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Agent Name Sulfuric acid
CAS Number 7664-93-9
Formula H2-O4-S
Major Category Toxic Gases & Vapors
Synonyms Acide sulfurique [French]; Acido solforico [Italian]; Acido sulfurico [Spanish]; Acidum sulfuricum; BOV; Battery acid; Dihydrogen sulfate; Dipping acid; Electrolyte acid; Hydrogen sulfate; Mattling acid; Oil of vitreol; Oil of vitriol; Schwefelsaeure; Schwefelsaeureloesungen [German]; Sulfuric acid; Sulphuric acid; Vitriol Brown Oil; Zwavelzuuroplossingen [Dutch]; [ChemIDplus] UN1830; UN1832; UN2796
Category Acids
Description Colorless to dark-brown, oily, odorless liquid. [Note: Pure compound is a solid below 51 degrees F. Often used in an aqueous solution.]; [NIOSH]
Sources/Uses Used in the fertilizer, petroleum refining, and battery industries; also used in metal cleaning and electroplating; [ACGIH] Used in printing, publishing, and photography shops; [ATSDR ToxFAQs]
Comments 77%-98% acid causes second or third degree burns after short contact; [CHRIS] Solutions <30% are corrosive; solutions >30% are highly corrosive; [Quick CPC] "Human carcinogen" designation refers to sulfuric acid contained in strong inorganic acid mists. A corrosive substance that can cause pulmonary edema; [ICSC] May cause erosion of teeth enamel; [HSDB]
Exposure Assessment
Skin Designation (ACGIH) No
TIH Yes
TLV (ACGIH) 0.2 mg/m3, thoracic fraction
PEL (OSHA) 1 mg/m3
MAK 0.1 mg/m3, inhalable fraction
IDLH (NIOSH) 15 mg/m3
Excerpts from Documentation for IDLHs In exposures of 5 to 15 minutes, some volunteers found 5 mg/m3 to be very objectionable, while others found it less so [Amdur et al. 1952b].
Vapor Pressure 5.93 x 10 -05 mm Hg
Odor Threshold Low 0.15 ppm
Lethal Concentration LC50 (rats) = 510 mg/m3/2h
Explanatory Notes Odor threshold from AIHA; The Guide from the Emergency Response Guidebook is for "Sulfuric acid, fuming."
Reference Link ATSDR ToxFAQs - Sulfuric Acid
Flammability (NFPA) 0: will not burn
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
IARC Carcinogen Known Carcinogen
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: SULFURIC ACID  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Biomedical References Search PubMed
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: September, 2008