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Content:
Joe Mullin
Pagemasters:
OEMM Web Team
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Oil Spill Chemical Treating Agents
There are different types of chemical treating agents that can be applied to
an oil spill to assist in controlling, cleaning up or removing the oil.
These include:
![bullet](Assets/Icons/bluebullet.gif) |
Dispersants |
![bullet](Assets/Icons/bluebullet.gif) |
Surface washing agents |
![bullet](Assets/Icons/bluebullet.gif) |
Bioremediation agents |
![bullet](Assets/Icons/bluebullet.gif) |
Miscellaneous oil spill control agents |
Dispersants
are the most commonly used chemical treating agent. Chemical dispersants are
designed to break up surface oil slicks, and disperse the oil as fine
droplets into the water column so that natural mixing action will dilute the
subsurface oil concentration. This action transfers the oil from the waters
surface into the water column. There it is dispersed by currents and
subjected to natural processes such as biodegradation that render the oil
harmless. If this process is effective, the oil is prevented from moving
into sensitive environments or stranding onshore. This will eliminate or
reduce the damage to important coastal habitats, marine life, or coastal
facilities.
The dispersion process does move the oil from the surface to the water
column. This potentially exposes the water column and near shore shallow
bottom-dwelling organisms to oil. These oil concentrations however, are
extremely low and decrease quickly, thus limiting overall impact to
sensitive environmental resources. Since the very small chemically dispersed
oil droplets are not prone to re-coalescing, the treated oil is unlikely to
form tar balls or patties. Modern dispersant formulations are a mixture of
low toxicity solvents and surfactants designed for use in the marine
environment to disperse oil with minimal toxic consequences. Approval must
be obtained from the appropriate authorities before these chemical agents
can be used. The U.S. Environmental Protection Agency (U.S. EPA) maintains
the National Contingency Plan
(NCP) Product Schedule that lists dispersants, other chemicals, and
other spill mitigating substances that may be authorized for use on oil
spills.
Surface
Washing Agents or beach cleaners are different from dispersants. Surface
washing agents are products which, when applied to oil stranded on the
shoreline or structures, increase the ease or efficiency of removal by
flushing with water. These products remove oil from solid surfaces such as
beaches or rocks through a detergent mechanism and do not involve dispersing
or solubilizing the oil into the water column. Surface washing agents allow
the released oil to readily float and be recovered. For oil spills affecting
the intertidal zone, surface washing agents are applied at low tide and left
to work for as long as possible. They are then washed off with a
low-pressure water stream into an area that has been isolated with
containment booms.
Bioremediation
agents are
microbiological cultures, enzyme additives or nutrient additives that are
deliberately introduced into an oil spill. They significantly increase the
rate biodegradation and thereby mitigate the effects of the spill.
Bioremediation agents are typically used as a polishing step after
conventional mechanical cleanup techniques options have been used.
Miscellaneous oil spill control agents
are any products, other than dispersant, surface washing
agent, bioremediation agent, burning agent or sorbent that can be used to
enhance oil spill cleanup, removal, treatment or mitigation. These products
include emulsifiers, elastizers, chemical based sorbents, solidifiers or
mixed products.
Historically
in the United States, dispersants have been considered by decision makers
and responders as a secondary response tool and have been given only minimal
consideration during oil spills and in contingency planning efforts. Since
the mid-1990’s, dispersant operations have become a more accepted
alternative response technology. This is especially true in the U.S. Gulf of
Mexico where dispersant operations have been conducted since 1989. The main
reason for this difference is that approximately 90% of the U.S. oil
supplies are transported through the Gulf, which creates more
“opportunities” for spills that are likely to be dispersible. The objectives
of current research are to examine and address the technical and
environmental issues associated with the use of dispersants on the Outer
Continental Shelf (OCS).
Desired Outcomes
- Gather data to support
decisions on the use of dispersants for oil spills located on the U.S.
OCS.
- Through Joint Industry
Projects conduct research with agencies, organizations and industry on the
use of chemical treating agents to contain, remove and remediate the
effects of an oil spill. Identify oil types and scenarios where chemical
treating agents may have potential to be utilized.
Tactical Plan (2005-2010)
- Research whether
dispersants work in cold water/broken ice conditions and identify oil
types and scenarios where dispersants may have potential to be utilized.
Proof of effectiveness will increase response options to oil spills in
cold water/broken ice conditions.
- Continue research to
correlate the results of dispersant effectiveness experiments conducted at
Ohmsett with laboratory and small wave tank experiments and at-sea field
trials.
- Work with state and
federal agencies including the U.S. EPA to improve standardized laboratory
dispersant effectiveness testing.
- Work with state and
federal agencies to improve the SMART (Surveillance and Monitoring for
Alternative Response Technology) monitoring protocols where direct,
independent, measurements of dispersant effectiveness are made in the
field. This will include evaluations of new types of sensors (e.g.,
fluorometers, and particle size analyzers) used by response teams.
- Work cooperatively with
agencies, organizations and industry to determine the limiting viscosity
for chemical dispersion at sea with different oil types and environmental
conditions. This includes calm and low wave energy environments.
- Work cooperatively with
agencies, organizations and industry to improve aerial and ship borne
dispersant delivery systems.
- Work cooperatively with
agencies, organizations and industry to determine the effects of
chemically dispersed and biodegraded oils.
- Research the use of
chemical herders to thicken oil slicks among broken ice floes so that the
oil can be ignited and burned effectively. Validate chemical herding
action in ice with the primary purpose to enhance in situ burning by
thickening oil slicks.
- Take advantage of
planned, experimental oil spills conducted outside of U.S. territorial
waters to conduct experiments on the use of dispersants and chemical
treating agents to improve oil spill response operations.
For more information on the Chemical Treating Agents Projects, contact
Joseph Mullin
at 703-787-1556, or via email.
Chemical Treating Agents Projects |
114 |
Field
Evaluation of Oil Spill Chemical Additives |
160 |
Study of
Oil Spill Chemical Treating Agents |
296 |
Chemical
Response to Oil Spill: Ecological Effects Research Forum (CROSERF) |
298 |
Testing at
Ohmsett to Determine Optimum Times to Decant to Temporary Storage
Devices |
338 |
Biodegradation of Chemically Dispersed Oil an Ecosystem Approach |
347 |
Emulsions
Formed at Sea and in Test Tanks |
349 |
Technology
Assessment of the Use of Dispersants on Spills from MMS-Regulated OCS
Facilities |
350 |
Laboratory
Study to Compare the Effectiveness of Chemical Dispersants When
Applied Dilute versus Neat |
375 |
Development
of Dispersant Test Protocol at Ohmsett |
395 |
Extending
Temporary Storage Capacity Offshore With Emulsion Breakers |
413 |
Assessment
of the Use of Dispersants on Marine Oil Spills in California |
427 |
Dispersant
Effectiveness Test Protocol Development for Ohmsett |
436 |
Chemical
Characteristics of an oil and the Relationship to Dispersant
Effectiveness |
449 |
Effects of
Chemically Dispersed and Biodegraded Oils |
450 |
Using
Dispersants to Test and Evaluate the Effectiveness of Dispersants in
Cold Water and Broken Ice |
456 |
Techniques
to Remove Dissolved Dispersant from Ohmsett Basin Water |
458 |
Process for
the Removal of Spent Oil Spill Dispersants from Test Water at Ohmsett |
476 |
Ohmsett
2003 Cold Water Dispersant Effectiveness Experiments |
477 |
Correlating
Results of Dispersants Effectiveness at Ohmsett with Identical At-Sea
Trials: Effects of Oil Viscosity and Dispersant to Oil Ratio |
486 |
Fate of
Emulsion Breakers Used for Decanting |
493 |
Understanding Oil Spill Dispersants: Efficacy and Effects |
506 |
Analysis of
IFO-180 and IFO-380 Oil Properties for Dispersant Window of
Opportunity |
507 |
Correlating
Results of Ohmsett Dispersant Test with At-Sea Trials: Workshop to
Coordinate Publications and Prioritize Follow-up Research |
512 |
Transfer of
Decanting Technology Research to Oil Spill Response Organizations and
Regulators |
513 |
Laboratory
Testing to Determine Dispersion Predictability of the Baffled Flask
Test and Swirling Flask Test |
514 |
Dispersant
Effectiveness Testing on Heavy OCS Crude Oils at Ohmsett |
516 |
Development
of a Method to Produce Large Quantities of Realistic Water-In-Oil
Emulsions for use in Evaluating Oil Spill Response Equipment and
Methods |
526 |
Correlate
Ohmsett Dispersant Tests with At Sea Trials; Supplemental Tests to
Complete Test Matrix |
527 |
The Effect
of Warming Viscous Oils Prior to Discharge on Dispersant Performance |
529 |
Analysis of
Dispersant Effectiveness of Heavy Fuel Oils and Weathered Crude Oils
at Two Different Temperatures Using the Baffled Flask Test |
542 |
Dispersant
Effectiveness Testing on Realistic Emulsions at Ohmsett |
545 |
Calm Sea
Application of Dispersants |
546 |
Chemical
Dispersibility of OCS Crude Oils in Non-Breaking Waves, Part 1
Determining the Limiting Oil Viscosity for Dispersion in Non-Breaking |
554 |
Mid-Scale Test Tank
Research On Using Oil Herding Surfactants To Thicken Oil Slicks In
Broken Ice |
563 |
Understanding the Effects of Time and Energy on the
Effectiveness of Dispersants |
568 |
Research at Ohmsett on the Effectiveness of Chemical
Dispersants on Alaskan Oils in Cold Water |
590 |
Changes with Dispersant Effectiveness with Extended
Exposure in Calm Seas |
595 |
Identification of Window of Opportunity for Chemical
Dispersants on Gulf of Mexico Crude Oils |
598 |
Upgrade of SMART Dispersant Effectiveness Monitoring
Protocol |
613 |
Development of a Training Package on the Use of
Chemical Dispersants for Ohmsett - The National Oil Spill Response
Test Facility |
615 |
Chemical Dispersant
Research at Ohmsett |
617 |
Employing Chemical Herders
to Improve Oil Spill Response Operations |
635 |
Literature Review on Chemical Treating Agents in Fresh and Brackish Water
|
636 |
Characteristics, Behavior and Response Effectiveness of Spilled Dielectric Insulating Oil in the Marine Environment |
637 |
Validation of the Two Models Developed to Predict the Window of Opportunity for Dispersant Use in the Gulf of Mexico
|
638 |
Chemical Dispersant Research at Ohmsett: Phase 2
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For more information on Oil Spill Chemical Treating Agents, contact Joseph Mullin at 703-787-1556 or via e-mail.
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Last Updated:
12/15/2008,
02:41 PM
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