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Agent Name Oleum
CAS Number 8014-95-7
Formula H2-O4-S.O3-S
Major Category Toxic Gases & Vapors
Synonyms Fuming sulfuric acid; Oleum; Oleum iodisum; Sulfur trioxide, mixt. with sulfuric acid; Sulfuric acid fuming; Sulfuric acid mixture with sulfur trioxide; Sulfuric acid, mixt with sulfur trioxide; [ChemIDplus] UN1831
Category Acids
Description Colorless to brown, fuming, viscous, and hygroscopic liquid; [ICSC]
Sources/Uses Used to make surfactants, dyes, nitrocellulose, explosives, and caprolactam; Also used in petroleum refining and as a drying agent for chlorine & nitric acid; [HSDB] Oleum is a solution of sulfur trioxide in 100% sulfuric acid used in the synthesis of organic chemicals; [Britannica]
Comments Highly corrosive to skin; [Quick CPC] A corrosive substance that can cause pulmonary edema; May cause erosion of teeth enamel; [ICSC] Can cause severe burns of the skin and eyes; [CAMEO] See "Sulfuric acid."
Exposure Assessment
TLV (ACGIH) 0.2 mg/m3, thoracic fraction
PEL (OSHA) 1 mg/m3
MAK 0.1 mg/m3, inhalable fraction
IDLH (NIOSH) 15 mg/m3
Lethal Concentration LC50 (rats) = 347 ppm/1h
Explanatory Notes Cancer designations refer to sulfuric acid contained in strong inorganic acid mists; [ACGIH]
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
IARC Carcinogen Known Carcinogen
Links to Other NLM Databases
Toxicity Information Search TOXNET
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: January, 2009