Agent Name |
Mercury II fulminate |
CAS Number |
628-86-4 |
Formula |
C-H-N-O.1/2Hg |
Major Category |
Nitrogen Compounds |
Synonyms |
Fulminate of mercury; Fulminate of mercury, dry; Fulminate of mercury, wet; Fulminic acid, mercury(2+) salt; Mercuric cyanate; Mercury fulminate; Mercury fulminate (Hg(ONC)2); Mercury(II) fulminate; Mercury, bis(fulminato)-; UN0135; [ChemIDplus] |
Category |
Explosives |
Description |
Silver-white metallic liquid; [CAMEO] White crystals or gray powder; [HSDB] |
Sources/Uses |
Used in the manufacturing of explosives; [ChemIDplus] Prepared in a difficult to control reaction of mercury, nitric acid and ethanol; It was first used in the 17th century by Nobel to detonate dynamite, but its use has been abandoned in most industrial countries. [HSDB] Used to manufacture caps and detonators for explosives; [Hawley] |
Comments |
A skin and eye irritant; Mercury poisoning has been reported in munitions workers handling this substance; [HSDB] Fulminates are compounds with the carbon-nitrogen-oxygen group that are sensitive explosives. [Hawley] See "Mercury, inorganic compounds." |
Restricted |
Transport of Mercury fulminate, (wetted, > = 20% water) is forbidden in passenger aircraft/rail or cargo aircraft. [HMT] |
Exposure Assessment |
BEI |
Total inorganic mercury in urine = 35 ug/g creatinine, sample prior to shift; Total inorganic mercury in blood = 15 ug/L, sample end of shift at end of workweek |
Skin Designation (ACGIH) |
Yes |
Bioaccumulates |
Yes |
TLV (ACGIH) |
0.025 mg/m3, as Hg |
PEL (OSHA) | Ceiling(OSHA)=0.1 mg/m3, as Hg |
MAK |
0.1 mg/m3, as Hg |
IDLH (NIOSH) |
10 mg/m3 |
Vapor Pressure |
3.2 x 10 -10 mm Hg |
Explanatory Notes |
Exposure values are for "Mercury, inorganic compounds, as Hg." |
Adverse Effects |
Neurotoxin |
Motor Neuropathy |
Hepatotoxin |
Hepatotoxin, Secondary |
Nephrotoxin |
Yes |
Reproductive Toxin |
Yes |
IARC Carcinogen |
Not Classifiable |
Links to Other NLM Databases |
Health Studies |
Human Health Effects from Hazardous Substances Data Bank: MERCURY FULMINATE
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