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Agent Name Cyanogen chloride
CAS Number 506-77-4
Formula C-Cl-N
Major Category Toxic Gases & Vapors
Synonyms Chlorcyan; Chlorine cyanide; Chlorine cyanide (ClCN); Chlorocyan; Chlorocyanide; Chlorocyanogen; Chlorure de cyanogene [French]; Cyanogen chloride; [ChemIDplus] UN1589
Category Corrosive Gases
Description Colorless gas or liquid (below 55 degrees F) with an irritating odor; Note: Shipped as a liquefied gas. A solid below 20 degrees F. Forms cyanide in the body; [NIOSH]
Sources/Uses Used in organic synthesis and as a military poison gas; may be generated in a reaction of hypochlorite and cyanide solutions in waste water treatment; [ACGIH] Used in metal cleaning and ore refining; [ATSDR ToxProfiles]
Comments Liquid causes second or third degree burns after short contact; [CHRIS] In animal inhalation studies, cyanogen chloride causes severe irritation of the respiratory tract and pulmonary edema. Workers treating cyanide plating solutions with hypochlorite had to leave the work area because of eye and nose irritation when the air concentration was measured at 0.7 ppm (1.78 mg/m3). [ACGIH] Effects are similar to those of hydrogen cyanide; A pulmonary irritant and lacrimator; [HSDB]
Exposure Assessment
Skin Designation (ACGIH) No
TIH Yes
Ceiling (ACGIH) 0.3 ppm
Odor Threshold Low 1 ppm
Explanatory Notes The Guide from the Emergency Response Guidebook is for "cyanogen chloride, inhibited." Detection odor threshold ; [CHEMINFO]
Reference Link International Chemical Safety Cards (WHO/IPCS/ILO)
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
Lacrimator Yes
Other Poison Chemical Asphyxiant
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: CYANOGEN CHLORIDE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009