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Agent Name 4-Aminodiphenylamine
CAS Number 101-54-2
Formula C12-H12-N2
Major Category Nitrogen Compounds
Synonyms 1,4-Benzenediamine, N-phenyl-; 4-Aminodiphenylamine; Acna Black DF Base; Azosalt R; Black Base P; C.I. 37240; C.I. 76085; C.I. Azoic Diazo Component 22; C.I. Developer 15; C.I. Oxidation Base 2; CI 37240; CI 76085; CI Azoic Diazo Component 22; CI Developer 15; CI Oxidation Base 2; Diphenyl Black; Diphenylamine, 4-amino-; Diphenylamine, p-amino-; Fast Blue R Salt; Luxan Black R; N, 4'-Bianiline; N-4'-Bianiline; N-Fenyl-p-fenylendiamin [Czech]; N-Phenyl-1,4-benzenediamine; N-Phenyl-1,4-phenylenediamine; N-Phenyl-p-aminoaniline; N-Phenyl-p-phenylenediamine; Naphthoelan Navy Blue; Oxy Acid Black Base; Peltol BR; Peltol BR II; Rodol Gray B base; Semidin; Semidine; Variamine Blue RT; Variamine Blue Salt RT; p-(Phenylamino)aniline; p-Aminodifenylamin [Czech]; p-Aminodiphenylamine; p-Anilinoaniline; p-Phenylenediamine, N-phenyl-; p-Semidine; [ChemIDplus] UN8027
Category Amines, Aromatic
Description Purple powder or needles; [HSDB]
Sources/Uses Used to produce dyes, pharmaceuticals, and photographic chemicals; [HSDB]
Comments Potential adverse effects form using this hair dye include dermatitis, eye injury, and liver damage. [HSDB] One of the allergens in hair dyes to which hairdressers may be exposed; [Kanerva, p. 965] Aminodiphenylamine can cause immunologic, occupational contact urticaria. [Kanerva 2004, p. 104] A skin and eye irritant; May cause skin sensitization after prolonged contact; Can induce methemoglobinemia if ingested; [ICSC]
Exposure Assessment
Skin Designation (ACGIH) Not evaluated
Vapor Pressure 1.21 x 10 -05 mm Hg
Explanatory Notes Flash point = 380 deg F';
Adverse Effects
Methemoglobinemia Methemoglobinemia, Secondary
Skin Sensitizer Yes
Hepatotoxin Hepatotoxin, Secondary
Links to Other NLM Databases
Health Studies Human Health Effects from Hazardous Substances Data Bank: P-AMINODIPHENYLAMINE  
Toxicity Information Search TOXNET
Chemical Information Search ChemIDplus
Related Information in Haz-Map
Diseases Occupational diseases associated with exposure to this agent:
Processes Industrial Processes with risk of exposure:





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Last updated: September, 2008