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Chemical Sampling Information
Phosphorus Pentasulfide
 Field Definitions
 Analytical Methods
 Health Guidelines
General Description

NAME: Phosphorus Pentasulfide

SYNONYM(s): Phosphorus persulfide; Regular phosphorus pentasulfide; Reactive phosphorus pentasulfide; Undistilled pentasulfide

IMIS: 2092

CAS: 1314-80-3

NIOSH: RTECS TH4375000

DOT: 1340 41

DESCRIPTION:

Greenish-yellow solid with an odor of rotten eggs.
MW: 222 or 445
BP: 955 F
VP: 1 mm at 572 F
MP: 527 F

INCOM: Water, alcohols, strong oxidizers

Exposure Limits

OSHA GENERAL INDUSTRY PEL: 1 mg/m3

OSHA CONSTRUCTION INDUSTRY PEL: 1 mg/m3 TWA

ACGIH TLV: 1 mg/m3 TWA; 3 mg/m3 STEL

NIOSH REL: 1 mg/m3 TWA; 3 mg/m3 STEL

Health Factors

SYMPTOM(s): Apnea; coma, convulsions; eye irritation, conjunctivitis pain, lacrimation, photophobia, kerato-conjunctivitis, corneal vesiculation; respiratory system irritation; dizziness; headaches; fatigue; irritability, insomnia; GI disturbance

HEALTH EFFECTS: Irritation-Eye, Nose, Throat, Skin---Marked (HE14) H2S Hazard (HE4)

ORGAN: Respiratory system, CNS, eyes, skin

Monitoring

PRIMARY SAMPLING/ANALYTICAL METHOD (SLC1):



MEDIA: Low Ash Polyvinyl Chloride (LAPVC) filter 5 microns
MAX V: 960 Liters
MAX V: 120 Liters   MAX F: 2.0 L/min (TWA)
MAX V: 30 Liters   MAX F: 2.0 L/min (STEL)
ANL 1: Ion Chromatography; IC
REF: 2 (OSHA ID-128SG)
CLASS: Partially Validated
NOTE: Submit as a separate sample.

WIPE:

MEDIA: Whatman smear tab; Solvent: Deionized water


Revision Date: 01/15/1993
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