What is Reid vapour pressure?

Under the ASTM Method D 323 (Reid vapour pressure), it is the absolute vapour pressure exerted by a liquid at 100°F. The higher this value, the more volatile the sample and the more readily it will evaporate. Unlike distillation data, vapour pressure provides a single value that reflects the combined effect of the individual vapour pressure of the different petroleum fractions in accordance with their mole ratios. It is thus possible for two wholly different products to exhibit the same vapour pressure at the same temperature - provided the cumulative pressures exerted by the fractions are the same. A narrow-cut distillate, for example, may exhibit the same vapour pressure as that of a dumbbell blend, where the effect of heavy fractions is counterbalanced by that of the lighter ones. In conjunction with other volatility data. Reid vapour pressure plays a role in the prediction of gasoline performance.

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