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Agent Name 3-Chloro-2-methyl-1-propene
Alternative Name Methallyl chloride
CAS Number 563-47-3
Formula C4-H7-Cl
Major Category Other Classes
Synonyms 3-Chloro-2-methylprop-1-ene; 3-Chloro-2-methylpropene; 1-Chloro-2-methyl-2-propene; 2-Methallyl chloride; 2-Methyl-2-propenyl chloride; 2-Methyl-allylchlorid [German]; 2-Methylallyl chloride; 3-Chlor-2-methyl-prop-1-en [German]; 3-Chloro-2-Methylpropene; 3-Chloro-2-methylpropene (IUPAC); 3-Chloroisobutylene; 3-Cloro-2-metil-prop-1-ene [Italian]; Chlorue de methallyle [French]; Chlorure de methallyle [French]; Cloruro di metallile [Italian]; Isobutenyl chloride; MAC; Methallyl chloride; Propene, 3-chloro-2-methyl-; beta-Methylallyl chloride; gamma-Chloroisobutylene; [ChemIDplus] UN2554
Category Halogenated Aliphatics
Description Colorless to yellow liquid, with pungent odor; [ICSC] Odor: stench; [MSDSonline]
Sources/Uses Used to make insecticides, plastics, pharmaceuticals, and other chemicals; Also used as a fumigant for grains, tobacco, and soil; [Hawley]
Comments A skin, eye, and respiratory tract irritant; Tear drawing; Inhalation of high concentrations may cause CNS effects; May cause skin sensitization after prolonged contact; [ICSC] Dangerous fire risk; Explosive limits in air are 3.2 - 8.1%; [Hawley] Harmful by inhalation and ingestion; Causes burns; May cause skin sensitization; [MSDSonline]
Exposure Assessment
Vapor Pressure 102 mm Hg
Lethal Concentration LC50 (rats) = 34,000 mg/m3/30 min
Explanatory Notes Flash point = -12 deg C; [HSDB]
Flammability (NFPA) 3: may ignite at ambient temperature
Adverse Effects
Dermatotoxin Skin Burns
Skin Sensitizer Yes
Lacrimator Yes
Neurotoxin CNS Solvent Syndrome
Hepatotoxin Hepatotoxin, Secondary
IARC Carcinogen Not Classifiable
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: 3-CHLORO-2-METHYL-1-PROPENE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009