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   Joe Mullin

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  Oil Spill Chemical Treating Agents

There are different types of chemical treating agents that can be applied to an oil spill to assist in controlling, cleaning up or removing the oil. These include:

bullet Dispersants
bullet Surface washing agents
bullet Bioremediation agents
bullet Miscellaneous oil spill control agents

Dispersant application by ship.Dispersants are the most commonly used chemical treating agent. Chemical dispersants are designed to break up surface oil slicks, and disperse the oil as fine droplets into the water column so that natural mixing action will dilute the subsurface oil concentration. This action transfers the oil from the waters surface into the water column. There it is dispersed by currents and subjected to natural processes such as biodegradation that render the oil harmless. If this process is effective, the oil is prevented from moving into sensitive environments or stranding onshore. This will eliminate or reduce the damage to important coastal habitats, marine life, or coastal facilities.

The dispersion process does move the oil from the surface to the water column. This potentially exposes the water column and near shore shallow bottom-dwelling organisms to oil. These oil concentrations however, are extremely low and decrease quickly, thus limiting overall impact to sensitive environmental resources. Since the very small chemically dispersed oil droplets are not prone to re-coalescing, the treated oil is unlikely to form tar balls or patties. Modern dispersant formulations are a mixture of low toxicity solvents and surfactants designed for use in the marine environment to disperse oil with minimal toxic consequences. Approval must be obtained from the appropriate authorities before these chemical agents can be used. The U.S. Environmental Protection Agency (U.S. EPA) maintains the National Contingency Plan (NCP) Product Schedule that lists dispersants, other chemicals, and other spill mitigating substances that may be authorized for use on oil spills.

Helicopter with dispersant spray bucket.Surface Washing Agents or beach cleaners are different from dispersants. Surface washing agents are products which, when applied to oil stranded on the shoreline or structures, increase the ease or efficiency of removal by flushing with water. These products remove oil from solid surfaces such as beaches or rocks through a detergent mechanism and do not involve dispersing or solubilizing the oil into the water column. Surface washing agents allow the released oil to readily float and be recovered. For oil spills affecting the intertidal zone, surface washing agents are applied at low tide and left to work for as long as possible. They are then washed off with a low-pressure water stream into an area that has been isolated with containment booms.

At sea dispersant application from helicopter.Bioremediation agents are microbiological cultures, enzyme additives or nutrient additives that are deliberately introduced into an oil spill. They significantly increase the rate biodegradation and thereby mitigate the effects of the spill. Bioremediation agents are typically used as a polishing step after conventional mechanical cleanup techniques options have been used.

Miscellaneous oil spill control agents are any products, other than dispersant, surface washing agent, bioremediation agent, burning agent or sorbent that can be used to enhance oil spill cleanup, removal, treatment or mitigation. These products include emulsifiers, elastizers, chemical based sorbents, solidifiers or mixed products.

Application of dispersants by DC-4 aircraft.Historically in the United States, dispersants have been considered by decision makers and responders as a secondary response tool and have been given only minimal consideration during oil spills and in contingency planning efforts. Since the mid-1990’s, dispersant operations have become a more accepted alternative response technology. This is especially true in the U.S. Gulf of Mexico where dispersant operations have been conducted since 1989. The main reason for this difference is that approximately 90% of the U.S. oil supplies are transported through the Gulf, which creates more “opportunities” for spills that are likely to be dispersible. The objectives of current research are to examine and address the technical and environmental issues associated with the use of dispersants on the Outer Continental Shelf (OCS).

Desired Outcomes

  1. Gather data to support decisions on the use of dispersants for oil spills located on the U.S. OCS.
     
  2. Through Joint Industry Projects conduct research with agencies, organizations and industry on the use of chemical treating agents to contain, remove and remediate the effects of an oil spill. Identify oil types and scenarios where chemical treating agents may have potential to be utilized.

Tactical Plan (2005-2010)

  1. Research whether dispersants work in cold water/broken ice conditions and identify oil types and scenarios where dispersants may have potential to be utilized. Proof of effectiveness will increase response options to oil spills in cold water/broken ice conditions.
     
  2. Continue research to correlate the results of dispersant effectiveness experiments conducted at Ohmsett with laboratory and small wave tank experiments and at-sea field trials.
     
  3. Work with state and federal agencies including the U.S. EPA to improve standardized laboratory dispersant effectiveness testing.
     
  4. Work with state and federal agencies to improve the SMART (Surveillance and Monitoring for Alternative Response Technology) monitoring protocols where direct, independent, measurements of dispersant effectiveness are made in the field. This will include evaluations of new types of sensors (e.g., fluorometers, and particle size analyzers) used by response teams.
     
  5. Work cooperatively with agencies, organizations and industry to determine the limiting viscosity for chemical dispersion at sea with different oil types and environmental conditions. This includes calm and low wave energy environments.
     
  6. Work cooperatively with agencies, organizations and industry to improve aerial and ship borne dispersant delivery systems.
     
  7. Work cooperatively with agencies, organizations and industry to determine the effects of chemically dispersed and biodegraded oils.
     
  8. Research the use of chemical herders to thicken oil slicks among broken ice floes so that the oil can be ignited and burned effectively. Validate chemical herding action in ice with the primary purpose to enhance in situ burning by thickening oil slicks.
     
  9. Take advantage of planned, experimental oil spills conducted outside of U.S. territorial waters to conduct experiments on the use of dispersants and chemical treating agents to improve oil spill response operations.

For more information on the Chemical Treating Agents Projects, contact Joseph Mullin at 703-787-1556, or via email.

Chemical Treating Agents Projects

114

Field Evaluation of Oil Spill Chemical Additives

160

Study of Oil Spill Chemical Treating Agents

296

Chemical Response to Oil Spill: Ecological Effects Research Forum (CROSERF)
298 Testing at Ohmsett to Determine Optimum Times to Decant to Temporary Storage Devices

338

Biodegradation of Chemically Dispersed Oil an Ecosystem Approach
 347 Emulsions Formed at Sea and in Test Tanks

349

Technology Assessment of the Use of Dispersants on Spills from MMS-Regulated OCS Facilities

350

Laboratory Study to Compare the Effectiveness of Chemical Dispersants When Applied Dilute versus Neat

375

Development of Dispersant Test Protocol at Ohmsett

395

Extending Temporary Storage Capacity Offshore With Emulsion Breakers

413

Assessment of the Use of Dispersants on Marine Oil Spills in California

427

Dispersant Effectiveness Test Protocol Development for Ohmsett

436

Chemical Characteristics of an oil and the Relationship to Dispersant Effectiveness

449

Effects of Chemically Dispersed and Biodegraded Oils

450

Using Dispersants to Test and Evaluate the Effectiveness of Dispersants in Cold Water and Broken Ice

456

Techniques to Remove Dissolved Dispersant from Ohmsett Basin Water

458

Process for the Removal of Spent Oil Spill Dispersants from Test Water at Ohmsett

476

Ohmsett 2003 Cold Water Dispersant Effectiveness Experiments

477

Correlating Results of Dispersants Effectiveness at Ohmsett with Identical At-Sea Trials: Effects of Oil Viscosity and Dispersant to Oil Ratio

486

Fate of Emulsion Breakers Used for Decanting

493

Understanding Oil Spill Dispersants: Efficacy and Effects

506

Analysis of IFO-180 and IFO-380 Oil Properties for Dispersant Window of Opportunity

507

Correlating Results of Ohmsett Dispersant Test with At-Sea Trials: Workshop to Coordinate Publications and Prioritize Follow-up Research

512

Transfer of Decanting Technology Research to Oil Spill Response Organizations and Regulators

513

Laboratory Testing to Determine Dispersion Predictability of the Baffled Flask Test and Swirling Flask Test

514

Dispersant Effectiveness Testing on Heavy OCS Crude Oils at Ohmsett

516

Development of a Method to Produce Large Quantities of Realistic Water-In-Oil Emulsions for use in Evaluating Oil Spill Response Equipment and Methods

526

Correlate Ohmsett Dispersant Tests with At Sea Trials; Supplemental Tests to Complete Test Matrix

527

The Effect of Warming Viscous Oils Prior to Discharge on Dispersant Performance

529

Analysis of Dispersant Effectiveness of Heavy Fuel Oils and Weathered Crude Oils at Two Different Temperatures Using the Baffled Flask Test

542

Dispersant Effectiveness Testing on Realistic Emulsions at Ohmsett

545

Calm Sea Application of Dispersants

546

Chemical Dispersibility of OCS Crude Oils in Non-Breaking Waves, Part 1 Determining the Limiting Oil Viscosity for Dispersion in Non-Breaking

554

Mid-Scale Test Tank Research On Using Oil Herding Surfactants To Thicken Oil Slicks In Broken Ice

563

Understanding the Effects of Time and Energy on the Effectiveness of Dispersants
568 Research at Ohmsett on the Effectiveness of Chemical Dispersants on Alaskan Oils in Cold Water
590 Changes with Dispersant Effectiveness with Extended Exposure in Calm Seas
595 Identification of Window of Opportunity for Chemical Dispersants on Gulf of Mexico Crude Oils
598 Upgrade of SMART Dispersant Effectiveness Monitoring Protocol

613

Development of a Training Package on the Use of Chemical Dispersants for Ohmsett - The National Oil Spill Response Test Facility

615

Chemical Dispersant Research at Ohmsett

617

Employing Chemical Herders to Improve Oil Spill Response Operations

635

Literature Review on Chemical Treating Agents in Fresh and Brackish Water

636

Characteristics, Behavior and Response Effectiveness of Spilled Dielectric Insulating Oil in the Marine Environment

637

Validation of the Two Models Developed to Predict the Window of Opportunity for Dispersant Use in the Gulf of Mexico

638

Chemical Dispersant Research at Ohmsett: Phase 2

For more information on Oil Spill Chemical Treating Agents, contact Joseph Mullin at 703-787-1556 or via e-mail.


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Last Updated: 12/15/2008, 02:41 PM

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