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Agent Name Oxalic acid
CAS Number 144-62-7
Formula C2-H2-O4
Major Category Other Classes
Synonyms Acide oxalique [French]; Acido ossalico [Italian]; Acidum oxalicum; Aktisal; Aquisal; Ethanedioic acid; Kyselina stavelova [Czech]; Oxaalzuur [Dutch]; Oxalate; Oxalic acid; Oxalsaeure [German]; Oxiric acid; [ChemIDplus]
Category Organic Acids
Description Colorless, odorless powder or granular solid. [Note: The anhydrous form (COOH)2 is an odorless, white solid.]; [NIOSH]
Sources/Uses Used in rust removers, radiator cleaners, ink eradicators, leather tanning compounds, textile bleaches, and in vitro anticoagulants. [ACGIH] Several species of plants contain soluble and insoluble oxalate salts. [Olson, p. 296] Used in photography (toner and platinum printing); Also used as a mordant in textile dyeing; [www.ci.tucson.az.us/arthazards/medium.html]
Comments Liquid causes second or third degree burns after short contact. [CHRIS] Solutions of 5-10% cause irritation of the skin after prolonged exposure. [ACGIH] Solutions range from irritating to corrosive. Inhalation of high concentrations may induce chemical pneumonitis. Ingestion of oxalic acid or soluble oxalate compounds causes acute hypocalcemia and deposition of calcium oxalate crystals in the brain, heart, kidney, and other organs. In plant poisoning cases, ingestion of insoluble oxalate compounds causes irritation and swelling of the mouth, throat, and esophagus. [Olson, p. 296] A corrosive substance that can cause pulmonary edema; [ICSC]
Exposure Assessment
Skin Designation (ACGIH) No
TLV (ACGIH) 1 mg/m3
STEL (ACGIH) 2 mg/m3
PEL (OSHA) 1 mg/m3
IDLH (NIOSH) 500 mg/m3
Excerpts from Documentation for IDLHs Human data: It has been reported that the lethal oral dose is 15 to 30 grams [Webster 1930]. [Note: An oral dose of 15 to 30 grams is equivalent to a 30�minute exposure to 10,000 to 20,000 mg/m3 assuming a 50 liter per minute breathing rate and 100% absorption.]
Vapor Pressure 0.000234 mm Hg
Flammability (NFPA) 1: must be preheated
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: OXALIC ACID  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:
Activities Activities with risk of exposure:





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Last updated: January, 2009