n-Butyronitrile
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CAS
109-74-0
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CH3CH2CH2CN
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RTECS
ET8750000
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Synonyms & Trade Names
Butanenitrile, Butyronitrile, 1-Cyanopropane, Propyl cyanide, n-Propyl cyanide
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DOT ID & Guide
2411 131
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Exposure
Limits
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NIOSH REL: TWA 8 ppm (22 mg/m3)
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OSHA PEL: none
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IDLH
N.D.
See: IDLH INDEX
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Conversion
1 ppm = 2.83 mg/m3
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Physical Description
Colorless liquid with a sharp, suffocating odor. [Note: Forms cyanide in the body.]
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MW: 69.1
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BP: 244°F
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FRZ: -170°F
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Sol(77°F): 3%
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VP: 14 mmHg
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IP: 11.67 eV
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Sp.Gr: 0.81
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Fl.P: 62°F
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UEL: ?
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LEL: 1.65%
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Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F.
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Incompatibilities & Reactivities
Strong oxidizers & reducing agents, strong acids & bases
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Measurement Methods
NIOSH 1606 (adapt)
See: NMAM or OSHA Methods
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Personal Protection & Sanitation (See protection codes)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet (flammable)
Change: No recommendation
Provide: Quick drench
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First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
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Respirator Recommendations
NIOSH
Up to 80 ppm:
(APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s)
(APF = 10) Any supplied-air respirator
Up to 200 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s)
Up to 400 ppm:
(APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s)
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Up to 1000 ppm:
(APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
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Exposure Routes
inhalation, skin absorption, ingestion, skin and/or eye contact
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Symptoms
Irritation eyes, skin, respiratory system; headache, dizziness, lassitude (weakness, exhaustion), confusion, convulsions; dyspnea (breathing difficulty); abdominal pain, nausea, vomiting
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Target Organs
Eyes, skin, respiratory system, central nervous system, cardiovascular system
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See also: INTRODUCTION
See ICSC CARD: 1465
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