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NIOSH Publication No. 2007-107:

School Chemistry Laboratory Safety Guide

October 2006

 

Appendix


Appendix A. Common Safety Symbols
Appendix C. Substances with Greater Hazardous Nature Than Educational Utility
Appendix D. Substances with a Hazardous Nature, But May Have Potential Educational Utility .
Appendix E. Incompatible Chemicals
Appendix F. Recommended Safety and Emergency Equipment for the Laboratory
Appendix G. How Does a Chemical Enter the Body?
Appendix H. What are Exposure Limits?
Appendix I. General Guidelines to Follow in the Event of a Chemical Accident or Spill
Appendix J. Understanding an MSDS
Appendix K. Sample MSDS
Appendix L. Web Site Resources
Appendix M. Glossary


Appendix B. National Fire Protection Association Hazard Labels


The National Fire Protection Association (NFPA) has developed a visual guide (right) for a number of chemicals pertinent to the MSDS. The ANSI/NFPA 704 Hazard Identification system, the NFPA diamond, is a quick visual review of the health hazard, flammability, reactivity, and special hazards a chemical may present.

The diamond is broken into four sections (blue, red, yellow, and white). The symbols and numbers in the four sections indicate the degree of hazard associated with a particular chemical or material.

Health Hazard (Blue)
4
Danger
May be fatal on short exposure. Specialized protective equipment
required
3
Warning
Corrosive or toxic. Avoid skin contact or inhalation
2
Warning
May be harmful if inhaled or absorbed
1
Caution
May be irritating
0
No unusual hazard

Flammability (Red)
4
Danger
Flammable gas or extremely flammable liquid
3
Warning
Combustible liquid flash point below 100 °F
2
Caution
Combustible liquid flash point of 100° to 200 °F
1
Combustible if heated
0
Not combustible

Reactivity (Yellow)
4
Danger
Explosive material at room temperature
3
Danger
May be explosive if shocked, heated under confinement or mixed with water
2
Warning
Unstable or may react violently if mixed with water
1
Caution
May react if heated or mixed with water but not violently
0
Stable
Not reactive when mixed with water

Special Notice Key (White)
W
Water Reactive
OX
Oxidizing Agent


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