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PUBLIC HEALTH ASSESSMENT

CHEMFAX, INC.
GULFPORT, HARRISON COUNTY, MISSISSIPPI



APPENDIX A -- SITE MAPS

LIST OF FIGURES

Figure
Number        Title

  1.        Site Location Map

  2.        Site Map


Figure 1. Site Location Map



Figure 2. Site Map



APPENDIX B -- CONTAMINANT AND PATHWAY TABLES

LIST OF TABLES

Table
Number        Title

  1.        Ambient Air, On Site

  2.        Groundwater, On Site and Off Site

  3.        Surface Soil, On Site and Off Site

  4.        Subsurface Soil, On Site and Off Site

  5.        Sediment, On Site and Off Site

  6.        Surface Water, On Site and Off Site

  7.        Summary--Completed Exposure Pathways

  8.        Summary--Potential Exposure Pathways

  9.        Comparison of Estimated Exposed Dose to Health Guidelines for Chemfax Workers On Site, Other Nearby Workers and Various Residents Off Site.



LIST OF ACRONYMS, CODES, AND ABBREVIATIONS

CREG Cancer Risk Evaluation Guide
RMEG Reference Dose Media Evaluation Guide
MRL Minimum Risk Level
EMEG Environmental Media Evaluation Guide
AL Action Level
ppb parts per billion
J estimated value
4,4-DDD p,p'-dichlorodiphenyldichloroethane
NA none available
ND not detected



Table 1 Ambient Air, On Site
Contaminant Maximum Concentration*
in ppb
Year--1990
Selection Comparison
Value
ppb Source
1,1,1-trichloroethane A-0.38J
B-0.24J
C-0.23J
NA
1,2,4-trichlorobenzene A-0.19J
B-ND
C-0.19J
NA
1,2,4-trimethylbenzene A-12
B-ND
C-ND
NA
1,3,5-trimethylbenzene A-4.8
B-0.38
C-ND
NA
benzene A-18
B-ND
C-1.6
0.03 CREG
carbon tetrachloride A-0.14J
B-0.12J
C-0.12J
0.01 CREG
dichlorodifluoromethane A-0.97
B-0.66
C-0.90
NA
methylene chloride A-22
B-1.1
C-22
0.6 CREG
naphthalene A-12
B-2.4
C-ND
2 MRL
styrene A-120
B-0.7J
C-1.7
60 MRL
trichlorofluoromethane A-1.8
B-0.28
C-1.8
NA
trichlorotrifluoro-
methane
A-8.4
B-ND
C-ND
NA
xylene A-95
B-ND
C-ND
NA
A- Maximum value for sampling period
B- Maximum value reported at apparent upwind sample locations based on winds predominantly from south through southeast (four sample points--the eastern- and southern-most sample locations); may approximate quality of air moving on site at the time sampled was conducted.
C- Maximum value at apparent downwind sample locations based on winds predominantly from south through southeast (seven sample points--at the northern-most sample locations); may approximate quality of air moving off site at the time sampling was conducted.
* Data is from reference (1)


Table 2 Groundwater, On Site and Off Site
Contaminant Maximum Concentration *
in ppb
Year--1990***
Selection Comparison
Value
On Site Off Site ppb Source
2-methylnaphthalene A-1,800
B-ND
C-ND NA
dibenzofuran A-7J
B-ND
C-ND NA
methyl butyl ketone A-610J
B-ND
C-ND NA
phenanthrene A-410
B-ND
C-ND NA
aluminum A-120,000
B-ND
C-80,000 NA
calcium A-51,000
B-2,400
C-17,000 NA
cobalt A-93
B-ND
C-22 NA
iron A-120,000
B-ND
C-36,000J NA
lead A-190
B-ND
C-40 15 AL
magnesium A-29,000
B-540
C-17,000 NA
nickel A-210
B-ND
C-ND 200 RMEG
potassium A-20,000
B-ND
C-11,000 NA
sodium A-180,000
B-57,000 **
C-36,000J NA
Note: Samples were not filtered
A-On site monitoring wells
B-On site industrial wells
C-Off site monitoring wells, several hundred feet southeast and northeast of property
* Data is from reference (1), except for that marked **
** Data is from reference (2)
*** Concentrations from 1988 sampling activity were less than for 1990 sampling.


Table 3 Surface Soil, On Site and Off Site
Contaminant Maximum Concentration *
in ppb
Selection Comparison
Value
On Site (year) Off Site*** (year) ppb Source
2-methylnaphthalene 100,000 (1990) ND NA
benzo(a)anthracene 79,000J (1990) 140J (1990) NA
benzo(b/k)fluoranthene 18,000J (1990) 180J (1990) NA
benzo(ghi)perylene 91J (1990) ND NA
endrin ketone 26 ** (1988) ND NA
4,4-DDD 62J ** (1988) ND 3 CREG
ideno(1,2,3-cd)pyrene 61J (1990) ND NA
naphthalene 240,000 ** (1988) ND NA
phenanthrene 180,000J (1990) 98J (1990) NA
aluminum 15,000 (1990) 3,100 (1990) NA
calcium 84,000 ** (1988) 3,000 (1990) NA
cobalt 2 (1990) ND NA
copper 25 ** (1988) 12 (1990) NA
iron 20,000J (1990) 5,100J (1990) NA
lead 53 ** (1988) 53 (1990) NA
magnesium 170 ** (1988) ND NA
mercury 0.32J (1990) 0.40J (1990) NA
nickel 76 (1990) 2 (1990) NA
sodium 680 ** (1988) ND NA
* Data from reference (1), except for data marked **
** Data from reference (2)
*** Sampled a few hundred feet north of property


Table 4 Subsurface Soil, On Site and Off Site
Contaminant Maximum Concentration *
in ppb
Year--1990
Selection Comparison
Value
On Site Off Site ** ppb Source
2-methylnaphthalene 170,000 ND NA
benzyl butyl phthalate 920 ND NA
chrysene 160J ND NA
naphthalene 380,000 ND NA
phenanthrene 45,000 ND NA
aluminum 14,000 230 NA
calcium 1,400J 670 NA
cobalt 34 34 NA
copper 27 140 NA
iron 42,000J 2,900J NA
lead 98 72 NA
magnesium 1,300 720 NA
mercury 1.3J 0.32J NA
nickel 72 36 NA
potassium 860 ND NA
sodium 2,100 ND NA
* Data from reference (1)
** Sampled near bayou


Table 5 Sediment, On Site and Off Site
Contaminant Maximum Concentration*
in ppb
Year--1990
Selection Comparison
Value
On Site Off Site ppb Source
2-methylnaphthalene A-200,000
B-2,500
C-27,000
D-240
E-ND
NA
benzo(a)anthracene A-4,500
B-ND
C-ND
D-140J
E-ND
NA
benzo(b/k)fluoranthene A-1,600J
B-ND
C-ND
D-220J
E-ND
NA
benzo(ghi)perylene A-880J
B-ND
C-ND
D-ND
E-ND
NA
chrysene A-6,400
B-820J
C-ND
D-280J
E-ND
NA
dibenzofuran A-290J
B-ND
C-ND
D-ND
E-ND
NA
ideno(1,2,3-cd)pyrene A-41J
B-ND
C-ND
D-ND
E-ND
NA
naphthalene A-200,000
B-10,000
C-200,000
D-2,300
E-ND
NA
phenanthrene A-97,000
B-1,400J
C-ND
D-430J
E-ND
NA
aluminum A-630,000
B-4,300
C-2,000
D-1,900
E-140
NA
calcium A-16,000,000
B-2,600
C-1,700
D-34,000
E-ND
NA
cobalt A-2,000
B-29
C-ND
D-ND
E-ND
NA
copper A-22,000
B-19
C-81
D-38
E-ND
NA
iron A-14,000J
B-8,800J
C-7,100J
D-4,100J
E-180J
NA
lead A-12,000
B-210
C-31
D-21
E-ND
NA
magnesium A-220,000
B-ND
C-ND
D-ND
E-ND
NA
mercury A-ND
B-ND
C-0.41J
D-0.54J
E-ND
NA
nickel A-3,300
B-11
C-3
D-ND
E-ND
NA
potassium A-270
B-ND
C-ND
D-ND
E-ND
NA
sodium A-6,400
B-ND
C-ND
D-ND
E-ND
NA
A-Ditches and drainage holding ponds
B-Within diked tank area
C-Former cooling pond
D-Off-site ditch, east side of Three Rivers Road; sampled by Bayou and south of bayou
E-Background--off site
* All data from reference (1)


Table 6 Surface Water, On Site and Off Site
Contaminant Maximum Concentration *
ppb
Selection Comparison
Value
On Site (year) Off Site (year) ppb Source
naphthalene A-ND
B-26J ** (1988)
C-ND NA
aluminum A-47 ** (1988)
B-76 ** (1988)
C-860 (1990) NA
calcium A-ND
B-3,200 ** (1988)
C-4,600 (1990) NA
iron A-250J ** (1988)
B-460J ** (1988)
C-1,500J (1990) NA
magnesium A-150 ** (1988)
B-230 ** (1988)
C-ND NA
sodium A-55,000 ** (1988)
B-64,000 ** (1988)
C-24,000 (1990) NA
Note: Samples were not filtered
A-On site former cooling pond
B-On site drainage holding pond
C-Off site ditch, sampled by bayou
* Data is from reference (1) except for that marked **
** Data is from reference (2)


Table 7 Summary--Completed Exposure Pathways
PATHWAY NAME: AMBIENT AIR
(on site)
AMBIENT AIR
(off site)
PROCESS CHEMICALS SURFACE SOILS
(on site)
SURFACE SOILS
(off site)
Source: Chemfax and other industries Local industries Chemfax Chemfax, possibly
area industries
Source
uncertain
Medium: Air Air Process Chemicals Surface Soils Surface Soils
Exposure Point: On site Off site On site On Site Off site
Exposure Route: Inhalation Inhalation Skin contact, inhalation skin contact,
inhalation, ingestion
skin contact,
inhalation,
ingestion
Receptor Population: Workers Workers, shoppers, various residents, students Workers Workers Nearby workers & mental health residents
Exposure Period: Past, present, future Past, present, future Past, present, future Past, present, future Past, present, future
Estimated Number Exposed: 30 to 60 More than 500 less than 50 30 to 60 unknown
Table Continues....


Table 7 (Continued) Summary--Completed Exposure Pathways
PATHWAY NAME: SEDIMENT, SURFACE
WATER
(on site)
DITCH
SEDIMENT,
SURFACE WATER
(off site)
Source: Chemfax Local industries
Medium: Sediment, surface water Sediment, surface water
Exposure Point: On site Off site
Exposure Route: Skin contact, ingestion Skin contact
Receptor Population: Maintenance workers Maintenance workers
Exposure Period: Past, present, future Past, present, future
Number Exposed: Potentially about 5 Potentially about 5


Table 8 Summary--Potential Exposure Pathways
PATHWAY NAME: PRIVATE WELL
(on site)
PRIVATE WELLS
(off site)
INDUSTRIAL SEAWAY
Source: Chemfax Local industries Area runoff, industries
Medium: Groundwater Groundwater Surface water, fish
Exposure Point: On site Off site Off site
Exposure Route: Ingestion Ingestion, inhalation, skin contact Skin contact, ingestion
Receptor Population: Workers Consumers served by private wells Boaters, fishermen, swimmers
Exposure Period: Past Past, present, future Past, present, future
Number Exposed: Potentially about 60 Unknown Unknown


Table 9. Comparison of Estimated Exposed Dose to Health Guidelines for Chemfax Workers On Site, Other Nearby Workers and Various Residents Off Site.
Contaminant Exposure Pathway Health Guideline for Ingestion - mg/kg/day
Value Source Exceeded by Estimated Exposure Dose
2-methylnaphthalene Soil On Site None None None
Benzo(a)anthracene Soil On Site

Soil Off Site

None

None

None

None

None

None

Benzo(b/k)fluoranthene Soil On Site

Soil Off Site

None

None

None

None

None

None

Endrin Ketone Soil On site None None None
4,4-DDD* Soil Site None None None
Indeno(1,2,3-cd)pyrene Soil On Site None None None
Naphthalene Soil Site None None None
Phenanthrene Soil On Site

Soil Off Site

None

None

None

None

None

None

*4,4-DDD = p,p'dichlorodiphenyldichloroethane.

Table 9 (Continued) Comparison of Estimated Exposed Dose to Health Guidelines for Chemfax Workers on Site, Other Workers and Various Residents Off Site.
Contaminant Exposure Pathway Health Guideline for Ingestion - mg/kg/day
Value Source Exceeded by Estimated Exposure Dose
Aluminum Soil On Site
Soil Off Site
1
1
RfD*
RfD
No
No
Calcium Soil On Site
Soil Off Site
50
50/11.43
RDA** Adult
RDA Adult/Child
No
No
Cobalt Soil On Site None None None
Copper Soil On Site
Soil Off Site
0.02
0.02
ADI***
ADI
No
No
Iron Soil On Site
Soil Off Site
0.14
1.13/0.14
RDA Adult
RDA Child/Adult
No
No
Lead Soil On Site
Soil Off Site
None
None
None
None
None
None
Magnesium Soil On site 15.6/5 RDA Adult No
Mercury Soil On Site
Soil Off Site
0.002/0.007
0.002/0.007
I/A MRLa
I/A MRL
No
No
Nickel Soil On Site
Soil Off Site
0.02
0.02
RfD
RfD
No
No
Sodium Soil On Site 37.5-112 /15.45 ADI Adult No

*RfD = EPA's provisional Reference Dose.

**RDA = Calculated from Recommended Dietary Allowance.

***ADI = Calculated from the range of Estimated Safe and Adequate Dietary Intake.

aI/A MRL = Intermediate and Acute Minimal Risk Levels.


APPENDIX C -- RESPONSE TO PUBLIC COMMENTS

The Chemfax, Inc. Public Health Assessment was available for public review and comment from approximately October 1 to November 30. The comment period was announced in local newspapers. Copies were made available at the public library, and copies were sent to several individuals and organizations. A summary of comments received and our responses are presented in this section. The list of comments does not include any that raised health effect and other issues previously addressed in the Community Health Concerns Evaluation section.

COMMENT 1. Some of the chemicals at Chemfax are listed chemicals requiring reporting and safe handling; none are particularly dangerous.

Response:

Essentially all chemicals have a capacity to pose a hazard to public health; many pose a hazard at very low concentrations and human exposure levels. The document has not been changed as a result of this comment.

COMMENT 2. The public health hazard determination stated in Paragraph 1 in the Conclusions Section is based on testing by EPA and others in the past. That sampling is disputed as being subject to errors and irregularities. Three key air samples (CF-AT-03, CF-AT-04, and CF-AT-05) and a key soil sample (CF-SS-02) were taken in the immediate vicinity of process operations where a minor spill of raw material had occurred the day of the sampling. As a result, those data points reflect then current operations conditions that are not present today.

Response:

ATSDR's public health hazard determination for workers is based on air, soil, and sediment data. Reference information show that air sampling was conducted in the process area on May 31, 1990 and beyond the process area on May 31, June 1, and June 5 of that year. Concentrations were greatest in the process area; ATSDR considers some of the levels reported there to be of public health concern for the workers. For later sampling elsewhere on the property, some of the lower concentrations detected are considered substantive from a worker health perspective. ATSDR also notes that references show two soil samples designated CF-SS-02 were taken; one in 1988 and one in 1990. The soil sample the commenter identifies as being in the process area was taken in 1988. Thus, the minor spill mentioned as a confounding factor for the ambient air data would have been cleaned up in 1988, long before the 1990 air sampling. Our recommendation for additional ambient air sampling (Characterization Recommendation 1., Page 27 of the Public Comment Release) is for the purpose of clarifying air quality under present operations. ATSDR's rereview of reference material shows that Sample CF-SS-02 (taken in soil in 1989) was not the single example of elevated PAHs; a few soil and sediment samples taken in 1991 within and beyond the process area also had some elevated PAHs.

ATSDR concludes that the available air, soil, and sediment data were sufficient bases for our public health hazard determination. The document has not been changed as a result of this comment.

COMMENT 3. The only substantial finding of contamination is for ambient air quality (which the commenter says is based on disputed testing--see Comment 2). Neither the groundwater, soil, surface water, or other media tests contain any definitive findings of significant contamination beyond permissible limits.

Response:

The media contaminant test data sections (Pages 8, 9, and 10 and Tables of the Public Comment Release) do not express permissible limits. Instead, the contaminant information presented there is analyzed further and pertinent elements are discussed in the Public Health Implications Section. The most important public health issues then are summarized in the conclusions. Note that Conclusion 1. (Page 26 of the Public Comment Release), says that there may be adverse health effects associated with worker exposure to air, soil, and sediment. The document has not been changed as a result of this comment.

COMMENT 4. The document does not identify any significant public health danger other than a possible exposure of workers to benzene, for which the risk is apparently manageable by protective clothing.

Response:

See response to comment 2.

COMMENT 5. The need for further testing should be carefully evaluated based upon the demonstrated insufficiency of EPA's ambient air test.

Response:

See response to Comment 2.

COMMENT 6. The other sources of air releases in the neighborhood should be positively ruled out before Chemfax is singled out as a public health hazard.

Response:

The public health hazard determination for Chemfax is based on worker exposures via soil and sediment, in addition to air. ATSDR believes that the available sampling data support that determination. Ambient air sampling has been recommended (Characterization Recommendation 2., Page 27 of the Public Comment Release) for the area potentially affected by other industries. The document has not been changed as a result of this comment.

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