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Agent Name Stibine
CAS Number 7803-52-3
Formula H3-Sb
Major Category Toxic Gases & Vapors
Synonyms Antimony hydride; Antimony trihydride; Hydrogen antimonide; [NIOSH] UN2676
Category Hydrides
Description Colorless gas with a disagreeable odor like hydrogen sulfide; [NIOSH]
Sources/Uses Stibine gas may be formed during battery overcharging or when antimony compounds come in contact with an acid plus a reducing substance such as zinc. Stibine is used as a dopant in the microelectronics industry. [ACGIH]
Comments A few cases of occupational stibine poisoning have been reported. Like arsine, stibine is a hemolytic agent that also injures the kidneys and liver. [ACGIH] A respiratory tract irritant that may have effects on the blood (hemolysis), liver, kidneys, and CNS; [ICSC] Liquefied gas may cause burns or frostbite; [CAMEO] Animals exposed to lethal concentrations develop anemia, hemoglobinuria, and acute renal failure. [HSDB]
Exposure Assessment
Skin Designation (ACGIH) No
TIH Yes
TLV (ACGIH) 0.1 ppm
PEL (OSHA) 0.1 ppm
IDLH (NIOSH) 5 ppm
Excerpts from Documentation for IDLHs Other animal data: It has been reported that exposure of dogs and cats to 40 to 45 ppm for 1 hour has proven dangerous [Webster 1946].
Lethal Concentration LCLo (mice) = 100 ppm/1H
Flammability (NFPA) 4: burns readily
Adverse Effects
Anemia Anemia, Hemolytic
Hepatotoxin Hepatotoxin, Secondary
Nephrotoxin Yes
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: STIBINE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009