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Agent Name Mercaptobenzothiazole
CAS Number 149-30-4
Formula C7-H5-N-S2
Major Category Plastics & Rubber
Synonyms 2(3H)-Benzothiazolethione; 2-Benzothiazolethiol; 2-Benzothiazolinethione; 2-Benzothiazolyl mercaptan; 2-MBT; 2-Mercaptobenzothiazole; 2-Mercaptobenzthiazole; 2-Mercptobenzothiazole; 2-Merkaptobenzotiazol [Polish]; 2-Merkaptobenzthiazol [Czech]; AG 63; Accel M; Accelerator M; Benzothiazole, mercapto-; Benzothiazole-2-thione; Benzothiazolethiol; Captax; Dermacid; Ekagom G; Kaptaks; Kaptax; Kaptax [Czech]; MBT; Mebetizole; Mebithizol; Mercaptobenzothiazol; Mercaptobenzothiazole; Mercaptobenzothiazole (VAN); Mercaptobenzthiazole; Mertax; Nuodeb 84; Nuodex 84; Pennac MBT powder; Pneumax MBT; Rokon; Rotax; Royal MBT; Soxinol M; Sulfadene; Thiotax; USAF XR-29; Vulkacit M; Vulkacit mercapto; Vulkacit mercapto/C; [ChemIDplus]
Category Rubber Additives
Description Yellowish to tan crystalline powder; [HSDB]
Sources/Uses Nonrubber sources of exposure include metalworking fluids, antifreezes, greases, anticorrosive agents, adhesives, detergents, and veterinary products. [Marks, p. 101] Allergic contact dermatitis in shoemakers; [Marks] A known skin sensitizer, mercaptobenzothiazole is used less and less as an anti-corrosion agent in metalworking fluids. [Kanerva, p. 692] "Metal indicators are organic compounds that form specifically colored metal ion complexes in aqueous media. These dye reactions can be employed for detection of the equivalence point in volumetry (complexometry), as well as for concentration determinations in colorimetry or photometry." 2-Mercaptobenzothiazole is used for the photometric determination of Au, Cd, Cu, Pb, and Pd. [Ullmann]
Comments A rubber accelerator, MBT is the most common cause of shoe allergy and second to the thiurams as the cause of glove contact dermatitis. [Marks, p. 100-2] An eye irritant; May cause skin sensitization after prolonged contact; [ICSC]
Exposure Assessment
Skin Designation (ACGIH) Not evaluated
MAK 4 mg/m3, inhalable fraction
Vapor Pressure 0.000464 mm Hg
Odor Threshold Low 2 ppm
Lethal Concentration LC50 (rats) > 1,270 mg/m3
Explanatory Notes Flash point = 392 deg F; Odor threshold from CHEMINFO;
Adverse Effects
Skin Sensitizer Yes
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: MERCAPTOBENZOTHIAZOLE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009