PUBLIC HEALTH ASSESSMENT
CHEMFAX, INC.
GULFPORT, HARRISON COUNTY, MISSISSIPPI
Figure
Number        Title
Figure 1. Site Location Map
Figure 2. Site Map
APPENDIX B -- CONTAMINANT AND PATHWAY TABLES
Table
Number        Title
LIST OF ACRONYMS, CODES, AND ABBREVIATIONS
CREG | Cancer Risk Evaluation Guide |
RMEG | Reference Dose Media Evaluation Guide |
MRL | Minimum Risk Level |
EMEG | Environmental Media Evaluation Guide |
AL | Action Level |
ppb | parts per billion |
J | estimated value |
4,4-DDD | p,p'-dichlorodiphenyldichloroethane |
NA | none available |
ND | not detected |
Table 1 Ambient Air, On Site
Contaminant |
Maximum Concentration* in ppb Year--1990 |
Selection Comparison Value | |
ppb | Source | ||
1,1,1-trichloroethane | A-0.38J B-0.24J C-0.23J |
NA | |
1,2,4-trichlorobenzene | A-0.19J B-ND C-0.19J |
NA | |
1,2,4-trimethylbenzene | A-12 B-ND C-ND |
NA | |
1,3,5-trimethylbenzene | A-4.8 B-0.38 C-ND |
NA | |
benzene | A-18 B-ND C-1.6 |
0.03 | CREG |
carbon tetrachloride | A-0.14J B-0.12J C-0.12J |
0.01 | CREG |
dichlorodifluoromethane | A-0.97 B-0.66 C-0.90 |
NA | |
methylene chloride | A-22 B-1.1 C-22 |
0.6 | CREG |
naphthalene | A-12 B-2.4 C-ND |
2 | MRL |
styrene | A-120 B-0.7J C-1.7 |
60 | MRL |
trichlorofluoromethane | A-1.8 B-0.28 C-1.8 |
NA | |
trichlorotrifluoro- methane |
A-8.4 B-ND C-ND |
NA | |
xylene | A-95 B-ND C-ND |
NA | |
A- Maximum value for sampling period B- Maximum value reported at apparent upwind sample locations based on winds predominantly from south through southeast (four sample points--the eastern- and southern-most sample locations); may approximate quality of air moving on site at the time sampled was conducted. C- Maximum value at apparent downwind sample locations based on winds predominantly from south through southeast (seven sample points--at the northern-most sample locations); may approximate quality of air moving off site at the time sampling was conducted. * Data is from reference (1) |
Table 2 Groundwater, On Site and Off Site
Contaminant | Maximum Concentration * in ppb Year--1990*** |
Selection Comparison Value | ||
On Site | Off Site | ppb | Source | |
2-methylnaphthalene | A-1,800 B-ND |
C-ND | NA | |
dibenzofuran | A-7J B-ND |
C-ND | NA | |
methyl butyl ketone | A-610J B-ND |
C-ND | NA | |
phenanthrene | A-410 B-ND |
C-ND | NA | |
aluminum | A-120,000 B-ND |
C-80,000 | NA | |
calcium | A-51,000 B-2,400 |
C-17,000 | NA | |
cobalt | A-93 B-ND |
C-22 | NA | |
iron | A-120,000 B-ND |
C-36,000J | NA | |
lead | A-190 B-ND |
C-40 | 15 | AL |
magnesium | A-29,000 B-540 |
C-17,000 | NA | |
nickel | A-210 B-ND |
C-ND | 200 | RMEG |
potassium | A-20,000 B-ND |
C-11,000 | NA | |
sodium | A-180,000 B-57,000 ** |
C-36,000J | NA | |
Note: Samples were not filtered A-On site monitoring wells B-On site industrial wells C-Off site monitoring wells, several hundred feet southeast and northeast of property * Data is from reference (1), except for that marked ** ** Data is from reference (2) *** Concentrations from 1988 sampling activity were less than for 1990 sampling. |
Table 3 Surface Soil, On Site and Off Site
Contaminant | Maximum Concentration * in ppb |
Selection Comparison Value | ||
On Site (year) | Off Site*** (year) | ppb | Source | |
2-methylnaphthalene | 100,000 (1990) | ND | NA | |
benzo(a)anthracene | 79,000J (1990) | 140J (1990) | NA | |
benzo(b/k)fluoranthene | 18,000J (1990) | 180J (1990) | NA | |
benzo(ghi)perylene | 91J (1990) | ND | NA | |
endrin ketone | 26 ** (1988) | ND | NA | |
4,4-DDD | 62J ** (1988) | ND | 3 | CREG |
ideno(1,2,3-cd)pyrene | 61J (1990) | ND | NA | |
naphthalene | 240,000 ** (1988) | ND | NA | |
phenanthrene | 180,000J (1990) | 98J (1990) | NA | |
aluminum | 15,000 (1990) | 3,100 (1990) | NA | |
calcium | 84,000 ** (1988) | 3,000 (1990) | NA | |
cobalt | 2 (1990) | ND | NA | |
copper | 25 ** (1988) | 12 (1990) | NA | |
iron | 20,000J (1990) | 5,100J (1990) | NA | |
lead | 53 ** (1988) | 53 (1990) | NA | |
magnesium | 170 ** (1988) | ND | NA | |
mercury | 0.32J (1990) | 0.40J (1990) | NA | |
nickel | 76 (1990) | 2 (1990) | NA | |
sodium | 680 ** (1988) | ND | NA | |
* Data from reference (1), except for data marked ** ** Data from reference (2) *** Sampled a few hundred feet north of property |
Table 4 Subsurface Soil, On Site and Off Site
Contaminant | Maximum Concentration * in ppb Year--1990 |
Selection Comparison Value | ||
On Site | Off Site ** | ppb | Source | |
2-methylnaphthalene | 170,000 | ND | NA | |
benzyl butyl phthalate | 920 | ND | NA | |
chrysene | 160J | ND | NA | |
naphthalene | 380,000 | ND | NA | |
phenanthrene | 45,000 | ND | NA | |
aluminum | 14,000 | 230 | NA | |
calcium | 1,400J | 670 | NA | |
cobalt | 34 | 34 | NA | |
copper | 27 | 140 | NA | |
iron | 42,000J | 2,900J | NA | |
lead | 98 | 72 | NA | |
magnesium | 1,300 | 720 | NA | |
mercury | 1.3J | 0.32J | NA | |
nickel | 72 | 36 | NA | |
potassium | 860 | ND | NA | |
sodium | 2,100 | ND | NA | |
* Data from reference (1) ** Sampled near bayou |
Table 5 Sediment, On Site and Off Site
Contaminant | Maximum Concentration* in ppb Year--1990 |
Selection Comparison Value | ||
On Site | Off Site | ppb | Source | |
2-methylnaphthalene | A-200,000 B-2,500 C-27,000 |
D-240 E-ND |
NA | |
benzo(a)anthracene | A-4,500 B-ND C-ND |
D-140J E-ND |
NA | |
benzo(b/k)fluoranthene | A-1,600J B-ND C-ND |
D-220J E-ND |
NA | |
benzo(ghi)perylene | A-880J B-ND C-ND |
D-ND E-ND |
NA | |
chrysene | A-6,400 B-820J C-ND |
D-280J E-ND |
NA | |
dibenzofuran | A-290J B-ND C-ND |
D-ND E-ND |
NA | |
ideno(1,2,3-cd)pyrene | A-41J B-ND C-ND |
D-ND E-ND |
NA | |
naphthalene | A-200,000 B-10,000 C-200,000 |
D-2,300 E-ND |
NA | |
phenanthrene | A-97,000 B-1,400J C-ND |
D-430J E-ND |
NA | |
aluminum | A-630,000 B-4,300 C-2,000 |
D-1,900 E-140 |
NA | |
calcium | A-16,000,000 B-2,600 C-1,700 |
D-34,000 E-ND |
NA | |
cobalt | A-2,000 B-29 C-ND |
D-ND E-ND |
NA | |
copper | A-22,000 B-19 C-81 |
D-38 E-ND |
NA | |
iron | A-14,000J B-8,800J C-7,100J |
D-4,100J E-180J |
NA | |
lead | A-12,000 B-210 C-31 |
D-21 E-ND |
NA | |
magnesium | A-220,000 B-ND C-ND |
D-ND E-ND |
NA | |
mercury | A-ND B-ND C-0.41J |
D-0.54J E-ND |
NA | |
nickel | A-3,300 B-11 C-3 |
D-ND E-ND |
NA | |
potassium | A-270 B-ND C-ND |
D-ND E-ND |
NA | |
sodium | A-6,400 B-ND C-ND |
D-ND E-ND |
NA | |
A-Ditches and drainage holding ponds B-Within diked tank area C-Former cooling pond D-Off-site ditch, east side of Three Rivers Road; sampled by Bayou and south of bayou E-Background--off site * All data from reference (1) |
Table 6 Surface Water, On Site and Off Site
Contaminant | Maximum Concentration * ppb |
Selection Comparison Value | ||
On Site (year) | Off Site (year) | ppb | Source | |
naphthalene | A-ND B-26J ** (1988) |
C-ND | NA | |
aluminum | A-47 ** (1988) B-76 ** (1988) |
C-860 (1990) | NA | |
calcium | A-ND B-3,200 ** (1988) |
C-4,600 (1990) | NA | |
iron | A-250J ** (1988) B-460J ** (1988) |
C-1,500J (1990) | NA | |
magnesium | A-150 ** (1988) B-230 ** (1988) |
C-ND | NA | |
sodium | A-55,000 ** (1988) B-64,000 ** (1988) |
C-24,000 (1990) | NA | |
Note: Samples were not filtered A-On site former cooling pond B-On site drainage holding pond C-Off site ditch, sampled by bayou * Data is from reference (1) except for that marked ** ** Data is from reference (2) |
Table 7 Summary--Completed Exposure Pathways
PATHWAY NAME: | AMBIENT AIR (on site) |
AMBIENT AIR (off site) |
PROCESS CHEMICALS | SURFACE SOILS (on site) |
SURFACE SOILS (off site) |
Source: | Chemfax and other industries | Local industries | Chemfax | Chemfax, possibly area industries |
Source uncertain |
Medium: | Air | Air | Process Chemicals | Surface Soils | Surface Soils |
Exposure Point: | On site | Off site | On site | On Site | Off site |
Exposure Route: | Inhalation | Inhalation | Skin contact, inhalation | skin contact, inhalation, ingestion |
skin contact, inhalation, ingestion |
Receptor Population: | Workers | Workers, shoppers, various residents, students | Workers | Workers | Nearby workers & mental health residents |
Exposure Period: | Past, present, future | Past, present, future | Past, present, future | Past, present, future | Past, present, future |
Estimated Number Exposed: | 30 to 60 | More than 500 | less than 50 | 30 to 60 | unknown |
Table Continues.... |
Table 7 (Continued) Summary--Completed Exposure Pathways
PATHWAY NAME: | SEDIMENT, SURFACE WATER (on site) |
DITCH SEDIMENT, SURFACE WATER (off site) |
Source: | Chemfax | Local industries |
Medium: | Sediment, surface water | Sediment, surface water |
Exposure Point: | On site | Off site |
Exposure Route: | Skin contact, ingestion | Skin contact |
Receptor Population: | Maintenance workers | Maintenance workers |
Exposure Period: | Past, present, future | Past, present, future |
Number Exposed: | Potentially about 5 | Potentially about 5 |
Table 8 Summary--Potential Exposure Pathways
PATHWAY NAME: | PRIVATE WELL (on site) |
PRIVATE WELLS (off site) |
INDUSTRIAL SEAWAY |
Source: | Chemfax | Local industries | Area runoff, industries |
Medium: | Groundwater | Groundwater | Surface water, fish |
Exposure Point: | On site | Off site | Off site |
Exposure Route: | Ingestion | Ingestion, inhalation, skin contact | Skin contact, ingestion |
Receptor Population: | Workers | Consumers served by private wells | Boaters, fishermen, swimmers |
Exposure Period: | Past | Past, present, future | Past, present, future |
Number Exposed: | Potentially about 60 | Unknown | Unknown |
Contaminant | Exposure Pathway | Health Guideline for Ingestion - mg/kg/day | ||
Value | Source | Exceeded by Estimated Exposure Dose | ||
2-methylnaphthalene | Soil On Site | None | None | None |
Benzo(a)anthracene | Soil On Site
Soil Off Site |
None
None |
None
None |
None
None |
Benzo(b/k)fluoranthene | Soil On Site
Soil Off Site |
None
None |
None
None |
None
None |
Endrin Ketone | Soil On site | None | None | None |
4,4-DDD* | Soil Site | None | None | None |
Indeno(1,2,3-cd)pyrene | Soil On Site | None | None | None |
Naphthalene | Soil Site | None | None | None |
Phenanthrene | Soil On Site
Soil Off Site |
None
None |
None
None |
None
None |
*4,4-DDD = p,p'dichlorodiphenyldichloroethane.
Table 9 (Continued) Comparison of Estimated Exposed Dose to Health Guidelines for Chemfax Workers on Site, Other Workers and Various Residents Off Site.
Contaminant | Exposure Pathway | Health Guideline for Ingestion - mg/kg/day | ||
Value | Source | Exceeded by Estimated Exposure Dose | ||
Aluminum | Soil On Site Soil Off Site |
1 1 |
RfD* RfD |
No No |
Calcium | Soil On Site Soil Off Site |
50 50/11.43 |
RDA** Adult RDA Adult/Child |
No No |
Cobalt | Soil On Site | None | None | None |
Copper | Soil On Site Soil Off Site |
0.02 0.02 |
ADI*** ADI |
No No |
Iron | Soil On Site Soil Off Site |
0.14 1.13/0.14 |
RDA Adult RDA Child/Adult |
No No |
Lead | Soil On Site Soil Off Site |
None None |
None None |
None None |
Magnesium | Soil On site | 15.6/5 | RDA Adult | No |
Mercury | Soil On Site Soil Off Site |
0.002/0.007 0.002/0.007 |
I/A MRLa I/A MRL |
No No |
Nickel | Soil On Site Soil Off Site |
0.02 0.02 |
RfD RfD |
No No |
Sodium | Soil On Site | 37.5-112 /15.45 | ADI Adult | No |
*RfD = EPA's provisional Reference Dose.
**RDA = Calculated from Recommended Dietary Allowance.
***ADI = Calculated from the range of Estimated Safe and Adequate Dietary Intake.
aI/A MRL = Intermediate and Acute Minimal Risk Levels.
APPENDIX C -- RESPONSE TO PUBLIC COMMENTS
The Chemfax, Inc. Public Health Assessment was available for public review and comment from
approximately October 1 to November 30. The comment period was announced in local
newspapers. Copies were made available at the public library, and copies were sent to several
individuals and organizations. A summary of comments received and our responses are
presented in this section. The list of comments does not include any that raised health effect and other issues previously addressed in the Community Health Concerns Evaluation section.
COMMENT 1. | Some of the chemicals at Chemfax are listed chemicals requiring reporting
and safe handling; none are particularly dangerous. |
Response: |
Essentially all chemicals have a capacity to pose a hazard to public health;
many pose a hazard at very low concentrations and human exposure levels.
The document has not been changed as a result of this comment. |
COMMENT 2. | The public health hazard determination stated in Paragraph 1 in the
Conclusions Section is based on testing by EPA and others in the past.
That sampling is disputed as being subject to errors and irregularities.
Three key air samples (CF-AT-03, CF-AT-04, and CF-AT-05) and a key
soil sample (CF-SS-02) were taken in the immediate vicinity of process
operations where a minor spill of raw material had occurred the day of the
sampling. As a result, those data points reflect then current operations
conditions that are not present today. |
Response: |
ATSDR's public health hazard determination for workers is based on air,
soil, and sediment data. Reference information show that air sampling was
conducted in the process area on May 31, 1990 and beyond the process
area on May 31, June 1, and June 5 of that year. Concentrations were
greatest in the process area; ATSDR considers some of the levels reported
there to be of public health concern for the workers. For later sampling
elsewhere on the property, some of the lower concentrations detected are
considered substantive from a worker health perspective. ATSDR also
notes that references show two soil samples designated CF-SS-02 were
taken; one in 1988 and one in 1990. The soil sample the commenter
identifies as being in the process area was taken in 1988. Thus, the minor
spill mentioned as a confounding factor for the ambient air data would
have been cleaned up in 1988, long before the 1990 air sampling. Our
recommendation for additional ambient air sampling (Characterization
Recommendation 1., Page 27 of the Public Comment Release) is for the
purpose of clarifying air quality under present operations. ATSDR's
rereview of reference material shows that Sample CF-SS-02 (taken in soil
in 1989) was not the single example of elevated PAHs; a few soil and
sediment samples taken in 1991 within and beyond the process area also
had some elevated PAHs.
ATSDR concludes that the available air, soil, and sediment data were
sufficient bases for our public health hazard determination. The document
has not been changed as a result of this comment. |
COMMENT 3. | The only substantial finding of contamination is for ambient air quality
(which the commenter says is based on disputed testing--see Comment 2).
Neither the groundwater, soil, surface water, or other media tests contain
any definitive findings of significant contamination beyond permissible
limits. |
Response: |
The media contaminant test data sections (Pages 8, 9, and 10 and Tables of
the Public Comment Release) do not express permissible limits. Instead,
the contaminant information presented there is analyzed further and
pertinent elements are discussed in the Public Health Implications Section.
The most important public health issues then are summarized in the
conclusions. Note that Conclusion 1. (Page 26 of the Public Comment
Release), says that there may be adverse health effects associated with
worker exposure to air, soil, and sediment. The document has not been
changed as a result of this comment. |
COMMENT 4. | The document does not identify any significant public health danger other
than a possible exposure of workers to benzene, for which the risk is
apparently manageable by protective clothing. |
Response: |
See response to comment 2. |
COMMENT 5. | The need for further testing should be carefully evaluated based upon the
demonstrated insufficiency of EPA's ambient air test. |
Response: |
See response to Comment 2. |
COMMENT 6. | The other sources of air releases in the neighborhood should be positively
ruled out before Chemfax is singled out as a public health hazard. |
Response: |
The public health hazard determination for Chemfax is based on worker exposures via soil and sediment, in addition to air. ATSDR believes that the available sampling data support that determination. Ambient air sampling has been recommended (Characterization Recommendation 2., Page 27 of the Public Comment Release) for the area potentially affected by other industries. The document has not been changed as a result of this comment. |