www.OSHA.gov | |
Regulations (Standards - 29 CFR)
Substance technical guidelines - 1910.1018 App B |
Regulations (Standards - 29 CFR) - Table of Contents |
Part Number: | 1910 |
Part Title: | Occupational Safety and Health Standards |
Subpart: | Z |
Subpart Title: | Toxic and Hazardous Substances |
Standard Number: | 1910.1018 App B |
Title: | Substance technical guidelines |
ARSENIC, ARSENIC TRIOXIDE, ARSENIC TRICHLORIDE (THREE EXAMPLES) I. Physical and chemical properties A. Arsenic (metal). 1. Formula: As. 2. Appearance: Gray metal. 3. Melting point: Sublimes without melting at 613C. 4. Specific Gravity: (H20=1):5.73. 5. Solubility in water: Insoluble. B. Arsenic Trioxide. 1. Formula: As203, (As406). 2. Appearance: White powder. 3. Melting point: 315C. 4. Specific Gravity (H20=1):3.74. 5. Solubility in water: 3.7 grams in 100cc of water at 20c. C. Arsenic Trichloride (liquid). 1. Formula: AsC13. 2. Appearance: Colorless or pale yellow liquid. 3. Melting point: 8.5C. 4. Boiling point: 130.2C. 5. Specific Gravity (H20=1):2.16 at 20C. 6. Vapor Pressure: 10mm Hg at 23.5C. 7. Solubility in Water: Decomposes in water. II. Fire, explosion and reactivity data. A. Fire: Arsenic, arsenic Trioxide and Arsenic Trichloride are nonflammable. B. Reactivity: 1. Conditions Contributing to instability: Heat. 2. Incompatibility: Hydrogen gas can react with inorganic arsenic to form the highly toxic gas arsine. III. Monitoring and Measurement Procedures Samples collected should be full shift (at least 7-hour) samples. Sampling should be done using a personal sampling pump at a flow rate of 2 liters per minute. Samples should be collected on 0.8 micrometer pore size membrane filter (37mm diameter). Volatile arsenicals such as arsenic trichloride can be most easily collected in a midget bubbler filled with 15 ml. of 0.1 N NaOH. The method of sampling and analysis should have an accuracy of not less than + or - 25 percent (with a confidence limit of 95 percent) for 10 micrograms per cubic meter of air (10 ug/m(3)) and + or - 35 percent (with a confidence limit of 95 percent) for concentrations of inorganic arsenic between 5 and 10 ug/m(3). |
Next Standard (1910.1018 App C) |
Regulations (Standards - 29 CFR) - Table of Contents |
Back to Top | www.osha.gov | www.dol.gov |
Contact Us | Freedom of Information Act | Customer Survey Privacy and Security Statement | Disclaimers |
||
Occupational Safety & Health Administration 200 Constitution Avenue, NW Washington, DC 20210 |