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Agent Name Ethanethiol
Alternative Name Ethyl mercaptan
CAS Number 75-08-1
Formula C2-H6-S
Major Category Other Classes
Synonyms 1-Mercaptoethane; Ethanethiol; Ethyl hydrosulfide; Ethyl sulfhydrate; Ethyl thioalcohol;
LPG ethyl mercaptan 1010; Mercaptoethane; Thioethanol; Thioethyl alcohol; [ChemIDplus] UN2363
Category Thiols
Description Colorless liquid with a strong, skunk-like odor; Note: A gas above 95 degrees F; [NIOSH]
Sources/Uses Used as an odorant for natural gas; used as an intermediate in the plastic, pesticide, and organic chemical industries; [ACGIH]
Comments Its toxicity in rats and mice is similar to that of butyl mercaptan. Acutely, it is about 1/5 as toxic as hydrogen sulfide. Human volunteers exposed to 1mg/m3 (0.5 ppm) experienced no symptoms, while those exposed to 10 mg/m3 (4 ppm) complained of mucous membrane irritation and fatigue. [ACGIH] Liver necrosis occurs in animals receiving sublethal doses. [HSDB]
Exposure Assessment
Skin Designation (ACGIH) No
TLV (ACGIH) 0.5 ppm
PEL (OSHA)Ceiling(OSHA) = 10 ppm
MAK 0.5 ppm
IDLH (NIOSH) 500 ppm
Excerpts from Documentation for IDLHs Basis for original (SCP) IDLH: The chosen IDLH is based on the mouse 4�hour LC50 of 2,770 ppm [Fairchild and Stokinger 1958 cited by ACGIH 1971]. . . . Human data: None relevant for use in determining the revised IDLH.
Vapor Pressure 529 mm Hg
Odor Threshold Low 9.8 x 10 -05 ppm
Odor Threshold High 0.003 ppm
Lethal Concentration LC50 (rats) = 4,420 ppm/4H
Explanatory Notes Detection odor threshold from AIHA (mean = 0.00035 ppm); Flash point = -48.3 C;
Flammability (NFPA) 4: burns readily
Adverse Effects
Hepatotoxin Hepatotoxin, Secondary
Other Poison Chemical Asphyxiant
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: ETHYL MERCAPTAN  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Other InformationNo other related information on this agent was found.





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Last updated: January, 2009