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Agent Name Manganese cyclopentadienyl tricarbonyl
CAS Number 12079-65-1
Formula C8-H5-Mn-O3
Major Category Metals
Synonyms Cyclopentadienylmanganese tricarbonyl; Cyclopentadienyl tricarbonyl manganese; MCT; [NIOSH]
Category Metals, Organic Compounds
Description Yellow, crystalline solid with a characteristic odor. [Note: An antiknock additive for gasoline. May be found in an oil & gaseous solution.] [NIOSH]
Sources/Uses Used as an anti-knock agent in unleaded gasoline--this use not permitted in the U.S.A. since 1981; [ACGIH]
Comments Injected doses of 20 mg/kg cause convulsions and pulmonary edema in rats. MCT was estimated to be twice as toxic to the lung as MMT (methylcyclopentadienyl manganese tricarbonyl). In chronic inhalation studies, rats showed no outward signs of disease during the exposure period (averaging 1 mg/m3 for 4 hours/day for 11 months), but increased excitability of the nervous system was detected with electrical studies after 7 months of exposure. [ACGIH]
Exposure Assessment
Skin Designation (ACGIH) Yes
Bioaccumulates Yes
TLV (ACGIH) 0.1 mg/m3, as Mn
PEL (OSHA)Ceiling(OSHA) = 5 mg/m3, as Mn
MAK 0.5 mg/m3, as Mn, inhalable fraction
Explanatory Notes Sublimes at 75-77 deg C; [CAMEO]
Adverse Effects
Neurotoxin Other CNS Neurotoxin
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: MANGANESE CYCLOPENTADIENYLTRICARBONYL  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:





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Last updated: January, 2009