PUBLIC HEALTH ASSESSMENT
ASARCO INCORPORATED (GLOBE PLANT)
DENVER, DENVER COUNTY, COLORADO
Appendix A -- Figures
Appendix B -- Air Data
Appendix C -- Soil Data
Appendix D -- Exposure Pathways
Appendix E -- Estimated Exposure Doses
Appendix F -- Public Comments
FIGURES 1-4
The following figure was not available in electronic format for conversin to HTML at the time of preparation of this document. To obtain a hard copy of the document, please contact:
Agency for Toxic Substances and Disease Registry
Division of Health Assessment and Consultation
Attn: Chief, Program Evaluation, Records, and Information Services
Branch, E-56
1600 Clifton Road NE, Atlanta, Georgia 30333
Figure 3.
Figure 4. Priority Sample Population
AIR DATA
TABLE 3. ON-SITE AIR QUALITY (1987 - 1992) | |||||||
Monitoring Stations | |||||||
Metal | Year | Bookstore 58 samples/yr |
Old Office Site 58 samples/yr |
Nutech 58 samples/yr | |||
Concentration (µg/m3) | |||||||
Max. | Avg. | Max. | Avg. | Max. | Avg. | ||
Cadmium | 1992 1991 1990 1989 1988 1987** |
0.054 0.233 0.053 0.184 0.142* 0.165 |
0.019 NC 0.027 0.041 0.018* NC |
0.090 0.136 0.603 0.447 0.429 0.589 |
0.046 0.028 0.080 0.065 0.048 NC |
0.195 0.093 0.879 0.589 0.440 0.745 |
0.032 NC 0.062 0.072 0.060 NC |
Arsenic*** | 1992 1991 1990 1989 1988 1987** |
<0.022 0.018 0.021 0.022 0.032* <0.010 |
0.009 NC 0.010 0.007 NC NC |
0.021 0.064 0.022 0.022 0.04 0.095 |
0.008 NC 0.009 0.009 0.012 NC |
0.021 0.074 0.098 0.042 0.05 0.087 |
0.009 NC 0.007 0.007 0.012 NC |
Lead | 1992 1991 1990 1989 1988 1987** |
0.23 0.18 0.25 0.33 0.66* 0.64 |
0.11 NC 0.11 0.12 NC NC |
0.16 0.34 1.4 0.38 0.79 1.57 |
0.17 NC 0.18 0.15 0.21 NC |
0.49 0.30 1.4 0.27 1.39 1.64 |
0.14 NC 0.14 0.13 0.23 NC |
TSP | 1992 1991 1990 1989 1988 1987** |
214.8 229.1 241.7 287.6 248.9* 738.5 |
113.80 108.34 92.19 111.00 122.80 NC |
165.6 217.9 234.9 224.3 188.3 281.3 |
85.01 NC 75.78 86.27 NC NC |
211.3 228.2 236.1 166.8 228.5 308.5 |
100.55 NC 82.76 83.46 NC NC |
TSP = Total Suspended Particulates NC = Not calculated * March through May data gaps, only 38 samples compared to about 58 samples per year in 1989, station relocated to site second quarter 1988. ** Based on 6 months of data *** Concentrations were usually below the detection limit so half of the minimal detectable activity was used in averaging. 1993 data were not available. The September 1982 NEIC sampling showed average results in µg/m3 of 0.022 - 0.095 cadmium, 0.003 - 0.014 arsenic, 0.641 - 0.955 lead, and 0.113 - 0.243 zinc. |
TABLE 4. OFF-SITE AIR QUALITY (1987 - 1993) | |||||||
Monitoring Stations | |||||||
Metal | Year | Clinicare 180- 361 samples/yr |
Forklift City 59 samples/yr |
Background,
Adams City* 56 samples/yr | |||
Concentration (µg/m3) | |||||||
Max. | Avg. | Max. | Avg. | Max. | Avg. | ||
Cadmium | 1993 1992 1991 1990 1989 1988 1987 |
2.027* 3.900 0.713 0.750 ND ND ND |
0.077* 0.054 0.035 0.073 ND ND ND |
ND 0.487 2.161 0.433 1.136 0.577 1.555 |
ND 0.054 0.071 0.063 0.092 0.046 NC |
0.024 0.100 0.009 0.016 ND ND ND |
0.003 0.004 0.002 0.004 ND ND ND |
Arsenic | 1993 1992 1991 1990 1989 1988 1987 |
0.070* 0.015 0.300 0.028 ND ND ND |
0.002* 0.002 0.005 0.004 ND ND ND |
ND <0.022 0.016 0.022 0.011 0.011 0.010 |
ND 0.006 NC 0.006 0.006 0.006 0.006 |
0.003 0.011 0.004 0.015 ND ND ND |
0.001 0.002 0.004 0.004 ND ND ND |
Lead | 1993 1992 1991 1990 1989 1988 1987 |
1.00* 0.50 0.43 0.72 ND ND ND |
0.10* 0.09 0.07 0.14 ND ND ND |
ND 1.21 0.53 1.66 0.79 6.34 2.48 |
ND 0.24 NC 0.28 NC 0.50 NC |
0.23 0.17 0.14 0.22 ND ND ND |
0.03 0.03 0.03 0.05 ND ND ND |
TSP | 1993 1992 1991 1990 1989 1988 1987 |
308* 368 359 246 ND ND ND |
101* 106 105 97 ND ND ND |
ND 311.6 239.5 190.5 241.8 187.2 293.1 |
ND 96.5 89.0 75.7 90.2 95.7 NC |
261 319 211 228 ND ND ND |
100 90 82 79 ND ND ND |
TSP = Total Suspended Particulates ND = No data NC = Not calculated Clinicare is about a half block North East of the North East corner of the ASARCO property. The Forklift City site is north of the site. The Adams City site is approx. 3 miles NE of ASARCO. *1993 data for Clinicare represents 1/1/93 through 6/30/93 or 180 samples, the other years represent the entire year or from 278 to 361 samples. |
SOIL DATA
TABLE 5. ON-SITE SOIL (RI, App 9) SURFACE SOIL 0-2" | |||||
August & June 1985, August 1986/ July 1987 | |||||
METAL | CONC.
RANGE (total metals) |
YEAR SAMPLED |
COMPARISON VALUE (CV) FOR INGESTION - CHILD**** | FREQ >CV | |
ppm | ppm | Source | |||
Antimony* | 9 - 104 | 1985 | 20 | RMEG | 15/16 |
Arsenic | 19 - 6770 | 1986/87 | 0.4 20 |
CREG EMEG |
9/9 8/9 |
3** - 535 | 1985 | 0.4 20 |
CREG EMEG |
17/17 17/17*** | |
Cadmium | 21 - 9900 | 1986/87 | 40 | EMEG | 7/9 |
21 - 272 | 1985 | 40 | EMEG | 14/17 | |
Lead | 120 - 11,500 | 1986/87 | None | --- | 6/9 > bkgrd of 413 ppm |
66 - 1875 | 1985 | None | --- | 11/17***
>bkgrd of 413 ppm | |
Manganese | 93 - 1000 | 1985 | 300 | RMEG | 12/17 |
Selenium | 0.5** - 108 | 1985 | 100 | IEMEG | 2/17 |
Zinc | 285 - 107,500 | 1987/87 | 20,000 | RMEG | 1/9 |
114 - 5200 | 1985 | 20,000 | RMEG | 0/17 | |
*Analyses by Globe lab only, not a Quality Assurance Project Plan (QAPP) lab ** Widely varying results between labs at this sample location *** When two or more labs analyzed a sample and the results varied on either side of the C.V. (Comparison Value), an average was taken to determine if the conc. > C.V. The Industrial Drainage Ditch (IDD) samples were considered to be on-site. **** Arsenic and cadmium were the only metals exceeding comparison values for an adult. The comparison values are 200 and 500 ppm, respectively with 11/26 samples >C.V. for As and 4/26 samples >C.V. for Cd. On-site maximums that exceed those found at 0-2" include: Arsenic at 15,250 ppm, 16' depth, former neutralization pond Antimony at 293 ppm, 0.5-1', IDD Cadmium at 14,708 ppm, 0-6" depth, center of site-terrace escarpment Lead at 16,000 ppm, 2-6" depth, lead slag pile Manganese at 1525 ppm, 2-6", NW corner Zinc at 117,500 ppm, 7'& 11' depths, former neutralization pond |
TABLE 6. OFF-SITE SOIL (RI, App 9) SURFACE SOIL 0-2" | |||||
August & June 1985, August 1986/ July 1987 | |||||
METAL | CONC.
RANGE (total) |
YEAR SAMPLED |
COMPARISON VALUE (CV) FOR INGESTION - CHILD**** | FREQ >CV | |
ppm | ppm | Source | |||
Antimony* | 15 - 442 | 1985 | 20 | RMEG | 28/34 |
Arsenic | 1.2 - 113 | 1986/87 | 0.4 20 |
CREG EMEG |
136/136 42/136 |
<1** - 168** | 1985 | 0.4 20 |
CREG EMEG |
39/39 29/39 | |
Cadmium | 0.48 - 175 | 1986/87 | 40 | EMEG | 18/136 |
5 - 398 | 1985 | 40 | EMEG | 21/39*** | |
Lead | 20 - 1150 | 1986/87 | None | --- | 19/136 > bkgrd of 413 ppm |
58 - 1500 | 1985 | None | --- | 11/39***
>bkgrd of 413 ppm | |
Manganese | 210 - 860 | 1985 | 300 | RMEG | 22/39 |
Selenium | 1 - 153 | 1985 | 100 | IEMEG | 4/38*** |
Zinc | 65 - 1535 | 1987/87 | 20,000 | RMEG | 0/136 |
69 - 720 | 1985 | 20,000 | RMEG | 0/39 | |
*Analyses by Globe lab only, not a Quality Assurance Project Plan (QAPP) lab ** Widely varying results between labs at this sample location *** When two or more labs analyzed a sample and the results varied on either side of the C.V. (Comparison Value), an average was taken to determine if the conc. > C.V. The Industrial Drainage Ditch (IDD) samples were considered to be on-site. **** All or nearly all of the samples for Sb, As, Cd, Mn, and Se exceed the C.V.'s for pica children. The exception is Zn where only 19/175 samples > C.V. On-site maximums that exceed those found at 0-2" include: Arsenic at 235 ppm, 2-6" depth, due north of site Cadmium at 1000 ppm, 2-6" depth, east of site in non-residential area Lead at 19,630 ppm, former smelter Manganese at 900 ppm, 2-6" depth, east of site in non-residential area Selenium at 182 ppm, 0.5-1' depth, immediately north of site |
APPENDIX D -- EXPOSURE PATHWAYS TABLES
TABLE 7. COMPLETED EXPOSURE PATHWAY | ||||||
PATHWAY | SOURCE | ENVIRONMENTAL MEDIA | POINT OF EXPOSURE | ROUTE OF EXPOSURE | EXPOSED POPULATION* | TIME |
Air | Plant emissions and re-entrained dust | air | ASARCO plant site and residential areas | Inhalation and ingestion | Workers on-site (200) and off-site residents in the area (4878) | past
future (dust) |
Off-site surface soil | Direct deposits from industrial stack emissions and wind-blown dust | surface soil and wind-blown dust | Residential areas particularly North/North-east and south/south-west of site | Inhalation and incidental ingestion | Residential population north/north-east and south/south-east of the site (1563), emphasis on children under six years of age (578) | past, present and future (until soil remediation) |
On-site surface soil | Plant emissions and wind-blown dust | surface soil and wind-blown dust | workers on-site | inhalation and incidental ingestion | on-site workers (unknown) | past present future |
On-site indoor air | Industrial metal processes | air | Indoor during active on-site industrial metal processes | Incidental inhalation and ingestion when protective equipment not correctly used | On-site workers (18) | past |
Garden vegetables | Air-borne deposits and irrigation | surface soil and water | Home gardens | ingestion | Individual eating home-grown vegetables (100) | past |
1.* Estimated total potentially affected receptor population: 4360; Total children 5 years or younger: 693; Total adults 60 years or older: 461; Total females aged 15-44: 897; Number of Blacks: 399; Number Whites: 1891; Number of American Indians: 61; Number of Asians: 54; Number of Hispanics: 2824; Other: 1646.
2.* Estimated total receptor population for current and past completed pathways: (a). Current -
1055; (b). past - 3305.
TABLE 8. POTENTIAL EXPOSURE PATHWAY | ||||||
PATHWAY | SOURCE | ENVIRONMENTAL MEDIA | POINT OF EXPOSURE | ROUTE OF EXPOSURE | EXPOSED POPULATION | TIME |
groundwater | neutralization pond, plant facilities, and historic deposits on land | groundwater | private wells for drinking or irrigation (currently none known to exist that are in use in contaminated water plume) | ingestion | no known residential or industrial use at present (population unknown) | past present future |
surface water/ sediment |
contaminated water and sediment in the Industrial Drainage Ditch and the Farmers and Gardeners Ditch | surface water/sediments | open ditch areas | dermal absorption of water and incidental ingestion | children playing in ditch area (population unknown) | past |
APPENDIX E -- ESTIMATED EXPOSURE DOSES
TABLE 9. COMPARISON OF EXPOSED DOSE TO HEALTH GUIDELINES FOR INHALATION | ||||
CONTAMINANT | EXPOSURE PATHWAY | HEALTH GUIDELINE IN µg/m3 |
SOURCE | EXCEEDS HEALTH GUIDELINES DOSE |
Arsenic | On-site air | 0.0002 | CREG1 | Yes |
Off-site air | 0.0002 | CREG1 | Yes | |
Cadmium | On-site air | 0.2 | Chronic MRL2 | No Yes3 |
Off-site air | 0.2 | Chronic MRL2 | No Yes3 | |
Lead | On-site air | NONE | NONE | N/A |
Off-site air | NONE | NONE | N/A |
1 Cancer Risk Evaluation Guide for 1 x 10-6 excess cancer risk.
2 Chronic Minimal Risk Level (MRL).
3 Exceeds MRL for overall maximum air value; however, the maximum may only be a 24 hour maximum from 180-361 samples taken in a year.
TABLE 10. COMPARISON OF ESTIMATED EXPOSED DOSE TO HEALTH GUIDELINES FOR INGESTION | ||||
Contaminant | Exposure Pathway | Health Guideline for Ingestion - mg/kg/day | ||
Value | Source | Exceeded by Estimated Exposure Dose | ||
Antimony | on-site surface soil | 0.0004 | chronic oral RfD | No |
off-site surface soil | 0.0004 | chronic oral RfD | Yes (pica child only) | |
Arsenic | on-site surface soil | 0.0003 | chronic oral MRL | Yes |
off-site surface soil | 0.0003 | chronic oral MRL | Yes | |
Cadmium | on-site surface soil | 0.0007/0.0005 | chronic oral MRL/RfD | Yes |
off-site surface soil | 0.0007/0.0005 | chronic oral MRL/RfD | Yes | |
Lead | on-site surface soil | none | none | N/A |
off-site surface soil | none | none | N/A | |
Manganese | on-site surface soil | 1 | chronic oral RfD | No |
off-site surface soil | 1 | chronic oral RfD | No | |
Selenium | on-site surface soil | 0.003 | chronic oral MRL | No |
off-site surface soil | 0.003 | chronic oral MRL | No | |
Zinc | on-site surface soil | 0.3 | chronic oral RfD | No |
off-site surface soil | 0.3 | chronic oral RfD | Yes (Pica Child only) |
PUBLIC COMMENTS
APPENDIX F -- RESPONSE TO PUBLIC COMMENTS
The ASARCO, Inc. (Globe Plant) Public Health Assessment was available for public review and
comment from approximately November 18, 1994 to January 6, 1995. The comment period was
announced in local newspapers. Copies were made available at the public library, and copies
were sent to several individuals and organizations. No comments were received from residents.
A summary of comments received from the potentially responsible party (PRP) and our
responses are presented in this section. We wish to acknowledge that comments received from
the Colorado Department of Health and Environment (CDPHE), and the City and County of
Denver were useful and have been used to revise the body of the document where appropriate.
Comment 1 | In general, the Globe ambient environmental issues should be viewed as
being addressed through process change that began in 1983, and continuing
program of emission control leading ultimately to cessation entirely of the
cadmium production in 1993. In addition, a July 1993 consent order with the
state requires the clean up of residential soils as well as soils, sediments and
water on site which address potential off site migration. It appears that the
risks the Agency for Toxic Substances and Disease Registry (ATSDR) has
characterized are based on data generated prior to the change in plant
operations and before the consent order. We are concerned that the ATSDR
document will cause concern on the part of the public that the remedy agreed
to by the state, and with oversight by the Environmental Protection Agency
(EPA) is not sufficiently rigorous. We believe that ATSDR should have
taken this opportunity to support what is being done. |
Response. | The PHA acknowledges the past and continuing efforts of the PRP to address
the environmental issues at the site. Past actions taken by the PRP and others
are clearly documented on pages three through seven, in the Summary,
Conclusions, and in other sections of the document. Since the purpose of the
PHA process is to address the entire exposure issues (accounting for human
exposures to contaminants in the past, present, and the future), it is imperative
to examine the entire available data. In addition, the document acknowledges
past actions by the PRP and others, which have succeeded in reducing or
preventing human exposures (as stated several times in the Summary,
Environmental Contamination, and Conclusions sections of the document).
ATSDR is supportive of all positive actions taken by the PRP to reduce and
prevent exposure at the site. ATSDR has given its concurrence for the
medical monitoring program, and has prepared a health consultation to assist
the state in establishing standards for soil cleanup. ATSDR has not received
any comments from residents that might be described as alarming as a result
of information contained the PHA. |
Comment 2 | The Colorado Department of Public Health and Environment's (CDPHE)
treatment of the data generated through the 1990 ATSDR sponsored
Globeville Childhood Metals Exposure study presents an interesting contrast
to the draft public health assessment. The CDPHE May 1994 Superfund
Bulletin for Health Professionals states that no elevated cadmium and arsenic
levels were found (in the metals study) and 14 of the children (11.3%) tested
had blood lead levels equal to or greater than 10 µg/dl, the CDC level of
concern. In addition, the average lead levels of Globeville children were
similar to the comparison neighborhoods. |
Response | The PHA states that 37 (about eight percent) of the young children tested
from four neighborhoods in Globeville and control areas have blood lead
levels equal to or greater than 10 µg/dl. In addition, the PHA states that a
Globeville child is more likely than other children to be in the 5-10 µg/dl
range for blood lead levels. The statements will be reworded to reflect the
number of study areas, a control area, and to indicate that the source of the
lead exposure is unknown. However, the information you quoted from the
CDPHE bulletin refers only to one of the study areas and not all four
neighborhoods and a control area as discussed in the PHA. |
Comment 3 | We firmly believe the use of the one excess cancer in a million risk criteria as
discussed on page 13 is unrealistic because of the lack of a sound basis for
using this level, and because of misunderstandings about one in a million risk
(see enclosed article that discuss the myth of 10-6). |
Response | The Cancer Risk Evaluation Guides (CREGs) used on page 13 are for
screening purposes to determine which contaminants should be looked at
more closely in the PHA. The selection of a contaminant for further
evaluation does not mean that either exposure to the contaminant or adverse
health effects has occurred or will occur. However, you are correct that there
is some uncertainty associated with using the risk level of 10-6 to describe
community exposure at hazardous waste sites. Because of this uncertainty the
risk of 10-6 should not be consistently applied in every exposure situation.
Although ATSDR recognizes the utility of numerical risk estimates in risk
analyses, the Agency considers these estimates in the context of the variables
and assumptions involved in their derivation and in the broader context of
biomedical opinion, host factors, and actual exposure conditions. For
example, ATSDR considers cancer exposure levels (as determined in
epidemiological studies), the type and magnitude of contaminant levels as
well as the route of exposure. These considerations influenced the cancer
risks described in the Public Health Implications section of the PHA. |
Comment 4 | It should be clear that the exacerbation of childhood respiratory disease
concerns as discussed on page 45 are far more likely to be caused by the
Denver area general air quality rather than the small amounts of cadmium,
tellurium, and antimony as alleged on page 41 in answer to a question
regarding respiratory problems. Is it not also true that cadmium, tellurium,
and antimony exposures that may have led to respiratory problems in humans
were in an occupational setting? |
Response | The PHA acknowledges that the Total Suspended Particulate (TSP) problems
in the Denver area are due in part to other industries in the area and the main
freeway systems. The TSP can exacerbate the respiratory conditions that are
commonly observed in the area. It is clearly stated in the Summary,
Environmental Contamination, Community Health Concerns Evaluation, and
Conclusions sections, that the city-wide problem of TSP levels contributes to
the occurrence of respiratory conditions. |
Comment 5 | If the document truly is a public health assessment, why are continued
references made to historical worker exposures and violations (examples are
found in paragraph two of the Summary, pages 17 and 18, and paragraph one
of the Conclusion). |
Response | As stated in the response to your first comment, the purpose of the PHA
process is to address indicated exposure scenarios, taking into consideration
workers as well as nearby residents. It is necessary to examine all
information pertaining to exposure to contaminants at the site. |
Comment 6 | On page 34, a reference is made to Globe workers eating Globeville grown
vegetables. ASARCO knew of only one Globe plant employee that lives in
Globeville, and that employee does not have a garden. |
Response | That reference in the PHA is made in regard to any past PRP workers who
may fall into that exposure category. The document will be changed to reflect
the new information. |
Comment 7 | It should be noted that EPA has not listed Globe on the NPL (page 3). |
Response | The statement on page three indicates that the site is proposed for listing on
the NPL. The document has not been changed. |
Comment 8 | The results of the 1982 FIT and EPA NEIC investigations did not
demonstrate either air quality or groundwater problems. |
Response | The document has been reworded to indicate that the study focused on those
contaminants listed on page 4 in the PHA. |
Comment 9 | On page 6, state year of site visit; and 2nd last line - Globe does not produce
thallium. |
Response | The document has been corrected. |
Comment 10 | While ATSDR may have heard some concerns (last two lines on page 8), the
enclosed news article from LA VOZ suggests community support for the
clean up process. |
Response | An exposure study by the Colorado Department of Health indicates that there
is concern among some residents about potential health threats posed by the
ASARCO plant. However, you are correct that the cleanup process is aimed
at addressing this potential threat. |
Comment 11 | On page 24 paragraph D - reference is made to buildings no longer being used
becoming a safety and chemical hazard for the public. However, it should be
noted that the site is completely fenced and public access strictly limited. |
Response | The PHA acknowledges on pages 7 and 24 that the site is fenced. However,
we have altered the last sentence of paragraph D, page 24, to clarify that the
unused buildings could only become public hazards if access to the site does
not continue to be strictly limited. |
Comment 12 | On page 26, it should be noted that the PRP consent order requires annual
water use surveys to preclude future use of shallow groundwater. |
Response | The document will be changed to reflect this comment. |
Comment 13 | On page 32, the PRP is concerned about unnecessary speculation with regard
to arsenic exposure and skin pigmentation. |
Response | Epidemiological studies in humans suggest that residents exposed to levels
similar to those reported in the PHA experienced hyperkeratosis. The PHA
only suggested that children exposed to the levels of arsenic reported in this
document might experience similar health effects. |
Comment 14 | On page 41, the PRP is concerned that ATSDR has not stated that soils below
the surface rapidly fall in metal concentration. |
Response | The PHA states that contaminant concentrations do decrease with depth. However, the document will be revised to reflect that soils below the surface rapidly fall in metal concentration. |