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Chemical Sampling Information
Osmium Tetroxide (as Os)
 Field Definitions
 Analytical Methods
 Health Guidelines
General Description

NAME: Osmium Tetroxide (as Os)

SYNONYM(s): Osmic acid

IMIS: 1960

CAS: 20816-12-0

NIOSH: RTECS RN1140000

DOT: 2471 55

DESCRIPTION:

Colorless to pale yellow solid with an odor like chlorine; sharp and choking.
MW: 254
VP: 11 mm at 27 C
BP: 130 C (Sublimes well below BP)
MP: 40.6 C

INCOM: Hydrochloric acid, easily oxidized organic materials

Exposure Limits

OSHA GENERAL INDUSTRY PEL: 0.002 mg/m3

OSHA CONSTRUCTION INDUSTRY PEL: 0.002 mg/m3 TWA

ACGIH TLV: 0.0002 ppm, 0.0016 mg/m3 TWA; 0.0006 ppm, 0.0047 mg/m3 STEL

NIOSH REL: 0.0002 ppm TWA; 0.0006 ppm STEL

Health Factors

SYMPTOM(s): Lacrimation, vision disturbance, conjunctivitis; headaches; coughing, dyspnea; dermatitis

HEALTH EFFECTS: Irritation-Eye, Nose, Throat, Skin---Marked (HE14) Lung edema (HE11)

ORGAN: Eyes, respiratory system, skin

Monitoring

PRIMARY SAMPLING/ANALYTICAL METHOD (SLC1):



MEDIA: Mixed Cellulose Ester Filter (MCEF) 0.8 microns in series with a Midget Fritted Glass Bubbler (MFGB) containing 15 mL Distilled Water
MAX V: 480 Liters   MIN V: 480 Liters   MAX F: 1.0 L/min (TWA)
MAX V: 15 Liters   MAX F: 1.0 L/min (STEL)
ANL 1: Inductively Coupled Argon Plasma; ICP/DCP-AES
REF: 2 (OSHA ID-125G)
CLASS: Not Validated
ANL A: Neutron Activation Analysis; NAA
REF: 2 (OSHA In-House File)
CLASS: Not Validated
NOTE: Before sampling, OSHA personnel are to contact SLTC for any additional instructions or changes to sampling strategies. When analysis of the compound is requested, an elemental analysis is performed and reported as the compound.


Revision Date: 12/28/1993
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