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 MTBE / Oxygenates

  Risk management research and development is conducting research on the treatment of of soils, ground water and drinking water contaminated with Methyl Tertiary Butyl Ether (MTBE). This research is intended to improve understanding of the physical, chemical, biological processes associated with the fate and transport and destruction of MTBE and to evaluate and develop more cost-effective MTBE treatment processes. Some research also is being conducted on other oxygenates, such as ethanol. Currently, research is focusing on natural attenuation and treatment (particularly biotreatment) of MTBE in ground water and enhancements of drinking water treatment technologies. Treatment studies are being conducted at bench- and pilot/field-scale. The Laboratory also is preparing several technical resource documents on natural attenuation of MTBE in ground water.

MTBE Demonstration Project

The Agency has formed a workgroup to conduct field evaluations of technologies and processes for remediating soils, groundwater, and drinking water contaminated with MTBE. This work group is comprised of individuals from US EPA Research and Development, Solid Waste and Emergency Response, Water, Air and Radiation, and Region 9 with the California Water Board and Department of Health. Both source water and wellhead MTBE treatment technologies will be demonstrated. For more information, see http://www.epa.gov/swerust1/mtbe/mtbedemo.htm.

Laboratory publications and web sites related to these MTBE topic areas include:

  • Summary of Workshop on MTBE, February 1-2, 2000 by Eastern Research Group, Inc. (2001).
  • Chen, C.T., A.N. Tafuri, M. Rahman, M.B. Foerst, E. Pfetzing, and M. Taylor. (1995) Oxidation of methyl-t-butyl ether (MTBE) using Fenton's Reagent, paper no. 95-WA91.03. Presented at the 88th annual meeting of the Air & Waste Management Association, San Antonio, Texas. Air & Waste Management Association, Pittsburgh, Pennsylvania.
  • Cho, Jong Soo, Dominic DiGiulio, and John T. Wilson. "In situ Air Injection, Soil Vacuum Extraction and Enhanced Biodegradation: A Case Study in a JP-4 Jet Fuel Contaminated Site," Environmental Progress, Volume 16, No. 1, pages 35 to 42, 1997.
  • Cho, Jong Soo, John T. Wilson, Dominic C. DiGiulio, James A. Vardy, and Woohee Choi. "Implementation of Natural Attenuation at a JP-4 Jet Fuel Release After Active Remediation," Biodegradation, Volume 8, pages 265 to 273, 1997.
  • Cho, Jong Soo, and John T. Wilson. "Hydrocarbon and MTBE Removal Rates During Natural Attenuation Application," in Natural Attenuation of Chlorinated Solvents, Petroleum Hydrocarbons and Other Organic Compounds, Volume 1, pages 109 to 114. Eds. Alleman, Bruce C. and Andrea Leeson, the Fifth International In Situ and On-Site Bioremediation Symposium, San Diego, California, April 19-22, 1999, Battelle Press, Columbus, Ohio.
  • Hurt, Kelly, John T. Wilson, Frank Beck, and Jong Soo Cho. "Anaerobic Biodegradation of MTBE in a Contaminated Aquifer," in Natural Attenuation of Chlorinated Solvents, Petroleum Hydrocarbons and Other Organic Compounds, Volume 1, pages 103 to 108. Eds. Alleman, Bruce C. and Andrea Leeson, the Fifth International In Situ and On-Site Bioremediation Symposium, San Diego, California, April 19-22, 1999, Battelle Press, Columbus, Ohio.
  • Wilson, Barbara H., Hai Shen, Jong Soo Cho, and James Vardy. "Use of BIOSCREEN to Evaluate Natural Attenuation of MTBE," in Natural Attenuation of Chlorinated Solvents, Petroleum Hydrocarbons and Other Organic Compounds, Volume 1, pages 115 to 120. Eds. Alleman, Bruce C. and Andrea Leeson, the Fifth International In Situ and On-Site Bioremediation Symposium, San Diego, California, April 19-22, 1999, Battelle Press, Columbus, Ohio.
  • Wilson, John T., Jong Soo Cho, and Barbara H. Wilson. Natural Attenuation of MTBE in the Subsurface under Methanogenic Conditions, U.S. EPA, Office of Research and Development, National Risk Management Research Laboratory, EPA/600/R-00/006 (January 2000).
  • Description of ongoing research projects at Ground Water and Ecosystems Restoration Research.

Visit the MTBE main web page.


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