Agent Name |
Iron pentacarbonyl |
CAS Number |
13463-40-6 |
Formula |
C5-Fe-O5 |
Major Category |
Toxic Gases & Vapors |
Synonyms |
Iron carbonyl; Pentacarbonyl iron; [NIOSH] |
Category |
Other Toxic Gases & Vapors |
Description |
Colorless to yellow to dark-red, oily liquid; [NIOSH] Ignites in air; Insoluble in water; [Sullivan, p. 979] |
Sources/Uses |
Used as an anti-knock agent in gasoline in Europe; may be generated when fine iron particles react with carbon monoxide; [ACGIH] |
Comments |
Acute inhalation studies of animals: lung irritation and pulmonary edema are prominent toxic effects. [ACGIH] Also can cause liver,kidney, and CNS injury; [CAMEO] Readily absorbed through the skin; Acute exposure can injure the lungs (pneumonitis), liver, and kidneys. Chronic exposure can cause iron overload and hemochromatosis. [Sullivan, p. 982] See "ORGANOMETALS." |
Exposure Assessment |
Skin Designation (ACGIH) |
No |
TIH |
Yes |
Bioaccumulates |
Yes |
TLV (ACGIH) |
0.1 ppm |
STEL (ACGIH) |
0.2 ppm |
MAK |
0.1 ppm |
Vapor Pressure |
21 mm Hg |
Explanatory Notes |
Flash point = 5 deg F; [CAMEO] |
Reference Link |
International Chemical Safety Cards (WHO/IPCS/ILO) |
Flammability (NFPA) |
3: may ignite at ambient temperature |
Adverse Effects |
Toxic Pneumonitis |
Yes |
Neurotoxin |
Other CNS Neurotoxin |
Hepatotoxin |
Hepatotoxin, Secondary |
Nephrotoxin |
Yes |
Links to Other NLM Databases |
Health Studies |
Human Health Effects from Hazardous Substances Data Bank: IRON PENTACARBONYL
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