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Agent Name Diborane
CAS Number 19287-45-7
Formula B2-H6
Major Category Toxic Gases & Vapors
Synonyms Boroethane; Boron hydride; Diboron hexahydride; Diborane; [ChemIDplus] UN1911
Category Hydrides
Description Colorless gas with a repulsive, sweet odor; Note: Usually shipped in pressurized cylinders diluted with hydrogen, argon, nitrogen, or helium; [NIOSH]
Sources/Uses Used as a rocket fuel, semiconductor doping agent, rubber vulcanizer, reducing agent, and polymerization catalyst; [ACGIH]
Comments Listed as one of "major irritant airborne toxicants"; [LaDou, p. 523] Animals exposed to high concentrations develop respiratory irritation and pulmonary edema; [ACGIH] Corrosive to the skin and eyes; [ICSC]
Reference Link ATSDR Medical Management - Diborane
Exposure Assessment
Skin Designation (ACGIH) No
TIH Yes
TLV (ACGIH) 0.1 ppm
PEL (OSHA) 0.1 ppm
IDLH (NIOSH) 15 ppm
Excerpts from Documentation for IDLHs Human data: None relevant for use in determining the revised IDLH.
Odor Threshold Low 1.8 ppm
Odor Threshold High 3.5 ppm
Lethal Concentration LC50 (rats) = 40 ppm/4H
Explanatory Notes Odor threshold from AIHA; Flash point = -90 deg C;
Reference Link International Chemical Safety Cards (WHO/IPCS/ILO)
Flammability (NFPA) 4: burns readily
Adverse Effects
Toxic Pneumonitis Yes
Dermatotoxin Skin Burns
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: DIBORANE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: September, 2008