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NIOSH Publication No. 2007-107:

School Chemistry Laboratory Safety Guide

October 2006

 

Appendix


Appendix A. Common Safety Symbols
Appendix B. National Fire Protection Association Hazard Labels
Appendix C. Substances with Greater Hazardous Nature Than Educational Utility
Appendix E. Incompatible Chemicals
Appendix F. Recommended Safety and Emergency Equipment for the Laboratory
Appendix G. How Does a Chemical Enter the Body?
Appendix H. What are Exposure Limits?
Appendix I. General Guidelines to Follow in the Event of a Chemical Accident or Spill
Appendix J. Understanding an MSDS
Appendix K. Sample MSDS
Appendix L. Web Site Resources
Appendix M. Glossary


Appendix D. Substances With a Hazardous Nature, but May Have Potential Educational Utility

These chemicals should be removed from the schools if alternatives can be used. For those that must be retained, amounts should be kept to a minimum. These are appropriate for advanced-level High School classes only.

This following list was generated from the Manual of Safety and Health Hazards in the School Science Laboratory published by U.S. Department of Health and Human Services, National Institute for Occupational Safety and Health [1984].

Carcinogenic substances were identified from the Report on Carcinogens (10th Edition) generated by the National Toxicology Program (2002).

Chemical CAS Number Hazard
Acetamide 60–35–5 Combustible solid
Aluminum chloride 7446–70–0 Water reactive, corrosive
Ammonium bichromate 7789–09–5 Oxidizer, corrosive, known human carcinogen
Ammonium oxalate 1113–38–8 May be fatal if inhaled or ingested
Ammonium vanadate 7803–55–6 May be fatal if inhaled or ingested
Antimony 7440–36–0 May be fatal if inhaled, irritant
Antimony oxide 1309–64–4 Irritant
Antimony potassium tartrate 11071–15–1 Irritant
Barium chloride 10361–37–2 May be fatal if ingested, irritant
Benzone (phenylbutazone) 50–33–9 Irritant
Beryllium carbonate 66104–24–3 Irritant
Bromine 7726–95–6 Oxidizer, corrosive, may be fatal if inhaled or ingested
Cadmium and cadmium compounds N/A Known human carcinogen
Carmine 860–22–0 Irritant, burning may produce carbon monoxide, carbon dioxide, sulfur oxides, and nitrogen oxides.
Catechol 120–80–9 Corrosive
Chromic acid 7738–94–5 Oxidizer, known human carcinogen
Chromium acetate 1066–30–4 Irritant
Cobalt, metal 7440–48–4 Possible human carcinogen (IARC, Group 2B)
Cobalt nitrate 10141–05–6 Oxidizer, irritant
Cyclohexane 110–82–7 Flammable (NFPA = 3)
Cyclohexene 110–83–8 Flammable (nfpa = 3), corrosive, forms peroxides
Dichloroindophenol sodium salt 620–45–1 Irritant
2,4–Dinitrophenol 51–28–5 Irritant
Ferrous Sulfate 7720–78–7 Irritant
Formaldehyde (formalin) 50–00–0 Flammable (NFPA = 3), reasonably anticipated human carcinogen
Fuchsin (acid/basic) 3244–88–0/ 632–99–5 Irritant
Gasoline 8006–61–9 Flammable (NFPA = 3)
Hematoxylin 517–28–2 Irritant
Hydrogen sulfide 7783–06–4 Corrosive
Hydroquinone 123–31–9 May be fatal if ingested
Isoamyl alcohol (isopentyl alcohol) 123–51–3 Irritant, combustible liquid and vapor
Isobutyl alcohol 78–83–1 Flammable (NFPA = 3)
Magnesium chlorate 10326–21–3 Irritant
Methyl ethyl ketone 78–93–3 Irritant, flammable (NFPA = 3)
Methyl oleate 112–62–9 Toxic properties not investigated
Nickel carbonate 3333–67–3 Reasonably anticipated human carcinogen
Nickelous acetate 373–02–4 Reasonably anticipated human carcinogen
Paradichlorobenzene 106–46–7 Irritant
Pentane 109–66–0 Irritant, flammable (NFPA = 4)
Petroleum ether 8032–32–4 Flammable (NFPA = 4)
1–Phenyl–2–Thiourea (Phenylthiocarbamide) 103–85–5 May be fatal if inhaled or ingested
Potassium chlorate 3811–04–9 Oxidizer
Potassium chromate 7789–00–6 Oxidizer, known human carcinogen
Potassium periodate 7790–21–8 Oxidizer
Potassium permanganate 7722–64–7 Oxidizer, corrosive
Salol (phenyl salicylate) 118–55–8 Irritant
Sodium bromate 7789–38–0 Oxidizer
Sodium chlorate 7775–09–9 Oxidizer
Sodium fluoride 7681–49–4 May be fatal if inhaled or ingested
Sodium oxalate 62–76–0 Corrosive, may be fatal if ingested
Sodium nitrate 7631–99–4 Oxidizer, irritant
Sodium silicofluoride 16893–85–9 Toxic
Sudan III 85–86–9 Decomposes to oxides of nitrogen
Sulfamethazine 57–68–1 Irritant
Toluene 108–88–3 Flammable (NFPA = 3), irritant, may be fatal if ingested
Trichloroethylene 79–01–6 Reasonably anticipated human carcinogen
Urethane 51–79–6 Combustible, reasonably anticipated human carcinogen
Xylenes 1330–20–7 Flammable (NFPA = 3), irritant, may be fatal if ingested

 

 


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< Appendix C
Appendix E >