Publication Information
Title: Condensed tannins: Reactions of model compounds with furfuryl alcohol and furfuraldehyde
Author: Foo, L.; Hemingway, Richard W.
Date: 1985
Source: Journal of Wood Chemistry and Technology 5(1):135-158
Description: Reaction products of phloroglucinol or catechin with furfuryl alcohol and furfuraldehyde were studied. In reactions of furfuryl alcohol with phloroglucinol, only 2-furyl-(11, 31, 51-trihydroxyphenyl) methane was obtained as product, and 53% of the phloroglucinol was recovered. Reactions of furfuryl alcohol with catechin gave 2-furyl-(8-catechinyl) methane and 2-furyl-(6-catechinyl) methane in 4.0% and 1.5% yields, respectively, while 62% of the catechin was unreacted. Polymeric furans with few catechin moieties made up the oligomeric products (38% of catechin). Reaction of phloroglucinol with furfuraldehyde gave 2-furyl-di(11, 31, 51-trihydroxyphenyl) methane, an ustable product that readily polymerized during isolation. The solid state 13C-NMR spectrum of the higher polymers suggested one phloroglucinol moiety per furan unit, but lower oligomers contained more furan-furan condensation products. Reactions of catechin with furfuraldehyde gave 2-furyl-di(8-catechinyl)-(8-catechinyl) methane in low yield, with 65% of the catechin unreacted.
Keywords:
View and Print this Publication (2.4 MB)
Publication Notes:
- We recommend that you also print this page and attach it to the printout of the article, to retain the full citation information.
- This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.
Get the latest version of the Adobe Acrobat reader or Acrobat Reader for Windows with Search and Accessibility
Citation
Foo, L.; Hemingway, Richard W. 1985. Condensed tannins: Reactions of model compounds with furfuryl alcohol and furfuraldehyde. Journal of Wood Chemistry and Technology 5(1):135-158
|