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Agent Name 1,6-Diaminohexane
Alternative Name 1,6-Hexanediamine
CAS Number 124-09-4
Formula C6-H16-N2
Major Category Nitrogen Compounds
Synonyms 1,6-Diamino-n-hexane; 1,6-Diaminohexane; 1,6-Hexamethylenediamine; 1,6-Hexanediamine; 1,6-Hexanediamine (solution); 1,6-Hexylenediamine; HMDA; Hexane, 1,6-diamino-; [ChemIDplus] UN1783(solution); UN2280(solid)
Category Amines, Aliphatic
Description Colorless solid; [Hawley] Hygroscopic; [ICSC] Has an ammonia-like or fishy odor; [CHEMINFO] White solid; [MSDSonline]
Sources/Uses Used as an intermediate to make polyamides with applications in fiber, plastics, polyurethane coatings and adhesives, specialty nylons (monofilaments and inks), and specialty chemicals (biocides, petroleum additives, and phenol purification); [eChemPortal: SIDSUNEP]
Comments A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation of high concentrations may cause pulmonary edema; [ICSC] Exposed workers complain of skin and respiratory tract irritation; [ACGIH] Liver injury in workers has been reported; [HSDB] See "Trimethylhexanediamine/Isophorone diamine."
Exposure Assessment
Skin Designation (ACGIH) No
TLV (ACGIH) 0.5 ppm
Vapor Pressure 0.4 mm Hg
Lethal Concentration LC (rats) > 200 ppm/4h
Explanatory Notes Flash point = 85 deg C; [ICSC]
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
Hepatotoxin Hepatotoxin, Secondary
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: HEXAMETHYLENE DIAMINE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:





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Last updated: January, 2009