HEALTH CONSULTATION
CERTAIN-TEED CORPORATION
EAST ST. LOUIS, ST. CLAIR COUNTY, ILLINOIS
Table 1 Summary of Soil Samples During Investigations of the Certain-Teed Corporation Site
Table 2 Contaminants of Concern in Soil Samples Collected from On-Site and Off-Site Areas
Table 3 Estimated Soil Exposures in Workers and Children to Soil Contaminants
Table 4 Completed Exposure Pathway Information
Figure 2 Soil Sample Location Map
Attachment 1 Description of Sampling Locations
Attachment 2 Exposure Dose Calculations
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Compound/CV | X101 | X102 | X103 | X104 | X105 | X106 | X107 | X108 | X109 | X110 | X111 | X112 |
SEMIVOLATILES | ||||||||||||
4-Methylphenol | 0 | 0.15 | 0 | 0.005 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Isophorone | 0 | 0 | 0 | 0.02 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Naphthalene | 0.017 | 0.12 | 0.009 | 0.076 | 0.15 | 2.6 | 0.024 | 0.059 | 0.026 | 0.069 | 0.09 | 0 |
4-Chloroaniline | 0 | 0 | 0.048 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
2-Methylnaphthalene | 0.024 | 0.28 | 0.016 | 0.11 | 0.24 | 2.8 | 0.03 | 0.055 | 0.046 | 0.17 | 0.12 | 0.34 |
Dimethylphthalate | 0 | 0 | 0 | 0.006 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Acenaphthylene | 0 | 0.077 | 0.008 | 0.042 | 0.034 | 0.35 | 0.066 | 0.039 | 0.025 | 0.03 | 0.04 | 0 |
Acenaphthalene | 0.019 | 0.021 | 0.008 | 0.072 | 0.15 | 2.6 | 0.01 | 0.057 | 0.019 | 0.1 | 0.11 | 0 |
Dibenzofuran | 0.018 | 0.055 | 0.009 | 0.096 | 0.14 | 2.1 | 0.02 | 0.063 | 0.029 | 0.096 | 0.092 | 0.18 |
Diethylphthalate | 0.007 | 0 | 0.017 | 0.015 | 0 | 0.16 | 0.013 | 0.018 | 0.013 | 0.013 | 0.015 | 0 |
Fluorene | 0.015 | 0.024 | 0.009 | 0.11 | 0.13 | 2.1 | 0.008 | 0.047 | 0.017 | 0.093 | 0.099 | 0 |
N-Nitrosodiphenylamine | 0 | 0.073 | 0 | 0.017 | 0.04 | 0.27 | 0 | 0 | 0 | 0.038 | 0.026 | 0 |
Phenanthrene | 0.26 | 0.61 | 0.15 | 1.2 | 2.4 | 31 | 0.23 | 0.74 | 0.43 | 1.4 | 1.9 | 0.83 |
Anthracene | 0.047 | 0.17 | 0.024 | 0.26 | 0.4 | 6.4 | 0.048 | 0.15 | 0.089 | 0.18 | 0.3 | 0 |
Carbazole | 0.023 | 0 | 0.017 | 0.14 | 0.32 | 4.1 | 0.043 | 0.08 | 0.046 | 0.19 | 0.15 | 0 |
Di-n-butylphthalate | 0 | 0 | 0 | 0 | 0 | 0.22 | 0 | 0 | 0 | 0 | 0 | 0.4 |
Fluoranthene | 0.41 | 1.3 | 0.26 | 1.8 | 3.6 | 41 | 0.74 | 1 | 0.64 | 1.8 | 2.9 | 0.91 |
Pyrene | 0.35 | 1.2 | 0.19 | 1.1 | 3.1 | 34 | 0.56 | 0.69 | 0.43 | 1.2 | 2.2 | 0.83 |
Butylbenzylphthalate | 0 | 0 | 0.025 | 6.4 | 0 | 0 | 0.024 | 0.024 | 0.034 | 0.026 | 0.041 | 0 |
Benz(a)Anthracene | 0.2 | 0.39 | 0.11 | 0.7 | 1.8 | 19 | 0.36 | 0.4 | 0.25 | 0.74 | 1.3 | 0.44 |
Chrysene | 0.22 | 1 | 0.14 | 0.48 | 2.1 | 20 | 0.47 | 0.44 | 0.31 | 0.84 | 1.6 | 0 |
bis(2-Ethylhexy 1)phthalate | 0 | 0 | 0 | 1.3 | 0 | 0.38 | 0 | 0 | 0 | 0 | 0 | 0 |
Benzo(b)Fluoranthene | 0.26 | 1.9 | 0.27 | 1.4 | 3 | 24 | 1.1 | 0.84 | 0.66 | 1.6 | 2.5 | 0.62 |
Benzo(k)Fluoranthene | 0.13 | 0 | 0.1 | 0.66 | 1.7 | 6.5 | 0.46 | 0.48 | 0.32 | 0.81 | 1.3 | 0 |
Benzo(a)Pyrene | 0.17 | 0 | 0.11 | 0.54 | 1.4 | 17 | 0.41 | 0.33 | 0.22 | 0.5 | 1.1 | 0.37 |
Indeno(1,2,3-cd)Pyrene | 0.16 | 0.57 | 0 | 0.36 | 0.97 | 15 | 0.3 | 0.25 | 0.19 | 0.37 | 0.69 | 0.64 |
Dibenz(a,h)anthracene | 0.045 | 0 | 0 | 0.096 | 0 | 0.7 | 0 | 0 | 0 | 0 | 0.21 | 0 |
Benzo(g,h,i)Perylene | 0.084 | 0.4 | 0 | 0.2 | 0.75 | 12 | 0.24 | 0.2 | 0.13 | 0.16 | 0.32 | 1.4 |
PESTICIDES/PCBs | ||||||||||||
alpha-BHC | 0 | 0 | 0 | 0 | 0 | 0.0028 | 0 | 0 | 0 | 0 | 0.0013 | 0 |
delta-BHC | 0.00027 | 0.0043 | 0 | 0.001 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
gamma-BHC (Lindane) | 0.00015 | 0 | 0 | 0.00017 | 0 | 0 | 0 | 0 | 0 | 0.00096 | 0.0004 | 0 |
Heptachlor | 0 | 0 | 0 | 0.00083 | 0 | 0.0035 | 0 | 0 | 0 | 0 | 0 | 0.0025 |
Aldrin | 0.0013 | 0.024 | 0 | 0 | 0 | 0 | 0 | 0.004 | 0.0032 | 0 | 0.0071 | 0 |
Heptachlor epoxide | 0 | 0.12 | 0 | 0.031 | 0 | 0 | 0.0063 | 0.031 | 0 | 0 | 0 | 0 |
Endosulfan I | 0 | 0 | 0 | 0 | 0.006 | 0.019 | 0 | 0.03 | 0 | 0 | 0.0015 | 0.0025 |
Dieldrin | 0.12 | 0.039 | 0.0017 | 0.03 | 0.014 | 0.29 | 0.02 | 0.095 | 0.066 | 0.042 | 0.012 | 0.88 |
4,4'-DDE | 0.026 | 0.16 | 0.0032 | 0.06 | 0.043 | 0.11 | 0.012 | 0.041 | 0.024 | 0.066 | 0.028 | 0.022 |
Endrin | 0.0015 | 0.029 | 0.0009 | 0.0095 | 0.0055 | 0.024 | 0.0023 | 0.0079 | 0.0036 | 0.0024 | 0.0011 | 0.016 |
4,4'-DDD | 0.0032 | 0.049 | 0.0011 | 0.011 | 0.017 | 0.035 | 0.0022 | 0 | 0 | 0.032 | 0.0055 | 0.031 |
4,4'-DDT | 0.047 | 0.12 | 0.0027 | 0.056 | 0.032 | 0.11 | 0.0073 | 0.019 | 0.011 | 0.24 | 0.049 | 0.086 |
Methoxychlor (Mariate) | 0.0052 | 0 | 0.0024 | 0.011 | 0.059 | 0.15 | 0.0062 | 0.024 | 0 | 0 | 0.019 | 0 |
Endrin Ketone | 0.0014 | 0.031 | 0.0013 | 0.0037 | 0.024 | 0.077 | 0.002 | 0.01 | 0 | 0.502 | 0.0099 | 0.016 |
Endrin Aldehyde | 0 | 0 | 0 | 0 | 0 | 0.058 | 0 | 0 | 0 | 0 | 0.014 | 0 |
alpha-Chlorodane | 0.0012 | 0.025 | 0.00091 | 0.0087 | 0.0025 | 0.0097 | 0.0024 | 0.017 | 0.0061 | 0.011 | 0 | 0.021 |
gamma-Chlorodane | 0.00063 | 0.056 | 0.0012 | 0.0096 | 0 | 0 | 0.002 | 0.007 | 0.0053 | 0.0083 | 0.0022 | 0.015 |
Arochlor-1254 | 0 | 2.8 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Arochlor-1260 | 0 | 1.8 | 0.31 | 2.7 | 0 | 0 | 0.64 | 1.2 | 0.76 | 0 | 0.22 | 0 |
INORGANICS | ||||||||||||
Aluminum | 16.8 | 4.49 | 1.92 | 4.91 | 9.94 | 5.42 | 7.82 | 9.75 | 8.76 | 9.55 | 7.65 | 9.44 |
Arsenic | 0.0118 | 0.01 | 0.0028 | 0.0077 | 0.0074 | 0.0264 | 0.029 | 0.0105 | 0.0099 | 0.0177 | 0.0086 | 0.0141 |
Barium | 0.251 | 0.123 | 0.0347 | 0.136 | 0.14 | 0.119 | 0.324 | 0.257 | 0.504 | 0.335 | 0.159 | 0.277 |
Beryllium | 0.0013 | 0 | 0 | 0.0004 | 0.0012 | 0.00085 | 0.00084 | 0.00049 | 0.00048 | 0.0014 | 0.00056 | 0.00063 |
Cadmium | 0.0048 | 0.0157 | 0.002 | 0.0045 | 0.0021 | 0.0042 | 0.0069 | 0.0027 | 0.0017 | 0.0057 | 0.0025 | 0.0043 |
Calcium | 9.21 | 15.3 | 3.95 | 105 | 43.2 | 19 | 18.2 | 40 | 34.1 | 9.4 | 35.9 | 16 |
Chromium | 0.0254 | 0.0805 | 0.0089 | 0.132 | 0.0274 | 0.025 | 0.0717 | 0.0828 | 0.0781 | 0.0266 | 0.0196 | 0.0253 |
Cobalt | 0.0094 | 0.0136 | 0.0033 | 0.0049 | 0.0061 | 0.0065 | 0.0116 | 0.0076 | 0.0074 | 0.0235 | 0.0067 | 0.0079 |
Copper | 0.0584 | 0.139 | 0.111 | 0.123 | 0.0562 | 0.0749 | 0.249 | 0.0946 | 0.0806 | 0.103 | 0.0445 | 0.0724 |
Iron | 25.1 | 16.8 | 5.36 | 35.3 | 18.7 | 30.6 | 87.1 | 20.6 | 19.1 | 36.4 | 17.7 | 24.5 |
Lead | 0.223 | 0.547 | 0.0646 | 0.63 | 0.157 | 0.195 | 0.377 | 0.156 | 0.121 | 0.557 | 0.215 | 3.32 |
Magnesium | 5.16 | 13.6 | 1.2 | 10.3 | 3.26 | 2.79 | 2.37 | 3.35 | 2.78 | 1.48 | 10.6 | 2.23 |
Manganese | 0.66 | 0.454 | 0.167 | 3.26 | 0.275 | 0.362 | 1.24 | 0.374 | 0.261 | 1.66 | 0.481 | 0.458 |
Mercury | 0.00015 | 0.00067 | 0.0095 | 0.00086 | 0.00019 | 0.002 | 0.00053 | 0.00017 | 0.00016 | 0.00061 | 0.00014 | 0.00032 |
Nickel | 0.024 | 0.0591 | 0.0107 | 0.0169 | 0.03 | 0.0265 | 0.0441 | 0.0426 | 0.0396 | 0.0297 | 0.0177 | 0.0212 |
Potassium | 3.93 | 0.526 | 0.318 | 1.01 | 1.94 | 0.774 | 1.14 | 1.67 | 1.7 | 1.81 | 1.64 | 1.97 |
Selenium | 0.00096 | 0.001 | 0 | 0 | 0 | 0.0012 | 0.0021 | 0 | 0 | 0.0013 | 0.00073 | 0.0014 |
Silver | 0.002 | 0.0013 | 0 | 0.0018 | 0.00097 | 0.0017 | 0.0056 | 0.0011 | 0 | 0.0021 | 0.00081 | 0.0016 |
Sodium | 0.304 | 0.432 | 0.22 | 0.437 | 2 | 0.579 | 0.618 | 1.04 | 1.06 | 0.442 | 0.389 | 0.492 |
Thallium | 0.0012 | 0.00088 | 0 | 0 | 0 | 0.0014 | 0.0034 | 0 | 0 | 0.0018 | 0 | 0.0013 |
Vanadium | 0.0446 | 0.0307 | 0.006 | 0.163 | 0.0592 | 0.0282 | 0.0579 | 0.0539 | 0.0551 | 0.0386 | 0.0292 | 0.0298 |
Zinc | 0.44 | 4.24 | 0.23 | 0.593 | 0.287 | 0.506 | 1.4 | 0.429 | 0.397 | 1.26 | 0.339 | 2.7 |
Cyanide | 0 | 0 | 0 | 0 | 0 | 0.0007 | 0 | 0 | 0 | 0 | 0 | 0.0014 |
Table 2 - Contaminants of Concern (in parts per million) |
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Compound/CV
|
X101 | X102 | X103 | X104 | X105 | X106 | X107 | X108 | X109 | X110 | X111 | X112 |
Soil ppm |
Source |
BCKGND | ONSITE | ONSITE | ONSITE | ONSITE | ONSITE | ONSITE | ONSITE | ONSITE | RES | RES | RES | |||
SEMIVOLATILES | ||||||||||||||
Naphthalene | 0.017J | 0.12J | 0.009J | 0.076J | 0.15J | 2.6J | 0.024J | 0.059J | 0.026J | 0.069J | 0.09J | ND | NONE | NONE |
2-Methylnaphthalene | 0.024J | 0.28J | 0.016J | 0.11J | 0.24J | 2.8J | 0.03J | 0.055J | 0.046J | 0.17J | 0.12J | 0.34J | NL | NL |
Acenaphthalene | 0.019J | 0.021J | 0.008J | 0.072J | 0.15J | 2.6J | 0.01J | 0.057J | 0.019J | 0.1J | 0.11J | ND | NL | NL |
Dibenzofuran | 0.018J | 0.055J | 0.009J | 0.096J | 0.14J | 2.1J | 0.02J | 0.063J | 0.029J | 0.096J | 0.092J | 0.18J | NL | NL |
Phenanthrene | 0.26J | 0.61 | 0.15J | 1.2 | 2.4 | 31 | 0.23J | 0.74 | 0.43 | 1.4 | 1.9 | 0.83J | NL | NL |
Carbazole | 0.023J | ND | 0.017J | 0.14J | 0.32J | 4.1J | 0.043J | 0.08J | 0.046J | 0.19J | 0.15J | ND | NL | NL |
Benz(a)Anthracene | 0.2J | 0.39J | 0.11J | 0.7 | 1.8 | 19 | 0.36J | 0.4J | 0.25J | 0.74 | 1.3 | 0.44J | NONE | NONE |
Chrysene | 0.22J | 1 | 0.14J | 0.48 | 2.1 | 20B | 0.47 | 0.44J | 0.31J | 0.84 | 1.6 | ND | NONE | NONE |
bis(2-Ethylhexyl)phthalate | ND | ND | ND | 1.3B | ND | 0.38J | ND | ND | ND | ND | ND | ND | NL | NL |
Benzo(b)Fluoranthene | 0.26J | 1.9 | 0.27J | 1.4 | 3 | 24 | 1.1 | 0.84 | 0.66 | 1.6 | 2.5 | 0.62J | NONE | NONE |
Benzo(k)Fluoranthene | 0.13J | ND | 0.1J | 0.66 | 1.7D | 6.5J | 0.46 | 0.48J | 0.32J | 0.81 | 1.3 | ND | NONE | NONE |
Benzo(a)Pyrene | 0.17J | ND | 0.11J | 0.54 | 1.4 | 17 | 0.41J | 0.33J | 0.22J | 0.5 | 1.1 | 0.37J | 0.1 | CREG |
Indeno(1,2,3-cd)Pyrene | 0.16J | 0.57J | ND | 0.36J | 0.97 | 15 | 0.3J | 0.25J | 0.19J | 0.37 | 0.69 | 0.64J | NONE | NONE |
Dibenz(a,h)anthracene | 0.045J | ND | ND | 0.096J | ND | 0.7J | ND | ND | ND | ND | 0.21J | ND | NONE | NONE |
Benzo(g,h,i)Perylene | 0.084J | 0.4J | ND | 0.2J | 0.75 | 12J | 0.24J | 0.2J | 0.13J | 0.16J | 0.32J | 1.4J | NONE | NONE |
PESTICIDES/PCBs | ||||||||||||||
Heptachlor epoxide | ND | 0.12JP | ND | 0.031JP | ND | ND | 0.0063JP | 0.031JP | ND | ND | ND | ND | 0.08 | CREG |
Dieldrin | 0.12D | 0.039JP | 0.0017JP | 0.03JPD | 0.014JP | 0.29JPD | 0.02P | 0.095JPD | 0.066 | 0.042JPD | 0.012P | 0.88D | 0.04 | CREG |
Arochlor-1254 | ND | 2.8P | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.04/1/10 | RMEG |
Arochlor-1260 | ND | 1.8P | 0.31 | 2.7D | ND | ND | 0.64 | 1.2P | 0.76P | ND | 0.22P | ND | 0.01/0.3 | C EMEG |
INORGANICS | ||||||||||||||
Arsenic | 11.8 | 10 | 2.8 | 7.7 | 7.4 | 26.4 | 29 | 10.5 | 9.9 | 17.7 | 8.6 | 14.1 | 0.6/20/200 | C EMEG |
Beryllium | 1.3 | ND | ND | 0.4B | 1.2B | 0.85B | 0.84B | 0.49B | 0.48B | 1.4 | 0.56B | 0.63B | 0.2 | CREG |
Lead | 223 | 547 | 64.6 | 630 | 157 | 195 | 377 | 156 | 121 | 557 | 215 | 3320 | NONE | NONE |
Mercury | 0.15 | 0.67 | 9.5 | 0.86 | 0.19 | 2 | 0.53 | 0.17 | 0.16 | 0.61 | 0.14 | 0.32 | NONE | NONE |
Thallium | 1.2 | 0.88 | ND | ND | ND | 1.4 | 3.4 | ND | ND | 1.8 | ND | 1.3 | NONE | NONE |
J= estimated value, qualitatively correct
but quantitatively suspect P=alternate analytical method used to analyze for this compound EMEG - Chronic Environmental Evaluation Guide |
B=analyte found in the associated blank and indicates possible/probable blank contamination ND = Not Detected CREG=Carcinogenic Risk Evaluation Guideline for 1 X 10-6 excess cancer risk |
NL - chemical not listed in ATSDR comparison
values EMEG=Environmental Media Evaluation Guide D - analyzed at a secondary dilution factor |
Table 3 - Estimated Soil Exposure in Workers and Children |
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Compound/CV
|
Concentration Range in Onsite Soils (in ppm) | Workers Exposure to Onsite Soil (using Maximum) | Concentration Range in Offsite Soils (in ppm) | Childs Exposure to Offsite Soil | Comparison Values in Soil | Exceeded | EPAs Oral Slope Factor | Cancer Risk | |||
Health Guidelines (mg/kg/day) | Source | Workers | Children | Workers | Children | ||||||
SEMIVOLATILES | |||||||||||
Benzo(a)pyrene | D-1.4 | 5.8 X 10-7 | 0.37J-1.1 | 1.1 X 10-5 | 0.1 | A Oral MRL | NO | NO | 7.3 | 4.2 X 10-5 | 8 X 10-5 |
PESTICIDES/PCBs | |||||||||||
Heptachlor epoxide | D-0.12 | 5.3 X 10-7 | D | 0 | 0.000013 | C.O.MRL | NO | NO | 9.1 | 4.8 X 10-7 | 0 |
Dieldrin | 0.0017JP-0.29JPD | 1.2 X 10-7 | 0.012P-0.88D | 8.8 X 10-6 | 0.00005 | C.O.MRL | NO | NO | 16 | 1.9 X 10-6 | 1.4 X 10-4 |
Arochlor-1254* | D-2.8P | 1.2 X 10-6 | D | 0 | 0.00002 | C.O.Rfd | NO | NO | None/0/05(1) | 6 X 10-8 | 0 |
Arochlor-1260* | D-2.7D | 1.1 X 10-6 | D-0.22P | 2.2 X 10-6 | 0.00002 | C.O.MRL | NO | NO | 0.05 | 5.5 X 10-8 | 1.1 X 10-7 |
INORGANICS | |||||||||||
Arsenic | 2.8-29 | 1.2 X 10-5 | 8.6-17.7 | 1.8 X 10-4 | C.O.MRL | 0.0003 | NO | NO | 1.5 | 1.8 X 10-5 | 2.7 X 10-4 |
Beryllium | D-1.3 | 5.3 X 10-7 4.14 X 10-7 |
D-1.8 | 1.8 X 10-5 | C.O.RFD | 0.005 | NO | NO | 4.3 | 2.3 X 10-6 | 7.7 X 10-5 |
mg/kg/day = milligrams per kilogram per day MRL = Minimal Risk Level * - There was not a slope factor for Arochlor-1254 so the slope factor for PCBs was used. A. Oral MRL - Acute Oral MRL |
D - Not Detected in Sample RFD=Reference Dose |
J=estimated value, qualitatively correct but quantitatively
suspect P=alternate analytical method used to analyze for this compound C. O. MRL - Chronic Oral MRL |
Table 4. Completed Exposure Pathways - Certain-Teed Site
Pathway Name: | Source | Medium | Exposure Point |
Exposure Route |
Receptor Population |
Time of Exposure |
Exposure Activities |
Estimated Number Exposed | Chemicals |
On-site Surface Soil | Surface Wastes | Surface Soil | Individuals on the site | Ingestion Inhalation Dermal |
On-site Workers Trespassers |
Past Present Future |
Working/trespassing on the site. | 10 | Table 2 |
Off-site Surface Soil | Soil | Surface Soil | Residential Yards | Ingestion Inhalation Dermal |
Residents | Past Present Future |
Contacting Soil | 40 | Table 2 |
Figure 1. Certain-teed Corporation Site Location Map
Figure 2. Soil Sample Location Map
Attachment 1. Sample Descriptions
On-site workers
ID = | C X IR X ER X 10-6 BW |
Where EF = Exposure Frequency X Exposure Duration/Exposure Time
= (5 days/week)(50 weeks/year)(30 years) |
|
= 0.29 |
ID = | (Concentration)(100 mg/day)(0.29)
X 10-6 70 kg |
IDs = Concentration (4.14 X 10-7) for workers
Children
ID = C X IR X EF X 10-6/BW
EF = | (7 days/week)(52 weeks/year)(10 years)
(365 days/year)(10 years) |
=
1.0
ID = | Concentration (100 mg/day)(1.0) X 10-6
10 kg |
Residential Child Exposure
= 1.0 X 10-5 (Concentration)
This Certain-teed Corporation Site Health Consultation was prepared by the Illinois Department of Public Health under a cooperative agreement with the Agency for Toxic Substances and Disease Registry (ATSDR). It is in accordance with approved methodology and procedures existing at the time the health consultation was begun.
Gail D. Godfrey
Technical Project Officer
Division of Health Assessment and Consultation
ATSDR
The Division of Health Assessment and Consultation, ATSDR, has reviewed this health consultation and concurs with its findings.
Richard E. Gillig
Chief, State Programs Section
Division of Health Assessment and Consultation
ATSDR