Themed series in organo-fluorine chemistry

Shape-persistent macrocycles with intraannular alkyl groups: some structural limits of discotic liquid crystals with an inverted structure

Synthesis of (-)-Indolizidine 167B based on domino hydroformylation/cyclization reactions

Knorr-Rabe partial reduction of pyrroles: Application to the synthesis of indolizidine alkaloids

Combining two-directional synthesis and tandem reactions, part 11: second generation syntheses of (±)-hippodamine and (±)-epi-hippodamine

Analogues of amphibian alkaloids: total synthesis of (5R,8S,8aS)-(-)-8-methyl-5-pentyloctahydroindolizine (8-epi-indolizidine 209B) and [(1S,4R,9aS)-(-)-4-pentyloctahydro-2H-quinolizin-1-yl]methanol

Facile synthesis of two diastereomeric indolizidines corresponding to the postulated structure of alkaloid 5,9E-259B from a Bufonid toad (Melanophryniscus)

Unexpected degradation of the bisphosphonate P-C-P bridge under mild conditions

Total synthesis of the indolizidine alkaloid tashiromine

Mechanistic aspects of the isomerization of Z-vinylic tellurides double bonds in the synthesis of potassium Z-vinyltrifluoroborate salts

Synthesis of dihydrophenanthridines by a sequence of Ugi-4CR and palladium-catalyzed intramolecular C-H functionalization

Stereoselective synthesis of (2S,3S,4Z)-4-fluoro-1,3-dihydroxy-2-(octadecanoylamino)octadec-4-ene, [(Z)-4-fluoroceramide], and its phase behavior at the air/water interface

New acylides: synthesis of 3-O-[γ-(4-oxo-2-aryl-thiazolidin-3-yl)butyryl]erythromycin A derivatives

Diels-Alder reactions using 4,7-dioxygenated indanones as dienophiles for regioselective construction of oxygenated 2,3-dihydrobenz[f]indenone skeleton

Efficient 1,4-addition of α-substituted fluoro(phenylsulfonyl)methane derivatives to α,β-unsaturated compounds

Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates

Synthesis of (S)-1-(2-chloroacetyl)pyrrolidine-2-carbonitrile: A key intermediate for dipeptidyl peptidase IV inhibitors

Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me₃SiCF₂SO₂Ph and PhSO₂CF₂H reagents catalyzed by chiral quaternary ammonium salts

Perhalogenated pyrimidine scaffolds. Reactions of 5-chloro-2,4,6-trifluoropyrimidine with nitrogen centred nucleophiles

Inversion symmetry and local vs. dispersive interactions in the nucleation of hydrogen bonded cyclic n-mer and tape of imidazolecarboxamidines

Control of asymmetric biaryl conformations with terpenol moieties: Syntheses, structures and energetics of new enantiopure C ₂-symmetric diols

Synthesis of 2-substituted 9-oxa-guanines {5-aminooxazolo[5,4-d]pyrimidin-7(6H)-ones} and 9-oxa-2-thio-xanthines {5-mercaptooxazolo[5,4-d]pyrimidin-7(6H)-ones}

C ₂-symmetric bisamidines: Chiral Brønsted bases catalysing the Diels-Alder reaction of anthrones

Phase-vanishing halolactonization of neat substrates

Dimerization of propargyl and homopropargyl 6-azido-6-deoxy-glycosides upon 1,3-dipolar cycloaddition

The role of an aromatic group in remote chiral induction during conjugate addition of α-sulfonylallylic carbanions to ethyl crotonate

Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT

End game strategies towards the total synthesis of vibsanin E, 3-hydroxyvibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A

A practical synthesis of the ¹³C/¹⁵N-labelled tripeptide N-formyl-Met-Leu-Phe, useful as a reference in solid-state NMR spectroscopy

Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds

Diastereoselective and enantioselective reduction of tetralin-1,4-dione

Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis

The first preparative solution phase synthesis of melanotan II

Synthesis of 2,3,6,7-tetrabromoanthracene

Synthesis of imidazol-1-yl-acetic acid hydrochloride: A key intermediate for zoledronic acid

Synthesis of chiral cyclohexanes and carbasugars by 6-exo-dig radical cyclisation reactions

Convenient method for preparing benzyl ethers and esters using 2-benzyloxypyridine

One-pot preparation of substituted pyrroles from α-diazocarbonyl compounds

DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

Synthesis of new triazole-based trifluoromethyl scaffolds

A simple route for renewable nano-sized arjunolic and asiatic acids and self-assembly of arjuna-bromolactone

Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester

N-Arylation of amines, amides, imides and sulfonamides with arylboroxines catalyzed by simple copper salt/EtOH system

Trifluoromethyl ethers – synthesis and properties of an unusual substituent

Sordarin, an antifungal agent with a unique mode of action