Chemical Sampling Information
Copper dusts & mists (as Cu)
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General Description
Synonyms: Copper metal dusts; Copper metal fumes
OSHA IMIS Code Number: 0730
Chemical Abstracts Service (CAS) Registry Number: 7440-50-8
NIOSH, Registry of Toxic Effects (RTECS) Identification Number: GL5325000
NIOSH Pocket Guide to Chemical Hazards, Copper (dusts and mists, as Cu) : chemical description, physical properties, potentially hazardous incompatibilities, and more
Exposure Limits
OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 1 mg/m3 TWA
OSHA Permissible Exposure Limit (PEL) for Construction Industry: 29 CFR 1926.55 Appendix A -- 1 mg/m3 TWA
OSHA Permissible Exposure Limit (PEL) for Maritime: 29 CFR 1915.1000 Table Z-Shipyards -- 1 mg/m3 TWA
American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): 1 mg/m3 TWA
National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): 1 mg/m3 TWA
Health Factors
Environmental Protection Agency (EPA) carcinogenic classification: Group D, not classified
NIOSH Immediately Dangerous To Life or Health Concentration (IDLH): 100 mg/m3 (as Cu)
Potential symptoms: Mucous membrane, nasal, pharyngeal irritation; nasal perforation; eye irritation; metallic taste; dermatitis. In animals: lung, liver, kidney damage; anemia; increased risk of Wilson's disease
Health Effects: Irritation-Eye, Nose, Throat, Skin---Mild (HE16)
Affected organs: Respiratory system, skin, liver, kidneys
Literature Basis:
Monitoring Methods used by OSHA
Laboratory Sampling/Analytical Method:
sampling media: Mixed Cellulose Ester Filter (MCEF) 0.8 microns
maximum volume: 960 Liters minimum volume: 480 Liters maximum flow rate: 2.0 L/min
current analytical method: Atomic Absorption Spectroscopy; AAS
method reference: OSHA Analytical Method (OSHA ID-121 )
method classification: Fully Validated
alternate analytical method: Inductively Coupled Argon Plasma; ICP-AES/MS, AAS
method reference: OSHA Analytical Method (OSHA ID-125G , OSHA ID-206 , OSHA ID-105 , OSHA 1006 )
method classification: Fully Validated
note: If the filter is not overloaded, samples may be collected up to an 8-hour period. Analytical method does not distinguish between dust and fume.
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