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B. Effects of an uneven random distribution
Einstein's work involved giving some greater mathematical
precision to some recent ideas of the physicist Marian von Smoluchowski.
Smoluchowski considered the significant effect that variations in a fluid's
density can have on how light waves travel through the fluid.
When a fluid, either gas or liquid, is compressed, its
molecules get crowded into a smaller space, so the fluid becomes more
dense. Since molecules constantly move about in random directions, there
is always some chance that the fluid will spontaneously compress itself as its
molecules move closer together at a given time. This chance is extremely
small if very many molecules are involved. But it's a less unlikely
coincidence for just a few independently-moving molecules to happen to move
towards each other, so the chance that a small mass of fluid will compress
spontaneously is much greater. Similarly, the chance that a portion of
fluid will spontaneously expand and decrease its density depends on the number
of molecules that have to move apart: small sets of molecules will happen
to move apart fairly often, while larger sets of molecules are less likely to
move apart at any given time.
The likelihood of a spontaneous density change depends on
the temperature. Higher temperature means higher average speed for the
molecules-or, viewed another way, higher temperature means higher average energy
per molecule. The molecules' energy is relevant, because it turns out that
the chance of a given-size density change is practically zero unless the energy
needed to compress or expand the fluid by the right amount is roughly equal to
the average energy of motion of a single molecule.
How will this affect light? Light waves travel more
slowly through matter than through empty space-even more slowly, the greater the
density of the material. If a transparent fluid has different densities at
different places, light waves will speed up or slow down as they travel
through. Furthermore, whenever light changes its speed, the light waves
will scatter; where the density changes a great deal within a short
distance, the light will scatter strongly.
While Smoluchowski had worked out this much, he had not
calculated the intensity of the scattered light waves. In taking up the
problem, Einstein considered two points. The likelihood of a given-sized
change in a fluid's density depends on the temperature; Einstein calculated this
dependence. Using the laws of electromagnetic force fields, Einstein also
calculated how strongly light waves would scatter when they ran into any given
density variation. Then, accounting for the likelihood of each possible
variation at a given temperature, Einstein combined these two results to see how
the light would be affected on the average-much scattering due to the most
likely density variations, plus a little scattering due to the less likely
density variations.
Einstein's result showed that the scattered light's
intensity depends on several factors.
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More light will scatter from a bigger volume of fluid,
since a bigger volume will contain more molecules to scatter the light.
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More light will scatter if the fluid has a higher
absolute temperature, since higher temperatures mean more agitation of the
fluid molecules and therefore larger density fluctuations.
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More light will scatter, the more easily the fluid is
compressed.
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More scattered light will be seen, the shorter one's
distance from the volume of fluid that scatters it. This is the same
phenomenon we see for any light source that sends waves out in all
directions: the closer you are to the source, the more light you catch
coming from it and the brighter it looks.
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More light will scatter, the more effective a small
density increase is in slowing down the light.
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More light will scatter, the more perpendicular the
original wave's direction of vibration is to its direction of
scattering. (As mentioned earlier, the polarization of light can be
detected with polarizing sunglasses or other devices; we'll have more to say
about this later.)
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More light will scatter, the shorter its waves (and
thus the higher the waves' frequency).
The last factor is particularly significant for why the
earth's atmosphere-a gaseous fluid itself-looks blue in the daytime.
If fluids scattered all light waves the same, independently of their frequency,
the light from the sky and the direct light from the sun would have the same
frequency mix and would thus both be the same color. But the atmosphere,
like any fluid, scatters high-frequency waves much more than low-frequency
waves. In fact, if two light waves are scattered by the air, one wave
having twice the frequency of the other, the higher-frequency scattered wave
will be about 16 times as intense as the lower-frequency scattered wave.
(The ratio would be exactly 16 if air slowed the speed of all light waves
equally, but the air slows higher-frequency light slightly more.) Unlike
direct sunlight, scattered sunlight has so much less of the low-frequency waves
like red and yellow that it looks blue.
(.....continued)
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