Table VI-1: Summary Table of Field Methods for Petroleum Hydrocarbon Analysis
Test Method | Media1 | Analyte | Data Quality Level2 | Analysis Time | Cost Per Sample3 | Skill Level | Limitations | ||
---|---|---|---|---|---|---|---|---|---|
S | SG | W | |||||||
Detector Tubes | X | X | >100 specific compounds | 1A/1B | 5 to 15 min | $8 to $27 | Low | High degree of cross-reactivity | |
Fiber Optic Chemical Sensors | X | X | VOCs and SVOCs ≥ C6 |
1A/1B | 3 to 5 min | <$1 to $10 | Low | Does not measure specific constituents | |
Colorimetric Test Kits | X | X | Aromatic hydrocarbons | 1A/1B | 10 to 20 min | $17 to $42 | Low-Med. | Colors may be difficult to distinguish | |
TOV Methods with FID/PID | X | X | X | Total VOCs | 1A/1B | 1 to 30 min | <$1 to $10 | Low-Med. | Does not measure specific constituents |
Turbidimetric Test Kit | X | TPH of mid-range hydrocarbons (e.g., diesel fuel) | 1B | 15 to 20 min (25 per hour)4 |
$10 to $15 | Low-Med. | Not useful for gasoline | ||
Immunoassay Test Kits | X | X | TEX/PAHs/TPH | 1B | 30 to 45 min (5 to 8 per hour)4 |
$20 to $60 | Med. | Cross-reactivity may affect interpretation | |
Portable Infrared Detectors | X | X | TPH of hydrocarbons from C6 to C26 | 2 | 5 to 20 min | $5 to $30 | Med. | VOCs are not accurately analyzed | |
Field GC | X | X | X | Specific VOCs and SVOCs | 2/3 | 10 to 60 min5 | $20 to $70 | Med.-High | Requires a skilled technician |
1Soil (S), Soil-Gas (SG), Water (W)
2Data quality levels are discussed in further detail in Chapter VI of the "Expedited Site Assessment..." manual (see note below).
3Includes estimation of capital costs and disposables -- excludes labor.
4When run in batches.
5Longer times result when high quality method preparations are performed.
NOTE: This table appears as Table VI-1 in Chapter VI of "Expedited Site Assessment Tools for Underground Storage Tank Sites: A Guide for Regulators" (EPA 510-B-97-001).