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Agent Name Sulfur monochloride
CAS Number 10025-67-9
Formula Cl2-S2
Major Category Toxic Gases & Vapors
Synonyms Chlorosulfane; Disulfur dichloride; Siarki chlorek [Polish]; Sulfur chloride; Sulfur chloride (di); Sulfur subchloride; Thiosulfurous dichloride; [ChemIDplus] UN1828
Category Other Toxic Gases & Vapors
Description Light-amber to yellow-red, oily liquid with a pungent, nauseating, irritating odor; [NIOSH]
Sources/Uses ". . . used in vulcanizing rubber, chemical synthesis, wood hardening, textile finishing, and gold extraction." [ACGIH]
Comments Highly corrosive to skin; [Quick CPC] Liquid causes second or third degree burns after short contact; [CHRIS] Sulfur monochloride is a respiratory irritant with a nauseating odor; it hydrolyzes into HCl and SO2. [ACGIH] "Tear drawing." A corrosive substance that can cause pulmonary edema; [ICSC]
Exposure Assessment
Skin Designation (ACGIH) No
TIH Yes
Ceiling (ACGIH) 1 ppm
PEL (OSHA) 1 ppm
IDLH (NIOSH) 5 ppm
Excerpts from Documentation for IDLHs Other animal data: It has been reported that cats have tolerated 15�minute exposures to 12 ppm, while 48 ppm could lead to death after a few days [Flury and Zernik 1931].
Vapor Pressure 7 mm Hg
Lethal Concentration LC50 (rats) = 2,500 mg/m3/4H
Explanatory Notes Flash point = 245 deg F;
Flammability (NFPA) 1: must be preheated
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
Lacrimator Yes
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: SULFUR MONOCHLORIDE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009