Bibliographic Citation

 
US 5751018
Semiconductor nanocrystals covalently bound to solid inorganic surfaces using self-assembled monolayers
View USPTO link (Link will open in a new window)
01/01/1998
Alivisatos, A. Paul (Berkeley, CA); Colvin, Vicki L. (Berkeley, CA)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
AC03-76SF00098
semiconductor; nanocrystals; covalently; bound; solid; inorganic; surfaces; self-assembled; monolayers; methods; described; attaching; semiconductor; nanocrystals; solid; inorganic; surfaces; self-assembled; bifunctional; organic; monolayers; bridge; compounds; techniques; relies; formation; self-assembled; monolayers; surfaces; exposed; solutions; nanocrystals; bridge; compounds; bind; crystals; anchor; surface; technique; attaches; nanocrystals; coated; bridge; compounds; surfaces; analyses; indicate; presence; quantum; confined; clusters; surfaces; nanolayer; level; materials; allow; electron; spectroscopies; completed; condensed; phase; clusters; represent; step; towards; synthesis; organized; assembly; clusters; products; disclosed; covalently bound; semiconductor nanocrystals; semiconductor nanocrystals; semiconductor nanocrystal; semiconductor nanocrystal; self-assembled monolayers; self-assembled monolayers; solid inorganic; solid inorganic; condensed phase; self-assembled monolayer; self-assembled monolayer; inorganic surfaces; inorganic surfaces /257/
Regents of University of CAlifornia (Oakland, CA)
Methods are described for attaching semiconductor nanocrystals to solid inorganic surfaces, using self-assembled bifunctional organic monolayers as bridge compounds. Two different techniques are presented. One relies on the formation of self-assembled monolayers on these surfaces. When exposed to solutions of nanocrystals, these bridge compounds bind the crystals and anchor them to the surface. The second technique attaches nanocrystals already coated with bridge compounds to the surfaces. Analyses indicate the presence of quantum confined clusters on the surfaces at the nanolayer level. These materials allow electron spectroscopies to be completed on condensed phase clusters, and represent a first step towards synthesis of an organized assembly of clusters. These new products are also disclosed.

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