PHYSICAL STATE; APPEARANCE:
BRITTLE, GREY, METALLIC-LOOKING CRYSTALS.
PHYSICAL DANGERS:
CHEMICAL DANGERS:
Upon heating, toxic fumes are formed.
Reacts
violently with
strong oxidants
and
halogens,
causing fire and explosion hazard.
Reacts
with
reducing agents
to produce
toxic and flammable arsine gas
(See ICSC 0222)
.
OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL: 1910.1018 TWA 0.010 mg/m3
NIOSH REL: Ca C 0.002 mg/m3 15-minute See Appendix A
NIOSH IDLH: Ca 5 mg/m3 (as As) See: 7440382
TLV: 0.01 mg/m³ as TWA; A1 (confirmed human carcinogen); BEI issued; (ACGIH 2010).
MAK:
Carcinogen category: 1; Germ cell mutagen group: 3A;
(DFG 2009).
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ROUTES OF EXPOSURE:
The substance can be absorbed into the body
by inhalation of its aerosol
and
by ingestion.
INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly when dispersed, especially, if powdered.
EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the
gastrointestinal tract
, resulting in severe gastroenteritis, loss of fluid, and electrolytes,
cardiac disorders
,
shock
and
convulsions
.
Exposure far above the OEL may result in death.
The effects may be delayed.
Medical observation is indicated.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the skin, mucous membranes,
peripheral nervous system
,
liver
and
bone marrow
, resulting in pigmentation disorders, hyperkeratosis, perforation of nasal septum, neuropathy,
anaemia
,
liver impairment
.
This substance is carcinogenic to humans.
Animal tests show that this substance possibly causes toxicity to human reproduction or development.
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