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Agent Name 1,3-Dichloro-5,5-dimethylhydantoin
CAS Number 118-52-5
Formula C5-H6-Cl2-N2-O2
Major Category Nitrogen Compounds
Synonyms 1,3-Dichloro-5,5'-methylhydantoin; 1,3-Dichloro-5,5-dimethyl hydantoin; 1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione; 1,3-Dichloro-5,5-dimethylhydantoin; 1,3-Dwuchloro-5,5-dwumetylohydantoina [Polish]; 2,4-Imidazolidinedione, 1,3-dichloro-5,5-dimethyl-; DDH; Dactin; Daktin; Dantoin; Dichlorantin; Dwuchlorantyny [Polish]; Halane; Hydan; Hydan (antiseptic); Hydantoin, dichlorodimethyl-; Omchlor; [ChemIDplus] UN8027
Category Other Nitrogen Compounds
Description White powder with a chlorine-like odor; [NIOSH]
Sources/Uses Used as a chlorinating agent, for organic synthesis, and to stabilize vinyl chloride polymers; [ACGIH] Used as a disinfectant and industrial deodorant; used in water treatment and laundry bleaches; [HSDB]
Comments Hypochlorous acid is released upon contact with water. A concentration of 10 ppm is the maximum level recommended to prevent respiratory irritation when used to sanitize swimming pools. A worker exposed to a concentration exceeding 0.2 mg/m3 complained of cough and chest discomfort. [ACGIH]
Exposure Assessment
Skin Designation (ACGIH) No
TLV (ACGIH) 0.2 mg/m3
STEL (ACGIH) 0.4 mg/m3
PEL (OSHA) 0.2 mg/m3
IDLH (NIOSH) 5 mg/m3
Excerpts from Documentation for IDLHs Based on health considerations and acute oral toxicity data in animals [Kay 1961/62; Korolev et al. 1982], a value of about 500 mg/m3 would have been appropriate for 1,3�dichloro�5,5�dimethylhydantoin. However, the revised IDLH for 1,3�dichloro�5,5�dimethylhydantoin is 5 mg/m3 based on being 25 times the NIOSH REL and OSHA PEL of 0.2 mg/m3 (25 is an assigned protection factor for respirators and was used during the Standards Completion Program for deciding when the "most protective" respirators should be used for 1,3�dichloro�5,5�dimethylhydantoin).
Odor Threshold Low 0.01 ppm
Lethal Concentration LCLo (rats) = 20,000 mg/m3/1H
Explanatory Notes Odor threshold from "Quick Guide: The Electronic NIOSH Pocket Guide to Chemical Hazards"; Flash point = 346 deg F;
Adverse Effects
Toxic Pneumonitis Yes
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: 1,3-DICHLORO-5,5-DIMETHYLHYDANTOIN  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: September, 2008