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PUBLIC HEALTH ASSESSMENT

ASARCO INCORPORATED (GLOBE PLANT)
DENVER, DENVER COUNTY, COLORADO



APPENDICES

Appendix A -- Figures
Appendix B -- Air Data
Appendix C -- Soil Data
Appendix D -- Exposure Pathways
Appendix E -- Estimated Exposure Doses
Appendix F -- Public Comments


APPENDIX A

FIGURES 1-4


Figure 1. Site Location

Figure 2. Globe Plant Plan

The following figure was not available in electronic format for conversin to HTML at the time of preparation of this document. To obtain a hard copy of the document, please contact:

Agency for Toxic Substances and Disease Registry
Division of Health Assessment and Consultation
Attn: Chief, Program Evaluation, Records, and Information Services
Branch, E-56
1600 Clifton Road NE, Atlanta, Georgia 30333


Figure 3.



Figure 4. Priority Sample Population



APPENDIX B

AIR DATA

TABLE 3. ON-SITE AIR QUALITY (1987 - 1992)

Monitoring Stations
Metal Year Bookstore
58 samples/yr
Old Office Site
58 samples/yr
Nutech
58 samples/yr


Concentration (µg/m3)
Max. Avg. Max. Avg. Max. Avg.
Cadmium 1992
1991
1990
1989
1988
1987**
0.054
0.233
0.053
0.184
0.142*
0.165
0.019
NC
0.027
0.041
0.018*
NC
0.090
0.136
0.603
0.447
0.429
0.589
0.046
0.028
0.080
0.065
0.048
NC
0.195
0.093
0.879
0.589
0.440
0.745
0.032
NC
0.062
0.072
0.060
NC
Arsenic*** 1992
1991
1990
1989
1988
1987**
<0.022
0.018
0.021
0.022
0.032*
<0.010
0.009
NC
0.010
0.007
NC
NC
0.021
0.064
0.022
0.022
0.04
0.095
0.008
NC
0.009
0.009
0.012
NC
0.021
0.074
0.098
0.042
0.05
0.087
0.009
NC
0.007
0.007
0.012
NC
Lead 1992
1991
1990
1989
1988
1987**
0.23
0.18
0.25
0.33
0.66*
0.64
0.11
NC
0.11
0.12
NC
NC
0.16
0.34
1.4
0.38
0.79
1.57
0.17
NC
0.18
0.15
0.21
NC
0.49
0.30
1.4
0.27
1.39
1.64
0.14
NC
0.14
0.13
0.23
NC
TSP 1992
1991
1990
1989
1988
1987**
214.8
229.1
241.7
287.6
248.9*
738.5
113.80
108.34
92.19
111.00
122.80
NC
165.6
217.9
234.9
224.3
188.3
281.3
85.01
NC
75.78
86.27
NC
NC
211.3
228.2
236.1
166.8
228.5
308.5
100.55
NC
82.76
83.46
NC
NC
TSP = Total Suspended Particulates
NC = Not calculated
* March through May data gaps, only 38 samples compared to about 58 samples per year in 1989, station relocated to site second quarter 1988.
** Based on 6 months of data
*** Concentrations were usually below the detection limit so half of the minimal detectable activity was used in averaging.
1993 data were not available.
The September 1982 NEIC sampling showed average results in µg/m3 of 0.022 - 0.095 cadmium, 0.003 - 0.014 arsenic, 0.641 - 0.955 lead, and 0.113 - 0.243 zinc.


TABLE 4. OFF-SITE AIR QUALITY (1987 - 1993)

Monitoring Stations
Metal Year Clinicare
180- 361 samples/yr
Forklift City
59 samples/yr
Background, Adams City*
56 samples/yr


Concentration (µg/m3)
Max. Avg. Max. Avg. Max. Avg.
Cadmium 1993
1992
1991
1990
1989
1988
1987
2.027*
3.900
0.713
0.750
ND
ND
ND
0.077*
0.054
0.035
0.073
ND
ND
ND
ND
0.487
2.161
0.433
1.136
0.577
1.555
ND
0.054
0.071
0.063
0.092
0.046
NC
0.024
0.100
0.009
0.016
ND
ND
ND
0.003
0.004
0.002
0.004
ND
ND
ND
Arsenic 1993
1992
1991
1990
1989
1988
1987
0.070*
0.015
0.300
0.028
ND
ND
ND
0.002*
0.002
0.005
0.004
ND
ND
ND
ND
<0.022
0.016
0.022
0.011
0.011
0.010
ND
0.006
NC
0.006
0.006
0.006
0.006
0.003
0.011
0.004
0.015
ND
ND
ND
0.001
0.002
0.004
0.004
ND
ND
ND
Lead 1993
1992
1991
1990
1989
1988
1987
1.00*
0.50
0.43
0.72
ND
ND
ND
0.10*
0.09
0.07
0.14
ND
ND
ND
ND
1.21
0.53
1.66
0.79
6.34
2.48
ND
0.24
NC
0.28
NC
0.50
NC
0.23
0.17
0.14
0.22
ND
ND
ND
0.03
0.03
0.03
0.05
ND
ND
ND
TSP 1993
1992
1991
1990
1989
1988
1987
308*
368
359
246
ND
ND
ND
101*
106
105
97
ND
ND
ND
ND
311.6
239.5
190.5
241.8
187.2
293.1
ND
96.5
89.0
75.7
90.2
95.7
NC
261
319
211
228
ND
ND
ND
100
90
82
79
ND
ND
ND
TSP = Total Suspended Particulates
ND = No data
NC = Not calculated
Clinicare is about a half block North East of the North East corner of the ASARCO property.
The Forklift City site is north of the site.
The Adams City site is approx. 3 miles NE of ASARCO.
*1993 data for Clinicare represents 1/1/93 through 6/30/93 or 180 samples, the other years represent the entire year or from 278 to 361 samples.



APPENDIX C

SOIL DATA

TABLE 5. ON-SITE SOIL (RI, App 9) SURFACE SOIL 0-2"
August & June 1985, August 1986/ July 1987
METAL CONC. RANGE
(total metals)
YEAR
SAMPLED
COMPARISON VALUE (CV) FOR INGESTION - CHILD**** FREQ >CV

ppm
ppm Source
Antimony* 9 - 104 1985 20 RMEG 15/16
Arsenic 19 - 6770 1986/87 0.4
20
CREG
EMEG
9/9
8/9
3** - 535 1985 0.4
20
CREG
EMEG
17/17
17/17***
Cadmium 21 - 9900 1986/87 40 EMEG 7/9
21 - 272 1985 40 EMEG 14/17
Lead 120 - 11,500 1986/87 None --- 6/9 > bkgrd of 413 ppm
66 - 1875 1985 None --- 11/17*** >bkgrd of
413 ppm
Manganese 93 - 1000 1985 300 RMEG 12/17
Selenium 0.5** - 108 1985 100 IEMEG 2/17
Zinc 285 - 107,500 1987/87 20,000 RMEG 1/9
114 - 5200 1985 20,000 RMEG 0/17
*Analyses by Globe lab only, not a Quality Assurance Project Plan (QAPP) lab
** Widely varying results between labs at this sample location
*** When two or more labs analyzed a sample and the results varied on either side of the C.V. (Comparison Value), an average was taken to determine if the conc. > C.V.
The Industrial Drainage Ditch (IDD) samples were considered to be on-site.
**** Arsenic and cadmium were the only metals exceeding comparison values for an adult. The comparison values are 200 and 500 ppm, respectively with 11/26 samples >C.V. for As and 4/26 samples >C.V. for Cd.
On-site maximums that exceed those found at 0-2" include:
Arsenic at 15,250 ppm, 16' depth, former neutralization pond
Antimony at 293 ppm, 0.5-1', IDD
Cadmium at 14,708 ppm, 0-6" depth, center of site-terrace escarpment
Lead at 16,000 ppm, 2-6" depth, lead slag pile
Manganese at 1525 ppm, 2-6", NW corner
Zinc at 117,500 ppm, 7'& 11' depths, former neutralization pond


TABLE 6. OFF-SITE SOIL (RI, App 9) SURFACE SOIL 0-2"

August & June 1985, August 1986/ July 1987
METAL CONC. RANGE
(total)
YEAR
SAMPLED
COMPARISON VALUE (CV) FOR INGESTION - CHILD**** FREQ >CV

ppm
ppm Source
Antimony* 15 - 442 1985 20 RMEG 28/34
Arsenic 1.2 - 113 1986/87 0.4
20
CREG
EMEG
136/136
42/136
<1** - 168** 1985 0.4
20
CREG
EMEG
39/39
29/39
Cadmium 0.48 - 175 1986/87 40 EMEG 18/136
5 - 398 1985 40 EMEG 21/39***
Lead 20 - 1150 1986/87 None --- 19/136 > bkgrd of 413 ppm
58 - 1500 1985 None --- 11/39*** >bkgrd of
413 ppm
Manganese 210 - 860 1985 300 RMEG 22/39
Selenium 1 - 153 1985 100 IEMEG 4/38***
Zinc 65 - 1535 1987/87 20,000 RMEG 0/136
69 - 720 1985 20,000 RMEG 0/39
*Analyses by Globe lab only, not a Quality Assurance Project Plan (QAPP) lab
** Widely varying results between labs at this sample location
*** When two or more labs analyzed a sample and the results varied on either side of the C.V. (Comparison Value), an average was taken to determine if the conc. > C.V.
The Industrial Drainage Ditch (IDD) samples were considered to be on-site.
**** All or nearly all of the samples for Sb, As, Cd, Mn, and Se exceed the C.V.'s for pica children. The exception is Zn where only 19/175 samples > C.V.
On-site maximums that exceed those found at 0-2" include:
Arsenic at 235 ppm, 2-6" depth, due north of site
Cadmium at 1000 ppm, 2-6" depth, east of site in non-residential area
Lead at 19,630 ppm, former smelter
Manganese at 900 ppm, 2-6" depth, east of site in non-residential area
Selenium at 182 ppm, 0.5-1' depth, immediately north of site



APPENDIX D -- EXPOSURE PATHWAYS TABLES

TABLE 7. COMPLETED EXPOSURE PATHWAY

PATHWAY SOURCE ENVIRONMENTAL MEDIA POINT OF EXPOSURE ROUTE OF EXPOSURE EXPOSED POPULATION* TIME
Air Plant emissions and re-entrained dust air ASARCO plant site and residential areas Inhalation and ingestion Workers on-site (200) and off-site residents in the area (4878) past

future (dust)

Off-site surface soil Direct deposits from industrial stack emissions and wind-blown dust surface soil and wind-blown dust Residential areas particularly North/North-east and south/south-west of site Inhalation and incidental ingestion Residential population north/north-east and south/south-east of the site (1563), emphasis on children under six years of age (578) past, present and future (until soil remediation)
On-site surface soil Plant emissions and wind-blown dust surface soil and wind-blown dust workers on-site inhalation and incidental ingestion on-site workers (unknown) past
present
future
On-site indoor air Industrial metal processes air Indoor during active on-site industrial metal processes Incidental inhalation and ingestion when protective equipment not correctly used On-site workers (18) past
Garden vegetables Air-borne deposits and irrigation surface soil and water Home gardens ingestion Individual eating home-grown vegetables (100) past

1.* Estimated total potentially affected receptor population: 4360; Total children 5 years or younger: 693; Total adults 60 years or older: 461; Total females aged 15-44: 897; Number of Blacks: 399; Number Whites: 1891; Number of American Indians: 61; Number of Asians: 54; Number of Hispanics: 2824; Other: 1646.

2.* Estimated total receptor population for current and past completed pathways: (a). Current - 1055; (b). past - 3305.

TABLE 8. POTENTIAL EXPOSURE PATHWAY

PATHWAY SOURCE ENVIRONMENTAL MEDIA POINT OF EXPOSURE ROUTE OF EXPOSURE EXPOSED POPULATION TIME
groundwater neutralization pond, plant facilities, and historic deposits on land groundwater private wells for drinking or irrigation (currently none known to exist that are in use in contaminated water plume) ingestion no known residential or industrial use at present (population unknown) past
present future
surface water/
sediment
contaminated water and sediment in the Industrial Drainage Ditch and the Farmers and Gardeners Ditch surface water/sediments open ditch areas dermal absorption of water and incidental ingestion children playing in ditch area (population unknown) past



APPENDIX E -- ESTIMATED EXPOSURE DOSES

TABLE 9. COMPARISON OF EXPOSED DOSE TO HEALTH GUIDELINES FOR INHALATION
CONTAMINANT EXPOSURE PATHWAY HEALTH GUIDELINE IN
µg/m3
SOURCE EXCEEDS HEALTH GUIDELINES DOSE
Arsenic On-site air 0.0002 CREG1 Yes
Off-site air 0.0002 CREG1 Yes
Cadmium On-site air 0.2 Chronic MRL2 No
Yes3
Off-site air 0.2 Chronic MRL2 No
Yes3
Lead On-site air NONE NONE N/A
Off-site air NONE NONE N/A

1 Cancer Risk Evaluation Guide for 1 x 10-6 excess cancer risk.
2 Chronic Minimal Risk Level (MRL).
3 Exceeds MRL for overall maximum air value; however, the maximum may only be a 24 hour maximum from 180-361 samples taken in a year.

TABLE 10. COMPARISON OF ESTIMATED EXPOSED DOSE TO HEALTH GUIDELINES FOR INGESTION
Contaminant Exposure Pathway Health Guideline for Ingestion - mg/kg/day
Value Source Exceeded by Estimated Exposure Dose
Antimony on-site surface soil 0.0004 chronic oral RfD No
off-site surface soil 0.0004 chronic oral RfD Yes (pica child only)
Arsenic on-site surface soil 0.0003 chronic oral MRL Yes
off-site surface soil 0.0003 chronic oral MRL Yes
Cadmium on-site surface soil 0.0007/0.0005 chronic oral MRL/RfD Yes
off-site surface soil 0.0007/0.0005 chronic oral MRL/RfD Yes
Lead on-site surface soil none none N/A
off-site surface soil none none N/A
Manganese on-site surface soil 1 chronic oral RfD No
off-site surface soil 1 chronic oral RfD No
Selenium on-site surface soil 0.003 chronic oral MRL No
off-site surface soil 0.003 chronic oral MRL No
Zinc on-site surface soil 0.3 chronic oral RfD No
off-site surface soil 0.3 chronic oral RfD Yes (Pica Child only)



APPENDIX F

PUBLIC COMMENTS


APPENDIX F -- RESPONSE TO PUBLIC COMMENTS

The ASARCO, Inc. (Globe Plant) Public Health Assessment was available for public review and comment from approximately November 18, 1994 to January 6, 1995. The comment period was announced in local newspapers. Copies were made available at the public library, and copies were sent to several individuals and organizations. No comments were received from residents. A summary of comments received from the potentially responsible party (PRP) and our responses are presented in this section. We wish to acknowledge that comments received from the Colorado Department of Health and Environment (CDPHE), and the City and County of Denver were useful and have been used to revise the body of the document where appropriate.

Comment 1 In general, the Globe ambient environmental issues should be viewed as being addressed through process change that began in 1983, and continuing program of emission control leading ultimately to cessation entirely of the cadmium production in 1993. In addition, a July 1993 consent order with the state requires the clean up of residential soils as well as soils, sediments and water on site which address potential off site migration. It appears that the risks the Agency for Toxic Substances and Disease Registry (ATSDR) has characterized are based on data generated prior to the change in plant operations and before the consent order. We are concerned that the ATSDR document will cause concern on the part of the public that the remedy agreed to by the state, and with oversight by the Environmental Protection Agency (EPA) is not sufficiently rigorous. We believe that ATSDR should have taken this opportunity to support what is being done.

Response. The PHA acknowledges the past and continuing efforts of the PRP to address the environmental issues at the site. Past actions taken by the PRP and others are clearly documented on pages three through seven, in the Summary, Conclusions, and in other sections of the document. Since the purpose of the PHA process is to address the entire exposure issues (accounting for human exposures to contaminants in the past, present, and the future), it is imperative to examine the entire available data. In addition, the document acknowledges past actions by the PRP and others, which have succeeded in reducing or preventing human exposures (as stated several times in the Summary, Environmental Contamination, and Conclusions sections of the document). ATSDR is supportive of all positive actions taken by the PRP to reduce and prevent exposure at the site. ATSDR has given its concurrence for the medical monitoring program, and has prepared a health consultation to assist the state in establishing standards for soil cleanup. ATSDR has not received any comments from residents that might be described as alarming as a result of information contained the PHA.

Comment 2 The Colorado Department of Public Health and Environment's (CDPHE) treatment of the data generated through the 1990 ATSDR sponsored Globeville Childhood Metals Exposure study presents an interesting contrast to the draft public health assessment. The CDPHE May 1994 Superfund Bulletin for Health Professionals states that no elevated cadmium and arsenic levels were found (in the metals study) and 14 of the children (11.3%) tested had blood lead levels equal to or greater than 10 µg/dl, the CDC level of concern. In addition, the average lead levels of Globeville children were similar to the comparison neighborhoods.

Response The PHA states that 37 (about eight percent) of the young children tested from four neighborhoods in Globeville and control areas have blood lead levels equal to or greater than 10 µg/dl. In addition, the PHA states that a Globeville child is more likely than other children to be in the 5-10 µg/dl range for blood lead levels. The statements will be reworded to reflect the number of study areas, a control area, and to indicate that the source of the lead exposure is unknown. However, the information you quoted from the CDPHE bulletin refers only to one of the study areas and not all four neighborhoods and a control area as discussed in the PHA.

Comment 3 We firmly believe the use of the one excess cancer in a million risk criteria as discussed on page 13 is unrealistic because of the lack of a sound basis for using this level, and because of misunderstandings about one in a million risk (see enclosed article that discuss the myth of 10-6).

Response The Cancer Risk Evaluation Guides (CREGs) used on page 13 are for screening purposes to determine which contaminants should be looked at more closely in the PHA. The selection of a contaminant for further evaluation does not mean that either exposure to the contaminant or adverse health effects has occurred or will occur. However, you are correct that there is some uncertainty associated with using the risk level of 10-6 to describe community exposure at hazardous waste sites. Because of this uncertainty the risk of 10-6 should not be consistently applied in every exposure situation. Although ATSDR recognizes the utility of numerical risk estimates in risk analyses, the Agency considers these estimates in the context of the variables and assumptions involved in their derivation and in the broader context of biomedical opinion, host factors, and actual exposure conditions. For example, ATSDR considers cancer exposure levels (as determined in epidemiological studies), the type and magnitude of contaminant levels as well as the route of exposure. These considerations influenced the cancer risks described in the Public Health Implications section of the PHA.

Comment 4 It should be clear that the exacerbation of childhood respiratory disease concerns as discussed on page 45 are far more likely to be caused by the Denver area general air quality rather than the small amounts of cadmium, tellurium, and antimony as alleged on page 41 in answer to a question regarding respiratory problems. Is it not also true that cadmium, tellurium, and antimony exposures that may have led to respiratory problems in humans were in an occupational setting?

Response The PHA acknowledges that the Total Suspended Particulate (TSP) problems in the Denver area are due in part to other industries in the area and the main freeway systems. The TSP can exacerbate the respiratory conditions that are commonly observed in the area. It is clearly stated in the Summary, Environmental Contamination, Community Health Concerns Evaluation, and Conclusions sections, that the city-wide problem of TSP levels contributes to the occurrence of respiratory conditions.

Comment 5 If the document truly is a public health assessment, why are continued references made to historical worker exposures and violations (examples are found in paragraph two of the Summary, pages 17 and 18, and paragraph one of the Conclusion).

Response As stated in the response to your first comment, the purpose of the PHA process is to address indicated exposure scenarios, taking into consideration workers as well as nearby residents. It is necessary to examine all information pertaining to exposure to contaminants at the site.

Comment 6 On page 34, a reference is made to Globe workers eating Globeville grown vegetables. ASARCO knew of only one Globe plant employee that lives in Globeville, and that employee does not have a garden.

Response That reference in the PHA is made in regard to any past PRP workers who may fall into that exposure category. The document will be changed to reflect the new information.

Comment 7 It should be noted that EPA has not listed Globe on the NPL (page 3).

Response The statement on page three indicates that the site is proposed for listing on the NPL. The document has not been changed.

Comment 8 The results of the 1982 FIT and EPA NEIC investigations did not demonstrate either air quality or groundwater problems.

Response The document has been reworded to indicate that the study focused on those contaminants listed on page 4 in the PHA.

Comment 9 On page 6, state year of site visit; and 2nd last line - Globe does not produce thallium.

Response The document has been corrected.

Comment 10 While ATSDR may have heard some concerns (last two lines on page 8), the enclosed news article from LA VOZ suggests community support for the clean up process.

Response An exposure study by the Colorado Department of Health indicates that there is concern among some residents about potential health threats posed by the ASARCO plant. However, you are correct that the cleanup process is aimed at addressing this potential threat.

Comment 11 On page 24 paragraph D - reference is made to buildings no longer being used becoming a safety and chemical hazard for the public. However, it should be noted that the site is completely fenced and public access strictly limited.

Response The PHA acknowledges on pages 7 and 24 that the site is fenced. However, we have altered the last sentence of paragraph D, page 24, to clarify that the unused buildings could only become public hazards if access to the site does not continue to be strictly limited.

Comment 12 On page 26, it should be noted that the PRP consent order requires annual water use surveys to preclude future use of shallow groundwater.

Response The document will be changed to reflect this comment.

Comment 13 On page 32, the PRP is concerned about unnecessary speculation with regard to arsenic exposure and skin pigmentation.

Response Epidemiological studies in humans suggest that residents exposed to levels similar to those reported in the PHA experienced hyperkeratosis. The PHA only suggested that children exposed to the levels of arsenic reported in this document might experience similar health effects.

Comment 14 On page 41, the PRP is concerned that ATSDR has not stated that soils below the surface rapidly fall in metal concentration.

Response The PHA states that contaminant concentrations do decrease with depth. However, the document will be revised to reflect that soils below the surface rapidly fall in metal concentration.

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