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Agent Name Chromium hexacarbonyl
CAS Number 13007-92-6
Formula C6-Cr-O6
Major Category Metals
Synonyms Hexacarbonyl chromium; Chromium carbonyl; [ChemIDplus] UN3466
Category Metals, Organic Compounds
Description White solid; Sublimes at room temperature; [CAMEO] Insoluble in water; Danger of explosion if heated; [MSDSonline]
Sources/Uses Used as a catalyst for olefin polymerization, a gasoline additive, and to prepare chromous oxide; [Merck Index]
Comments Skin contact: dermatitis; Inhalation: perforation of nasal septum, lacrimation, and acute hepatitis; [CAMEO] A skin, eye, and respiratory tract irritant; Harmful if ingested, absorbed through skin, or inhaled; Decomposition of carbonyl compounds can yield carbon monoxide; [MSDSonline] See "Chromium and compounds."
Exposure Assessment
Vapor Pressure 0.26 mm Hg
Lethal Concentration LCLo (rats) = 35 mg/ m3/30min
Explanatory Notes VP = 1 mm Hg at 97 deg F; [CAMEO] Explodes at 204 deg C; [Hawley] VP = 0.26 mmHG at 20 deg C; mp = 150 deg C; [MSDSonline] UN3466 is "Metal carbonyls, solid, n.o.s. [ERG 2008]
Adverse Effects
Hepatotoxin Hepatotoxin, Secondary
Links to Other NLM Databases
Toxicity Information Search TOXNET
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:





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Last updated: January, 2009