NAME: alpha-Chloroacetophenone
SYNONYM(s):
Phenacyl chloride; omega-Chloroacetophenone; Chloromethyl phenyl
ketone; Phenyl chloromethyl ketone; Tear gas; CN; Phenacylchloride
IMIS: 0618
CAS: 532-27-4
NIOSH: RTECS AM6300000; 3237
DOT: UN1697 Poison
DESCRIPTION:
Colorless to gray solid with a sharp, irritating odor.
MW:
154
BP:
477 F
VP:
0.012 mm
MP:
138 F
INCOM:
Water, steam
Exposure Limits
OSHA GENERAL INDUSTRY PEL:
0.05 ppm, 0.3 mg/m3
OSHA CONSTRUCTION INDUSTRY PEL:
0.05 ppm, 0.3 mg/m3 TWA
ACGIH TLV:
0.05 ppm, 0.32 mg/m3 TWA; Appendix A4 (Not Classifiable as a Human
Carcinogen) (TLV listed for 2-Chloroacetophone)
NIOSH REL: 0.05 ppm TWA
Health Factors
SYMPTOM(s):
Eye, skin, respiratory system irritation; pulmonary edema
HEALTH EFFECTS:
Irritation-Eye, Nose, Throat, Skin---Marked (HE14)
ORGAN:
Eyes, skin, respiratory system
Monitoring
PRIMARY SAMPLING/ANALYTICAL METHOD (SLC1):
MEDIA:
Silica Gel Tube (100/50 mg sections; 20/40 mesh)
ANL SOLVENT:
Ethanol
MAX V:
10 Liters MAX F:
0.1 L/min
ANL 1:
High Performance Liquid Chromatography; HPLC/UL59
REF:
2 (OSHA In-House File)
CLASS:
Partially Validated
COND:
Column: Zorbax ODS (25cm x 4.6mm)
Mobile Phase: 60:40 Methanol:Water with 0.1% H3PO4, 0.1%
Di-n-butylamine
|
Back to Top
