 0.005 mg/m3 See Appendix C |
Measurement MethodsNIOSH 7600 , 7604 , 7605 , 7703 , 9101; OSHA ID103 , ID215 , W4001 See: NMAM or OSHA Methods |
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Physical DescriptionCrO3: Dark-red, odorless flakes or powder. [Note: Often used in an aqueous solution (H2CrO4).] |
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MW:100.0 |
BP:482°F (Decomposes) |
MLT: 387°F (Decomposes) | Sol:63% |
VP:Very low |
IP:NA |
Sp.Gr:2.70 (CrO3) |
Fl.P:NA |
UEL:NA |
LEL:NA |
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CrO3: Noncombustible Solid, but will accelerate the burning of combustible materials. | |||||
Incompatibilities & ReactivitiesCombustible, organic, or other readily oxidizable materials (paper, wood, sulfur, aluminum, plastics, etc.); corrosive to metals |
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Exposure Routesinhalation, ingestion, skin and/or eye contact |
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Symptomsirritation respiratory system; nasal septum perforation; liver, kidney damage; leukocytosis (increased blood leukocytes), leukopenia (reduced blood leukocytes), eosinophilia; eye injury, conjunctivitis; skin ulcer, sensitization dermatitis; [potential occupational carcinogen] |
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Target OrgansBlood, respiratory system, liver, kidneys, eyes, skin |
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Cancer Site[lung cancer] | |||||
Personal Protection/Sanitation(See protection codes)Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench |
First Aid(See procedures)Eye: Irrigate immediately Skin: Soap flush immediately Breathing: Respiratory support Swallow: Medical attention immediately |
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Respirator Recommendations
NIOSH At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: Escape: |
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See also: INTRODUCTION See ICSC CARD: 1194 See MEDICAL TESTS: 0051 |
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