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Agent Name Methane
CAS Number 74-82-8
Formula C-H4
Major Category Toxic Gases & Vapors
Synonyms Biogas; Fire Damp; Marsh gas; Methane; Methyl hydride; R 50 (refrigerant); [ChemIDplus] UN1971; UN1972;
Category Simple Asphyxiants
Description Colorless, odorless gas; [Merck Index]
Sources/Uses In the USA 85% of natural gas is methane. [Merck Index] Produced by decaying matter in swamps and marshes; [Hawley]
Comments The "Critical Effects" for aliphatic hydrocarbon gases are CNS depression and cardiac sensitization. "From a toxicologic standpoint, methane and ethane are practically inert; however, at very high concentrations, they act as a simple asphyxiant and can cause suffocation by displacement of oxygen from breathing atmosphere, below the critical level of 16% oxygen that is required to sustain life." [ACGIH] Simple asphyxiant; Evaporating liquid can cause frostbite; [ICSC]
Exposure Assessment
Skin Designation (ACGIH) No
TLV (ACGIH) 1000 ppm
Explanatory Notes For TLV, see Aliphatic hydrocarbon gases: Alkane (C1-C4); [ACGIH]; Flash point = -306 deg F;
Flammability (NFPA) 4: burns readily
Adverse Effects
Other Poison Simple Asphyxiant
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: METHANE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:
Activities Activities with risk of exposure:





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Last updated: January, 2009